Search results for "Composites"

Analytical stress-strain law of FRP confined masonry in compression: Literature review and design provisions

2017

Abstract The use of Fibre Reinforced Polymer (FRP) wraps has become common in practical applications to retrofit existing columns with poor structural features. Wrapping the member with one or more FRP sheets makes it possible to induce confinement action and enhance strength and ductility. This application has been widely studied and adopted in reinforced concrete members for about twenty years, while its suitability to masonry columns and piers has been investigated during the last decade. The results of several studies were summarized in different design expressions for calculating effective confinement pressure, ultimate compressive stress and strain, and the overall trend of the stress…

Finite element analysis of the out-of-plane behavior of FRP strengthened masonry panels

2017

Abstract In the present study a numerical model is proposed for the response of out-of-plane loaded calcarenite masonry walls strengthened with vertical CFRP strips applied on the substrate by means of epoxy resin. A simplified structural scheme is considered consisting in a beam fixed at one end, subjected to constant axial load and out-of-plane lateral force monotonically increasing. Two different constraint conditions are taken into account: in the first one, the panel is assumed free to rotate at the top end while, in the second one, the rotation is restrained. Three-dimensional finite elements are used for the calcarenite parts and an equivalent constitutive law available in the litera…

Biological oxygen apparent transmissibility of hydrogel contact lenses with and without organosilicon moieties.

2003

The instrument oxygen transmissibility (IOT) of organosilicon hydrogels, measured by electrochemical procedures, is 5-10 times larger than that of conventional hydrogels. A method is described that allows the estimation of the oxygen tension at the lens-cornea interface for closed- and open-eyelids situations by combining the IOT of the hydrogels and corneal parameters such as corneal thickness, corneal permeability and oxygen flux across the cornea. From these results the biological oxygen apparent transmissibility (BOAT) is obtained, an important parameter which an multiplication with the pressure of oxygen on the external part of the lens gives the oxygen flux onto the cornea. Contact le…

Comparative Hybrid Hartree-Fock-DFT Calculations of ReO3, SrTiO3, BaTiO3, PbTiO3 and CaTiO3 (001) Surfaces

2021

A [Cr2Ni] coordination polymer: slow relaxation of magnetization in quasi-one-dimensional ferromagnetic chains

2018

The reaction of [Cr3IIIO(OAc)6(H2O)3]NO3·AcOH with 2-hydroxynaphthaldehyde, 2-amino-isobutyric acid and NiCl2·6H2O in MeOH, under basic and solvothermal conditions, led to the formation of the quasi-1D coordination polymer {[CrIII2NiII(L)4(MeOH)2]}n (where L = the dianion of the Schiff base between 2-hydroxynaphthaldehyde and 2-amino-isobutyric acid), which behaves as a ferromagnetic chain, displaying slow relaxation of magnetization.

Synthesis of YAG nanopowder by the co-precipitation method: Influence of pH and study of the reaction mechanisms

2012

International audience; YAG nanopowders with an average grain size of 30 nm have been successfully synthesized by the co-precipitation method using nitrates with precipitant of ammonium hydrogen carbonate. The influence of precipitation conditions such as pH, aging time and calcination temperature on the formation of secondary phases has been studied. The accurate control of pH value at every stage of precipitation process is crucial to avoid the presence of YAM (Yttrium Aluminium Monoclinic, Y4Al2O9) and yttrium oxide (Y2O3) after calcination. The reaction mechanisms have been investigated using different techniques such as infrared spectroscopy, x-ray diffraction and thermal analyses. The…

Spark plasma sintering of cobalt ferrite nanopowders prepared by coprecipitation and hydrothermal synthesis.

2007

International audience; Cobalt ferrite exhibits a high coercivity at room temperature and a strong magnetic anisotropy compared to the other spinel ferrites and, consequently appears as an interesting material for permanent magnets and high-density recording. The magnetic properties depend also on the crystallite size. In order to keep the powder properties in a bulk material, dense nanostructured cobalt ferrite has to be sintered. A field activated sintering process like spark plasma sintering (SPS) may be promising for such challenge. The present paper deals with: (i) the preparation of cobalt ferrite by two methods: coprecipitation and hydrothermal synthesis in supercritical water; (ii) …

The Ba2LnFeNb4O15 “tetragonal tungsten bronze”: Towards RT composite multiferroics

2009

Several Niobium oxides of formula Ba2LnFeNb4O15 (Ln = La, Pr, Nd, Sm, Eu, Gd) with the Tetragonal Tungsten Bronze (TTB) structure have been synthesised by conventional solid-state methods. The Neodymium, Samarium and Europium compounds are ferroelectric with Curie temperature ranging from 320 to 440K. The Praseodymium and Gadolinium compounds behave as relaxors below 170 and 300 K respectively. The Praseodymium, Neodymium, Samarium, Europium and Gadolinium compounds exhibit magnetic hysteresis loops at room temperature originating from traces of a barium ferrite secondary phase. The presence of both ferroelectric and magnetic hysteresis loops at room temperature allows considering these mat…

Halloysite nanotubes/pluronic nanocomposites for waterlogged archeological wood: thermal stability and X-ray microtomography

2020

Filling a polymer with halloysite nanotubes is considered a promising strategy to generate nanocomposites with tailored physicochemical properties. We have focused our attention on pluronic block copolymer/halloysite nanocomposites prepared by melt blending. The effect of composition on thermal stability and polymer crystallinity was investigated by thermogravimetry and differential scanning calorimetry. Electron microscopy was used to monitor the nanoparticle distribution in the polymeric matrix. The pluronic thermal stability is reduced by the clay nanoparticles. Concerning the polymer crystallinity, it is slightly decreased even if the melting temperature is lowered by halloysite. Furthe…

Optimization of two-step techniques engineered for the preparation of polyamide 6 graphene oxide nanocomposites

2019

Abstract Different processing conditions to achieve polyamide 6 (PA6)-graphene oxide (GO) nanocomposites were investigated. GO was pre-dispersed in PA6 by three different solvent-based methods and, further, melt processed to prepare nanocomposites at two different loading levels, namely 2 and 5 wt.%. The evolution of rheological and mechanical properties was analyzed by investigating eventual changes in the microstructure and polymer crystallinity, aiming at providing a detailed processing-structure-properties relationship for these systems.