Search results for "Compres"
showing 10 items of 1107 documents
Comparative study of the high-pressure behavior of ZnV2O6, Zn2V2O7, and Zn3V2O8
2020
We report a study of the high-pressure structural behavior of ZnV2O6, Zn2V2O2, and Zn3V2O8, which has been explored by means of synchrotron powder x-ray diffraction. We found that ZnV2O6 and Zn3V2O8 remain in the ambient-pressure structure up to 15 GPa. In contrast, in the same pressure range, Zn2V2O2 undergoes three phase transitions at 0.7, 3.0, and 10.8 GPa, respectively. Possible crystal structures for the first and second high-pressure phases are proposed. Reasons for the distinctive behavior of Zn2V2O2 are discussed. The compressibility of the different polymorphs has been determined. The response to pressure is found to be anisotropic in all the considered compounds and the room-temp…
New high-pressure phase of HfTiO4 and ZrTiO4 ceramics
2010
We studied the high-pressure effects on the crystalline structure of monoclinic HfTiO4 and ZrTiO4. We found that the compressibility of these ceramics is highly non-isotropic, being the b-axis the most compressible one. In addition, the a-axis is found to have a small and negative compressibility. At 2.7 GPa (10.7 GPa) we discovered the onset of an structural phase transition in HfTiO4 (ZrTiO4), coexisting the low- and high-pressure phases in a broad pressure range. The new high-pressure phase has a monoclinic structure which involves an increase in the Ti-O coordination and a collapse of the cell volume. The equation of state for the low-pressure phase is also determined.
High-pressure structural and vibrational properties of monazite-type BiPO4, LaPO4, CePO4, and PrPO4
2018
[EN] Monazite-type BiPO4, LaPO4, CePO4, and PrPO4 have been studied under high pressure by ab initio simulations and Raman spectroscopy measurements in the pressure range of stability of the monazite structure. A good agreement between experimental and theoretical Raman-active mode frequencies and pressure coefficients has been found which has allowed us to discuss the nature of the Raman-active modes. Besides, calculations have provided us with information on how the crystal structure is modified by pressure. This information has allowed us to determine the equation of state and the isothermal compressibility tensor of the four studied compounds. In addition, the information obtained on th…
High-pressure structural and elastic properties of Tl2O3
2014
The structural properties of Thallium (III) oxide (Tl2O3) have been studied both experimentally and theoretically under compression at room temperature. X-ray powder diffraction measurements up to 37.7 GPa have been complemented with ab initio total-energy calculations. The equation of state of Tl2O3 has been determined and compared to related compounds. It has been found experimentally that Tl2O3 remains in its initial cubic bixbyite-type structure up to 22.0 GPa. At this pressure, the onset of amorphization is observed, being the sample fully amorphous at 25.2 GPa. The sample retains the amorphous state after pressure release. To understand the pressure-induced amorphization process, we h…
Getting insights into the behavior of variable speed direct expansion air conditioning systems under faulty operating conditions
2019
Direct expansion air conditioning systems, such as rooftop units, are widely adopted in small and medium scale commercial buildings. In order to increase the energy performance of these systems during part-load operation, variable-speed compressors and fans have been adopted in the last two decades. However, profitable energy saving could be achieved not only by optimizing the design and the control of these systems, but also by scheduling a proper maintenance strategy. In fact, if not properly maintained, no benefits would be achieved even when more sophisticated systems are adopted. In order to support plant owners in scheduling cost-effective maintenance program, Fault Detection and Diag…
SETUP OF VIRTUAL EXPERIMENTS AND CRITICAL ANALYSIS OF CONVENTIONAL THERMOECONOMIC DIAGNOSIS OF MULTIPLE FAULTS IN AIR-CONDENSED ROOFTOP SYSTEMS
2012
The diagnosis of soft faults in vapor compression cooling systems is a crucial activity, since malfunctions may provoke heavy degradation in plant performance and increase the power consumption for space cooling. Among the various Faults Detection and Diagnosis techniques developed over the last two decades, thermoeconomic diagnosis has been playing only a marginal role due to the difficulties encountered when applying the conventional thermoeconomic approaches to vapor compression refrigeration plants. In this paper a critical analysis on capabilities and limits of thermoeconomic diagnosis of refrigeration systems is proposed. The reference plant assumed for this study is a 116 kWc air-con…
Performance maps for an air-cooled air conditioning system as a preliminary instrument for the diagnosis of evaporator fouling
2019
Abstract During the past few decades, there has been increased interest in the development of automated approaches for detecting and diagnosing faults in air conditioning systems. Among them, thermoeconomic diagnosis is a technique which involves the use of exergy analysis. As a first step towards improving its performance, this work is focused on the thermodynamic and exergy analysis of a direct expansion air conditioning system used in small commercial building applications. The analysis was carried out by means of experimental activities on a 17.5 kW rooftop unit installed at the Herrick Laboratories, Purdue University, Indiana (USA). The system under investigation was equipped with a va…
Exergy analysis and thermoeconomic cost accounting of a Combined Heat and Power steam cycle integrated with a Multi Effect Distillation-Thermal Vapou…
2017
Abstract In this paper an exergy analysis and thermoeconomic cost accounting of a Combined Heat and Power steam cycle integrated with Multi Effect Distillation-Thermal Vapour Compression plant is performed; the goal of the study is to show how these methodologies provide a rational criterion to allocate production costs on electricity and freshwater in such a dual purpose system. After a brief overview on the methodology and a description of reference plant, exergy analysis is carried out to calculate exergy flows and exergy efficiencies at component level. A detailed description of the adopted thermoeconomic model is given. In a first scenario, cost accounting is performed assuming that th…
Thermodynamic, Exergy, and Thermoeconomic analysis of Multiple Effect Distillation Processes
2018
Abstract Multiple effect distillation (MED) is nowadays the preferred technology for the construction of new plants based on thermal processes in the growing desalination market. MED technology, in fact, presents a number of advantages with respect to the more traditional multistage flash technology, among all the lower energy consumption achievable in MED plants. However, a large potential for improvement in terms of lowering production costs still exists, which stimulates further efforts on process optimization from companies and researchers involved in the field. Thermodynamic and exergy analysis provides useful insights regarding the identification of main inefficiencies and the margins…
On numerical simulation of electromagnetic field effects in the combustion process
2018
This paper deals with a simplified model taking into account the interplay of compressible, laminar, axisymmetric flow and the electrodynamical effects due to Lorentz force’s action on the combustion process in a cylindrical pipe. The combustion process with Arrhenius kinetics is modelled by a single step exothermic chemical reaction of fuel and oxidant. We analyze non-stationary PDEs with 6 unknown functions: the 3 components of velocity, density, concentration of fuel and temperature. For pressure the ideal gas law is used. For the inviscid flow approximation ADI method is used. Some numerical results are presented.