Search results for "Compounds"

showing 10 items of 3372 documents

Synthesis, characterization, and cellular investigations of porphyrin– and chlorin–indomethacin conjugates for photodynamic therapy of cancer

2021

Indomethacin is a potent non-steroidal anti-inflammatory drug (NSAID) with a strong selective inhibitor activity towards cyclooxygenase-2 (COX-2), an enzyme that is highly overexpressed in various tumour cells, being involved in tumourigenesis. Concomitantly, porphyrins have gained much attention as promising photosensitizers (PSs) for the non-invasive photodynamic therapy (PDT) of cancer. Herein, we report the design, and determine the singlet oxygen generation capacity and in vitro cellular toxicity of porphyrin- and chlorin-indomethacin conjugates (P2-Ind and C2-Ind). Both the conjugates were obtained in high yields and were characterized by 1H, 19F and 13C NMR as well as by high resolut…

photosensitizermedicine.medical_treatmentPhotodynamic therapyDFT calculations010402 general chemistryPhotochemistry01 natural sciencesBiochemistrychemistry.chemical_compoundnon-steroidal anti-inflammatory drugpolycyclic compoundsmedicinePhysical and Theoretical ChemistryTriplet stateCytotoxicity010405 organic chemistrySinglet oxygenOrganic Chemistrysinglet oxygen generationPorphyrin0104 chemical sciencesPhotochemotherapychemistrySettore CHIM/03 - Chimica Generale E InorganicaChlorincytotoxicityPhototoxicityporphyrinConjugateOrganic & Biomolecular Chemistry
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Use of Biostimulants for Organic Apple Production: Effects on Tree Growth, Yield, and Fruit Quality at Harvest and During Storage

2018

The experiment was conducted during two consecutive seasons (years 2016 and 2017) in an organic apple orchard of the cultivar Jonathan. Several biostimulants were tested (10 in total), including humic acids, macro and micro seaweed extracts, alfalfa protein hydrolysate, amino acids alone or in combination with zinc, B-group vitamins, chitosan and a commercial product containing silicon. Treatments were performed at weekly intervals, starting from the end of May until mid-August. The macroseaweed extract was effective in stimulate tree growth potential in both years, as shown by a significantly larger leaf area (+20% as compared to control) and by an higher chlorophyll content and leaf photo…

photosynthesisorganic productionMalus × domesticaphysiological disordersfungiseaweed extractfood and beverageslcsh:SB1-1110Plant Sciencephenolic compoundslcsh:Plant cultureanthocyaninsOriginal ResearchFrontiers in Plant Science
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TRAIL acts synergistically with iron oxide nanocluster-mediated magneto- and photothermia

2019

International audience; Targeting TRAIL (Tumor necrosis factor (TNF)-Related Apoptosis-Inducing Ligand) receptors for cancer therapy remains challenging due to tumor cell resistance and poor preparations of TRAIL or its derivatives. Herein, to optimize its therapeutic use, TRAIL was grafted onto iron oxide nanoclusters (NCs) with the aim of increasing its pro-apoptotic potential through nanoparticle-mediated magnetic hyperthermia (MHT) or photothermia (PT). Methods: The nanovector, NC@TRAIL, was characterized in terms of size, grafting efficiency, and potential for MHT and PT. The therapeutic function was assessed on a TRAIL-resistant breast cancer cell line, MDA-MB-231, wild type (WT) or T…

photothermal therapyCell SurvivalMedicine (miscellaneous)TRAIL02 engineering and technologyFerric CompoundsFlow cytometryTNF-Related Apoptosis-Inducing LigandCell membrane03 medical and health sciences0302 clinical medicineMicroscopy Electron TransmissionCell surface receptorCell Line Tumormedicine[SDV.BBM] Life Sciences [q-bio]/Biochemistry Molecular BiologyHumans[SDV.BBM]Life Sciences [q-bio]/Biochemistry Molecular Biologymagnetic hyperthermiaReceptorPharmacology Toxicology and Pharmaceutics (miscellaneous)ComputingMilieux_MISCELLANEOUSchemistry.chemical_classificationCell Deathmedicine.diagnostic_testTumor Necrosis Factor-alphairon oxide nanoclustersapoptosisHyperthermia InducedFlow Cytometry021001 nanoscience & nanotechnology3. Good healthMagnetic hyperthermiamedicine.anatomical_structurechemistryTransferrinApoptosis030220 oncology & carcinogenesisCancer research[SDV.IB]Life Sciences [q-bio]/BioengineeringTumor necrosis factor alpha0210 nano-technologyResearch Paper
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Assessment of Physical and Chemical Stability of Different Magnesium Compounds in Tablets

