Search results for "Composites"
showing 10 items of 1905 documents
Defect characterization in Al welded joints by non-contact Lamb wave technique
2006
Abstract The use of air-coupled sensors to detect flaws in Al welded joints and the advantage of Lamb wave for their characterization has been proved. Ultrasonic waves were generated by a pulsed laser and by contact angle-beam transducer, and received by an air-coupled capacitive transducer. Laser-based configuration was used to quickly locate the defect, whereas the angle-beam contact probe configuration to characterize it thanks to the dispersive behavior of Lamb waves. Guided waves allow inspection of the complete thickness with only one scan, permitting to detect and to size both internal and surface defects; their high flexibility in the measurement is due to the various parameters cha…
Creep of polymer concrete in the nonlinear region
2000
Two polyester-based polymer concretes with various volume content of diabase as an extender and aggregate are tested in creep under compression at different stress levels. The phenomenological and structural approaches are both used to analyze the experimental data. Common features of changes in the instantaneous and creep compliances are clarified, and a phenomenological creep model which accounts for the changes in the instantaneous compliance and in the retardation spectrum depending on the stress level is developed. It is shown that the model can be used to describe the experimental results of stress relaxation and creep under repeated loading. Modeling of the composite structure and su…
Green composites of organic materials and recycled post-consumer polyethylene
2004
International audience; Addition of organic fillers to post‐consumer recycled plastics can give rise to several advantages. First of all, the cost of these fillers is usually very low, the organic fillers are biodegradable contributing to an improved environmental impact and, last but not least, some mechanical and thermomechanical properties can be enhanced. Organic fillers are not widely used in the plastic industry although their use is increasing. Bad dispersion into the polymer matrix at high‐level content and poor adhesion with the matrix are the more important obstacles to this approach. In this work various organic fillers have been used with a post‐consumer plastic material origina…
Effect of media composition on long-term in vitro stability of barium alginate and polyacrylic acid multilayer microcapsules.
2000
For a number of applications stability of microcapsules is a critical factor. Since the maintenance of polyelectrolyte complexes depends considerably on the ion composition we tested the physical properties of barium alginate capsules and searched for conditions to improve stability by a multilayer coating with polyethylenimine (PEI) and polyacrylic acid (PAA). Mechanical stability and diameters were determined in barium alginate capsules and compared with multilayer capsules. Multilayer coating resulted in smaller capsules than barium complexing alone. The difference was more pronounced when CaCl2 was used instead of NaCl during coating. Barium alginate capsules and application of CaCl2 du…
Phase evolution by thermal treatment of equimolar cobalt–magnesium cordierite glass powders
2004
Abstract The structural evolution with annealing time at temperatures between 900 and 1100 °C of loosely compacted equimolar cobalt–magnesium cordierite glass powder was reported. The glass, with composition MgCoAl4Si5O18, was prepared by melting a glass precursor, previously synthesized by a semiwet method, at 1650 °C. Field emission scanning electron microscopy (FESEM) of isothermally heated glasses at 900 and 950 °C revealed increased phase separation with thermal treatment. X-ray diffraction (XRD) results of these powders indicated that the first crystalline phase formed was μ cobalt-containing cordierite which transformed to α cordierite with longer annealing. At the beginning of the μ…
Synthesis and characterization of nanometric powders of UO2+x, (Th,U)O2+x and (La,U)O2+x
2009
This paper describes a new way of preparing nanometric powders of uranium oxide, to fit the needs of studies on UO{sub 2} oxidation, through the electrochemical reduction of U(VI) into U(IV). These powders can also be doped with radionuclides if necessary. The precipitation of oxides occurs in reducing and anoxic conditions. This original method makes it possible to synthesize nanometric UO{sub 2} powders with a calibrated size, as well as the Th- and La-doped UO{sub 2} powders with a predefined composition. The powder characterization by the X-ray diffraction, X-ray photoelectron spectroscopy and transmission electron Microscopy shows the formation of spherical crystallites of UO{sub 2+x},…
Silica nanoparticle core structure examined by the E?Si? center 29Si strong hyperfine interaction
2015
Abstract β-Ray irradiation up to 1.2 GGy was employed to induce E′Si γ defects and to study the structure of silica nanoparticles with diameters from 7 up to 20 nm. Defect concentration and their 29 Si strong hyperfine doublet were investigated through electron paramagnetic resonance measurements. Our data indicate that stable defects are located in the nanoparticle core. Furthermore, the E′Si γ hyperfine interaction evidences that the core structure is denser than bulk silica and independent from the particle size. Finally, we put in evidence that the core structure is stable and unaffected by the irradiation in the investigated dose range maintaining the specific features of nanoparticles.
On the origin of the sigmoid shape in the UO2 oxidation weight gain curves
2009
International audience; Cracking and spalling are known to occur during the oxidation of UO2. However, these phenomena are not considered by the existing kinetic models of the oxidation of UO2 into U3O8. In this study the oxidation of UO2 samples of various sizes from the single crystal to nanopowders, has been followed by isothermal and isobaric thermogravimetry, environmental scanning electron microscopy and in situ X-ray diffraction at temperatures ranging from 250 to 370°C in air. It has been shown that cracking occurs once a critical layer thickness of intermediate oxide has been reached, which corresponds to the beginning of the sigmoid kinetic curve. Cracking contribution to the sigm…
Oxygen stoichiometry control of nanometric oxide compounds: The case of titanium ferrites
2011
Three techniques have been coupled with an original device, based on H{sub 2}/H{sub 2}O equilibrium, controlling oxygen partial pressure: XRD, TGA and DC conductivity in order to characterize very reactive compounds such as nanometric powders. From XRD, both the structure and the oxygen stoichiometry (thanks to their lattice parameter) were investigated in situ. From TGA, it was the oxygen stoichiometry (thanks to mass gain or loss) which was determined. From DC conductivity, it was both the structure and the oxygen stoichiometry (thanks to the activation energy) which were obtained. The advantages were to determine very rapidly and with a small amount of powder the equilibrium conditions (…
(La0.8Sr0.2)(Mn1−yFey)O3±δ oxides for ITSOFC cathode materials?
2005
The oxygen transport properties in (La 0.8 Sr 0.2 )(Mn 1-y Fe y )O 3±δ (LSMF) with various iron contents y = 0, 0.2, 0.5, 0.8 and 1 were determined by the IEDP technique. Both oxygen diffusion and surface exchange coefficients were found to be greater for y = 0.8 and 1 than those of LSM (y=0). Moreover, for y ≤0.5, grain boundary diffusion was the rate limiting step especially at lower temperatures. Thus, in the LSMF perovskite materials, the oxygen diffusion via oxygen vacancies is enhanced by Fe. The LSMF electrical performances were measured by impedance spectroscopy. Compared to LSM and LSF (y= 1), porous LSMF cathodes with y= 0.2-0.8 exhibit poor electronic conductivity: Fe, by reducin…