Search results for "Condensed Matter::Strongly Correlated Electrons"
showing 10 items of 888 documents
Atomistic Theory of the Growth Mode for a Thin Metallic Film on an Isulating Substrate
2002
We have developed a novel theory for predicting the growth mode of a thin metallic film on an insulating substrate. Our theory combines ab initio electronic structure calculations for several ordered metal/insulator interfaces with varying metal coverage, with a thermodynamic method known in the theory of alloys. We illustrate this approach for an Ag film deposited on a MgO(001) substrate. Ab initio Hartree-Fock calculations predict a high mobility of adsorbed silver atoms on the perfect magnesia surface even at low temperatures. Our theoretical analysis clearly demonstrates that the growth of metal islands is predominant at the initial stage of silver deposition on MgO, which agrees with t…
Theoretical and experimental developments in quantum spin liquid in geometrically frustrated magnets: a review
2019
The exotic substances have exotic properties. One class of such substances is geometrically frustrated magnets, where correlated spins reside in the sites of triangular or kagome lattice. In some cases, such magnet would not have long-range magnetic order. Rather, its spins tend to form kind of pairs, called valence bonds. At $$T \rightarrow 0$$ these highly entangled quantum objects condense in the form of a liquid, called quantum spin liquid (QSL). The observation of a gapless QSL in actual materials is of fundamental significance both theoretically and technologically, as it could open a path to creation of topologically protected states for quantum information processing and computation…
Half-metallic compensated ferrimagnetism with a tunable compensation point over a wide temperature range in the Mn-Fe-V-Al Heusler system
2017
The cubic Heusler compound Mn1.5FeV0.5Al with the L21 Heusler structure is the first fully compensated half-metallic ferrimagnet with 24 valence electrons. The ferrimagnetic state can be tuned by changing the composition such that the compensation point appears at finite temperatures ranging from 0 K up to 226 K, while retaining half-metallicity in the system. In this paper, the structural, magnetic and transport properties of the Mn-Fe-V-Al system are discussed. Magnetic reversal and a change of sign of the anomalous Hall effect were observed at the compensation point, which gives rise to a sublattice spin-crossing. These materials present new possibilities for potential spintronic devices…
Emergence of a metallic metastable phase induced by electrical current in Ca2RuO4
2019
A comprehensive study of the behavior of the Mott insulator ${\mathrm{Ca}}_{2}{\mathrm{RuO}}_{4}$ under electrical current drive is performed by combining two experimental probes: the macroscopic electrical transport and the microscopic x-ray diffraction. The resistivity, $\ensuremath{\rho}$, versus electric current density, $J$, and temperature, $T,\ensuremath{\rho}(J,T)$, resistivity map is drawn. In particular, the metastable state, induced between the insulating and the metallic thermodynamic states by current biasing ${\mathrm{Ca}}_{2}{\mathrm{RuO}}_{4}$ single crystals, is investigated. Such an analysis, combined with the study of the resulting ${\mathrm{RuO}}_{6}$ octahedra energy le…
A first peek into sub-picosecond dynamics of spin energy levels in magnetic biomolecules
2019
We estimate the time- and temperature-evolution of spin energy levels in a metallopeptide by combining molecular dynamics with crystal field analysis. Fluctuations of tens of cm-1 for spin energy levels at fs times gradually average out at longer times. We confirm that local vibrations are key in spin dynamics.
Electronic Properties of Point Defects in Metals
1982
Recent progress in electronic structure and related properties of point defects in metals is reviewed. Topics discussed include transition metal impurities in a non-magnetic host, construction of potential energy surfaces from effective-medium theories, trapping of light interstitials, and pair potential in metals.
Symmetry of valence states of Heusler compounds explored by linear dichroism in hard-x-ray photoelectron spectroscopy.
2011
This study reports on the linear dichroism in angular-resolved photoemission from the valence band of the Heusler compounds ${\mathrm{NiTi}}_{0.9}{\mathrm{Sc}}_{0.1}\mathrm{Sn}$ and NiMnSb. High-resolution photoelectron spectroscopy was performed with an excitation energy of $h\ensuremath{\nu}=7.938\text{ }\text{ }\mathrm{keV}$. The linear polarization of the photons was changed using an in-vacuum diamond phase retarder. The valence band spectra exhibit the typical structure expected from first-principles calculations of the electronic structure of these compounds. Noticeable linear dichroism is found in the valence band of both materials, and this allows for a symmetry analysis of the cont…
Phonon Softening and Electron-Phonon Interaction in YBa2Cu3O7−δ
1993
We report on the Raman scattering investigation of the 335 cm−1 phonon of Ag (pseudo-B1g) symmetry in thin YBa2Cu3O7−δfilms on various substrates. The experiments yield values for the phonon softening below Tc, which differ from sample to sample. We find a linear relation between the softening and the inverse asymmetry parameter of the phonon Fano-like lineshape, when these parameters, obtained from different samples, are compared with each other. In contrast to this, the onset temperatures for the softening are the same for these samples.
Luminescence of ferroelectric crystals: LiNbO3and KNbO3
2000
Abstract The thermostimulated luminescence and time-resolved luminescence of LiNbO3 (congruent, stoichiometric, Eu−, Mn−, or Cr−doped) and KNbO3 crystals (undoped, Fe−, or Mn− doped) excited by X-ray, pulsed nitrogen laser or pulsed electron beam were studied. The luminescence decay times of niobium-oxygen groups (regular or perturbed by defect or impurity) were obtained. It is shown that the energy transfer from bulk to the activator in LiNbO3 is not effective during the electron-hole recombination process.
Electroswitching of the single-molecule magnet behaviour in an octahedral spin crossover cobalt(ii) complex with a redox-active pyridinediimine ligand
2020
Thermal-assisted spin crossover and field-induced slow magnetic relaxation coexist in the solid state for the mononuclear cobalt(II) complex with the non-innocent 2,6-bis(N-4-methoxyphenylformimidoyl)pyridine ligand. One-electron oxidation of the paramagnetic low-spin CoII ion (SCo = 1/2) to the diamagnetic low-spin CoIII ion (SCo = 0) leads to the electroswitching of the slow magnetic relaxation in acetonitrile solution.