Search results for "Computation"
showing 10 items of 7362 documents
A Bidirectional IPT system for Electrical Bicycle Contactless Energy Transfer
2019
Contactless Energy Transfer characterized by Inductive Power Transfer (IPT) is a viable solution for Electric Vehicle (EV) battery charging, giving advantages in terms of safety, comfort and automatism of the recharging operation. IPT is a smart option for the Vehicle- To-Grid (V2G) implementation as well: the EV's battery can provide power to other users, if possible and if required, in order to adequately respond to an active demand scenario. IPT shall therefore allow a Bidirectional power flow, so that it can be properly defined as Bidirectional IPT (BIPT). In this paper, a 300 W BIPT system for E-bikes is proposed and experimental results are shown as well. Considering power level and s…
Low-complexity AoA and AoD Estimation in the Transformed Spatial Domain for Millimeter Wave MIMO Channels
2021
High-accuracy angle of arrival (AoA) and angle of departure (AoD) estimation is critical for cell search, stable communications and positioning in millimeter wave (mmWave) cellular systems. Moreover, the design of low-complexity AoA/AoD estimation algorithms is also of major importance in the deployment of practical systems to enable a fast and resource-efficient computation of beamforming weights. Parametric mmWave channel estimation allows to describe the channel matrix as a combination of direction-dependent signal paths, exploiting the sparse characteristics of mmWave channels. In this context, a fast Transformed Spatial Domain Channel Estimation (TSDCE) algorithm was recently proposed …
Corrigendum to “Bipolar disorder: An evolutionary psychoneuroimmunological approach”
2021
Double precision errors in the logistic map: statistical study and dynamical interpretation.
2007
The nature of the round-off errors that occur in the usual double precision computation of the logistic map is studied in detail. Different iterative regimes from the whole panoply of behaviors exhibited in the bifurcation diagram are examined, histograms of errors in trajectories given, and for the case of fully developed chaos an explicit formula is found. It is shown that the statistics of the largest double precision error as a function of the map parameter is characterized by jumps whose location is determined by certain boundary crossings in the bifurcation diagram. Both jumps and locations seem to present geometric convergence characterized by the two first Feigenbaum constants. Even…
Counter-complementarity control of the weak exchange interaction in a bent {Ni(ii)3 complex with a μ-phenoxide-μ-carboxylate double bridge
2019
We have prepared and structurally characterized a novel {Ni3} bent complex bearing a double μ-phenoxide-μ-carboxylate bridge. Both terminal Ni(ii) sites are symmetry related, offering a simplified exchange interaction scheme. DC magnetic data is consistent with a weak antiferromagnetic interaction between the central and terminal Ni(ii) ions. As expected for a Ni(ii) system, local zero-field splitting is observed, which can be experimentally established. Broken symmetry quantum chemical calculations, as well as ab initio CASSCF-SA-SOC computations that support the magnetic experimental data, were also performed. From the analysis of other reported closely related Ni(ii) systems, a counter-c…
Kinetics of the Strain-Promoted Oxidation-Controlled Cycloalkyne-1,2-quinone Cycloaddition: Experimental and Theoretical Studies
2018
Stimulated by its success in both bioconjugation and surface modification, we studied the strain-promoted oxidation-controlled cycloalkyne–1,2-quinone cycloaddition (SPOCQ) in three ways. First, the second-order rate constants and activation parameters (ΔH⧧) were determined of various cyclooctynes reacting with 4-tert-butyl-1,2-quinone in a SPOCQ reaction, yielding values for ΔH⧧ of 4.5, 7.3, and 12.1 kcal/mol, for bicyclo[6.1.0]non-4-yne (BCN), cyclooctyne (OCT), and dibenzoazacyclooctyne (DIBAC), respectively. Second, their reaction paths were investigated in detail by a range of quantum mechanical calculations. Single-configuration theoretical methods, like various DFT and a range of MP2…
Arynic species; effect of substituents on the reactivity of monosubstituted dehydrobenzenes
1986
Abstract Evidence is presented demonstrating the existence of free dehydrobenzenes in the thermal decomposition of diaryliodonium-2-carboxylates, and that o-benzyne itself and its 4-methyl-, 4-chloro-,4-bromo- and 4-nitro-derivatives are generated from insoluble polymer-bound precursors and trapped by a second solid phase in Diels-Alder reactions. Lifetimes for these elusive species are determined.
Formation of Pyrazol-1,3,4-Thiadiazoles through 1,3-Dipolar Cycloadditions of 3-Thioxo-[1,2,4]-Triazepin-5-one with Nitrilimines: An Experimental and…
2009
In this work the results of experimental and computational study of the title compounds and some ancillary compounds are reported. Two bicyclic pyrazol-1,3,4-thiadiazole derivatives were synthesized by reaction between 6-dimethylaminomethylene-3-thioxo-[1,2,4]- triazepin-5-one 1 and several nitrilimines 2a-f to give corresponding spirocycloadducts 3a-f, which undergo a rapid rearrangement leading to the new bicyclic compounds, 4a-f and 5a-f. These obtained bicyclic products were characterized by 1H and 13C NMR spectroscopy and finally by X-ray crystallography. Theoretical calculations have been carried out using DFT methods to rationalize the formation of the two new bicyclic compounds. Two…
Uncertainty on w from large-scale structure
2012
We find that if we live at the center of an inhomogeneity with total density contrast of roughly 0.1, dark energy is not a cosmological constant at 95% confidence level. Observational constraints on the equation of state of dark energy, w, depend strongly on the local matter density around the observer. We model the local inhomogeneity with an exact spherically symmetric solution which features a pressureless matter component and a dark-energy fluid with constant equation of state and negligible sound speed, that reaches a homogeneous solution at finite radius. We fit this model to observations of the local expansion rate, distant supernovae and the cosmic microwave background. We conclude …
Big Data Processing in the ATLAS Experiment: Use Cases and Experience
2015
Abstract The physics goals of the next Large Hadron Collider run include high precision tests of the Standard Model and searches for new physics. These goals require detailed comparison of data with computational models simulating the expected data behavior. To highlight the role which modeling and simulation plays in future scientific discovery, we report on use cases and experience with a unified system built to process both real and simulated data of growing volume and variety.