Search results for "Compres"
showing 10 items of 1107 documents
Bending or buckling: Compression-induced phase transition in a semi-flexible polymer brush
2013
Molecular-dynamics simulations are presented for systems of densely grafted semiflexible macromolecules grafted to a planar non-adsorbing substrate, studying the case where the persistence length of the polymers is of the same order as their contour length so that the polymer brush may exhibit nematic order. We focus our attention on the case where the first bond must orient perpendicularly to the substrate (so the structure resembles a "Fakir's bed" for short chains and a "polymer bristle" for longer chains). When such layers are exposed to uniform compression, the pressure vs. distance relationship exhibits two stages: i) for very small compression the chains exhibit "buckling" yet mainta…
Der Einflu� einer ven�sen Stauung im Kopfbereich auf die Wasser- und Elektrolytausscheidung von Ratten
1960
1. Salt and water retention can be produced in rats by compression in the neck region or by ligature of the jugular veins.
Medidas de Tromboprofilaxis en Artroplastia Total de Rodilla. Práctica habitual en la Comunidad Valenciana y revisión bibliográfica.
2020
espanolAntecedentes: El tromboembolismo es una complicacion de la cirugia de artroplastia total de rodilla. Para su prevencion disponemos de multiples medidas fisicas y farmacologicas.Objetivo:Conocer quemedidas de prevencion tromboembolica son las empleadas por los cirujanos ortopedicos en cirugia protesica de rodilla primaria en diferentes centros hospitalarios de nuestra region.Metodo: Estudio transversal descriptivo observacional basado en encuesta dirigida a especialistas COT de 9 hospitales publicos de la Comunidad Valenciana y busqueda bibliografica.Resultados: Se obtuvieron 64 encuestas. Todos los cirujanos eligen HBPM durante un mes como medida de tromboprofilaxis, descartando anti…
Characterization and Decomposition of the Natural van der Waals SnSb2Te4 under Compression
2020
[EN] High pressure X-ray diffraction, Raman scattering, and electrical measurements, together with theoretical calculations, which include the analysis of the topological electron density and electronic localization function, evidence the presence of an isostructural phase transition around 2 GPa, a Fermi resonance around 3.5 GPa, and a pressure-induced decomposition of SnSb2Te4 into the high-pressure phases of its parent binary compounds (alpha-Sb2Te3 and SnTe) above 7 GPa. The internal polyhedral compressibility, the behavior of the Raman-active modes, the electrical behavior, and the nature of its different bonds under compression have been discussed and compared with their parent binary…
Experimental and theoretical study of dense YBO3 and the influence of non-hydrostaticity.
2021
[EN] YBO3 is used in photonics applications as a host for red phosphors due to its desirable chemical stability, high quantum efficiency and luminescence intensity. Despite its fundamental thermodynamic nature, the isothermal bulk modulus of YBO3 has remained a contentious issue due to a lack of comprehensive experimental and theoretical data and its vibrational modes are far from being understood. Here, we present an experimental-theoretical structural and vibrational study of YBO3. From structural data obtained from synchrotron X-ray diffraction data and ab initio calculations, we have determined the YBO3 bulk modulus, isothermal compressibility tensor and pressure-volume (P-V) equation o…
Comment on “Molybdenum sound velocity and shear modulus softening under shock compression”
2015
In this Comment we discuss recent results presented by Nguyen et al. on shock compressed molybdenum up to 438 GPa [Phys. Rev. B 89, 174109 (2014)]. The aim of Nguyen's article is to show that there is no phase transition near 210 GPa. We propose instead an interpretation of their data that this material shows the onset of partial melting along the Hugoniot at $240(20)\phantom{\rule{0.28em}{0ex}}\mathrm{GPa}$, which is evident from abrupt changes in the pressure dependence of the shear modulus. This interpretation may solve the significant controversy in the melting slopes derived from shock and static experiments.
Optical measurements of an acylated azacrown at the air-water interface
1991
In this study, a cyclame derivative bearing four aliphatic chain substituents shows, like many amphiphiles, solid-condensed as well as liquid-expanded phases. In contrast to the classical amphiphiles, the onset of its phase transition is characterized by a bump-like shape whose amplitude is a function of the compression speed. Ellipsometry which is very sensitive to the monolayer physical state changes, and fluorescence microscopy which has contributed significantly to the understanding of the phenomena occurring in the phase transition region have been used to investigate the monolayer behavior of this compound. This study shows that in the liquid-expanded state, the film is homogeneous an…
Experimental and Theoretical Investigations on Structural and Vibrational Properties of Melilite-Type Sr2ZnGe2O7 at High Pressure and Delineation of …
2015
We report a combined experimental and theoretical study of melilite-type germanate, Sr2ZnGe2O7, under compression. In situ high-pressure X-ray diffraction and Raman scattering measurements up to 22 GPa were complemented with first-principles theoretical calculations of structural and lattice dynamics properties. Our experiments show that the tetragonal structure of Sr2ZnGe2O7 at ambient conditions transforms reversibly to a monoclinic phase above 12.2 Gpa with similar to 1% volume drop at the phase transition pressure. Density functional calculations indicate the transition pressure at, similar to 13 GPa, which agrees well with the experimental value. The structure of the high-pressure mono…
Exploring the high-pressure behavior of the three known polymorphs of BiPO4: Discovery of a new polymorph
2015
We have studied the structural behavior of bismuth phosphate under compression. We performed x-ray powder diffraction measurements up to 31.5 GPa and ab initio calculations. Experiments were carried out on different polymorphs: trigonal (phase I) and monoclinic (phases II and III). Phases I and III, at low pressure (P < 0.2-0.8 GPa), transform into phase II, which has a monazite-type structure. At room temperature, this polymorph is stable up to 31.5 GPa. Calculations support these findings and predict the occurrence of an additional transition from the monoclinic monazite-type to a tetragonal scheelite-type structure (phase IV). This transition was experimentally found after the simultaneo…
Experimental and Theoretical Study of SbPO 4 under Compression
2019
SbPO4 is a complex monoclinic layered material characterized by a strong activity of the non-bonding lone electron pair (LEP) of Sb. The strong cation LEP leads to the formation of layers piled up along the a-axis and linked by weak Sb-O electrostatic interactions. In fact, Sb is 4-fold coordination with O similar to what occurs with the P-O coordination, despite the large difference of ionic radii and electronegativity between both elements. Here we report a joint experimental and theoretical study of the structural and vibrational properties of SbPO4 at high pressure. We show that SbPO4 is not only one of the most compressible phosphates but also one of the most compressible compounds of …