2020

Modern lifestyle, excessive chemicalization of agricultural products, excessive processing and refining of food, cause a decrease in daily intake of magnesium, cation with an extremely important role in prevention and treatment of many diseases. As a result, there arises the need for extra magnesium intake in the form of dietary supplements. In this study were evaluated the physical and chemical stability of magnesium-containing tablets, depending on the active compound and the excipients used. Magnesium tablets in the form of orotate, lactate, citrate, oxide and hydroxide were taken into study and physical and chemical stability were observed over the validity period, at 6 and at 12 month…

physicochemical stabilityDaily intakeMaterials Science (miscellaneous)Oxidechemistry.chemical_elementGeneral Biochemistry Genetics and Molecular Biologychemistry.chemical_compoundMaterials ChemistryFood scienceGeneral Pharmacology Toxicology and PharmaceuticsChemical composition2. Zero hungerMagnesium intakeMagnesiumProcess Chemistry and TechnologytabletsGeneral EngineeringGeneral ChemistryGeneral Medicinemagnesium compoundsvalidity period.3. Good healthchemistryActive compound[SDE]Environmental SciencesHydroxideChemical stability
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Apparent and quantitative loss of fatty acids and triacylglycerols at frying temperatures

2012

[EN]: Olive and sunflower oils were heated at 180 °C for 5, 10 and 15 hours with the aim of defining the changes in the contents of fatty acid methyl esters (FAME) and triacylglycerols (TAG) under frying conditions. Differences between apparent and real loss of FAME or TAG are defined for an adequate interpretation of the changes taking place at high temperature. Such differences depend on the expression of the results and frequently result in erroneous conclusions. Results showed that from the normalized composition it could be deduced that only the most unsaturated FAME (C18:2) or TAG containing it was significantly altered. However, quantitative data indicated that all the unsaturated FA…

polar famefood.ingredientDouble bond[ SDV.AEN ] Life Sciences [q-bio]/Food and NutritionFrituralcsh:TX341-641Ésteres metílicos de ácidos grasos polaresoilTriglicéridoschemistry.chemical_compoundfoodFood and NutritionTX341-641polar compoundFatty acidsPolar FAMEÁcidos grasoschemistry.chemical_classificationChromatographyChemistryNutrition. Foods and food supplySunflower oilOrganic ChemistryPolar compoundsFatty acidSunflowerAlimentation et NutritionFryingComposition (visual arts)Triacylglycerolsfatty acidfryingtriacylglycerolfatty acid;frying;polar compound;polar fame;triacylglycerol;oil[SDV.AEN]Life Sciences [q-bio]/Food and Nutritionlcsh:Nutrition. Foods and food supplyAcyl groupFood ScienceOlive oilCompuestos polares
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Sequestration of biogenic amines by alginic and fulvic acids.

2006

The interaction of natural (alginic and fulvic acids) and synthetic (polyacrylic acid 2.0 kDa) polyelectrolytes with some protonated polyamines [diamines: ethylendiamine, 1,4-diaminobutane (or putrescine), 1,5-diaminopentane (or cadaverine); triamines: N-(3-aminopropyl)-1,4diaminobutane (or spermidine), diethylenetriamine; tetramine: N.N'-bis(3-aminopropyl)-1,4-diaminobutane (or spermine); pentamine: tetraethylene-pentamine; hexamine: pentaethylenehexamine] was studied at T=25 degrees C by potentiometry and calorimetry. Measurements were performed without supporting electrolyte, in order to avoid interference, and results were reported at I=0 mol L(-1). For all the systems, the formation of…

polyammonium-polycarboxylate interactionsAlginatesPolymersBiogenic aminesInorganic chemistryFulvic acidCarboxylic AcidsBiophysicsProtonationCalorimetryBiochemistryMedicinal chemistryElectrolyteschemistry.chemical_compoundbiogenic amineGlucuronic AcidPolyaminesBenzopyransAlginic acidPolyacrylic acidCadaverineChemistryHexuronic AcidsOrganic ChemistryPolyacrylic acidPentaminesequestrationPolyelectrolytesPolyelectrolyteQuaternary Ammonium CompoundsBiogenic amines; Fulvic acid; Alginic acid; Polyacrylic acid; sequestrationModels ChemicalDiethylenetriamineThermodynamicsAmine gas treatingProtonsMathematics
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Additional file 6: of Male breast cancer in BRCA1 and BRCA2 mutation carriers: pathology data from the Consortium of Investigators of Modifiers of BR…

2016

Pathology of invasive MBCs in the general population from SEER and BRCA1 MBCs and ORs in predicting male BRCA1 mutation carrier status. (DOCX 19 kb)

polycyclic compoundsbacteriabiochemical phenomena metabolism and nutritionbacterial infections and mycosesskin and connective tissue diseases3. Good health
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Additional file 6: of Male breast cancer in BRCA1 and BRCA2 mutation carriers: pathology data from the Consortium of Investigators of Modifiers of BR…

2016

Pathology of invasive MBCs in the general population from SEER and BRCA1 MBCs and ORs in predicting male BRCA1 mutation carrier status. (DOCX 19 kb)

polycyclic compoundsbacteriabiochemical phenomena metabolism and nutritionbacterial infections and mycosesskin and connective tissue diseases3. Good health
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Pro-Degradant Activity of Naturally Occurring Compounds on Polyethylene in Accelerate Weathering Conditions

2019

In this work, naturally occurring compounds, such as Vitamin E (VE) and Ferulic Acid (FA), at high concentrations, have been considered as pro-degradant agents for Low Density Polyethylene (PE). However, all obtained results using the naturally occurring molecules as pro-oxidant agents for PE have been compared with the results achieved using a classical pro-oxidant agent, such as calcium stearate (Ca stearate) and with neat PE. The preliminary characterization, through rheological, mechanical and thermal analysis, of the PE-based systems highlights that the used naturally occurring molecules are able to exert a slight plasticizing action on PE and subsequently the PE rigidity and crystalli…

polyethylene02 engineering and technology010402 general chemistryCalcium stearatelcsh:Technology01 natural sciencesArticlepro-oxidant activityFerulic acidchemistry.chemical_compoundCrystallinityStearateGeneral Materials Sciencelcsh:MicroscopyNaturally occurring compoundlcsh:QC120-168.85lcsh:QH201-278.5lcsh:TPolyethylene021001 nanoscience & nanotechnologyphoto-oxidation0104 chemical sciencesPolyolefinLow-density polyethylenechemistrylcsh:TA1-2040Degradation (geology)lcsh:Descriptive and experimental mechanicsnaturally occurring compoundslcsh:Electrical engineering. Electronics. Nuclear engineeringlcsh:Engineering (General). Civil engineering (General)0210 nano-technologylcsh:TK1-9971Nuclear chemistryMaterials
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Analysis of a GC/MS Thermal Desorption System with Simultaneous Sniffing for Determination of Off-Odor Compounds and VOCs in Fumes Formed during Extr…

2001

A thermal desorption equipment introducing volatile organic compounds (VOCs) into the gas chromatographic/ mass spectrometric system (GC/MS) with simultaneous sniffing (SNIFF) is a suitable method for identifying the volatile organic off-odor compounds formed during the extrusion coating process of low-density polyethylene. Fumes emitted during the extrusion coating process of three different plastic materials were collected at two different temperatures (285 and 315 degrees C) from an outgoing pipe and near an extruder. The VOCs of fumes were analyzed by drawing a known volume of air through the adsorbent tube filled with a solid adsorbent (Tenax GR). The air samples were analyzed by using…

polyethylenechemistry.chemical_classificationfumesChromatographyVOCPlastics extrusionThermal desorptionTenaxExtrusion coatingcoatingsMass spectrometrymethodsAnalytical Chemistrychemistryvolatile organic compoundsVolatile organic compoundGas chromatographyGas chromatography–mass spectrometryAnalytical Chemistry
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