Search results for "Confine"
showing 10 items of 285 documents
Structure and dynamics of water confined in silica hydrogels: X-ray scattering and dielectric spectroscopy studies.
2003
We have used a sol-gel technique to obtain optically transparent hydrogels in which water is confined within a 3D silica matrix. In this work we report X-ray scattering and dielectric spectroscopy measurements on samples having different aging times and compare them with previously obtained results with near-infrared (NIR) absorption spectroscopy. X-ray scattering at room temperature enables to characterize the structure and size of the matrix pores and the non-uniform distribution of water inside the hydrogel. Broad band dielectric spectroscopy in the temperature range 130-280 K enables to study water dynamics. In aged hydrogels two relaxations are clearly evident and show characteristic t…
Synthesis of yttrium aluminum garnet nanoparticles in confined environment III: Cerium doping effect
2018
Abstract Cerium yttrium aluminum garnet (Ce:YAG, CexY3-xAl5O12) nanoparticles doped with different cerium amount were obtained by calcining the precursors synthesized via co-precipitation in w/o microemulsion for 1 h at 900 °C. The structural and morphological properties were investigated by using X-ray Diffraction (XRD), Infrared Spectroscopy (IR) and Transmission Electron Microscopy (TEM) coupled with Energy Dispersive X-ray Spectroscopy (EDS) in order to investigate the effect of doping level on formation and microstructure of obtained nanoparticles. It was found that the composition of the final products strongly depends on the concentration of cerium. The formation of single YAG phase …
Compressive behavior of FRP externally wrapped R.C. column with buckling effects of longitudinal bars
2018
Abstract In this paper, a calculation model to simulate the compressive behavior of R.C. columns with square cross-sections externally wrapped with FRP, including buckling effects of the longitudinal bars and reduction of the confinement pressure induced by the buckled compressed bars, is presented and discussed. The model distinguishes the cases of corner and side bars, calculating the different critical lengths and the critical loads. The Teng et al. (2009) model was adopted to predict the compressive behavior of FRP-confined concrete, and the Dhakal and Maekawa (2002) model was taken into account to predict the compressive behavior of longitudinal bars. The critical length and critical s…
Moment-axial force domain of corroded R.C. columns
2016
In the present paper, a simple model to determine the moment-axial force domain of the cross-section of reinforced concrete (R.C.) columns subjected to corrosion process is presented. The model considers members with square and rectangular cross-sections and it accounts for—cover spalling; buckling of longitudinal reinforcing bars; loss of bond of bar in tension; reduction of confinement pressures (due to the reduction of the area of stirrups and cracking of concrete induced by rust formation). The analytical expressions for prediction of the area reduction of steel, bond strength and critical load of longitudinal bars utilized were verified against experimental data available in the litera…
Masonry columns confined with fabric reinforced cementitious matrix (FRCM) systems: A round robin test
2021
Abstract The conservation and the preservation of existing masonry buildings, most of them recognized as cultural heritage, require retrofitting techniques that should reduce the invasiveness and assure reversibility and compatibility with the substrate. In this perspective, the strengthening system should be able to improve the bearing capacity of the structural member and, at the same time, to assure mechanical and material compatibility. The use of Fabric Reinforced Cementitious Matrix (FRCM) composites is now recognized to be suitable for these purposes. Indeed, the inorganic matrix has comparable properties with respect to the existing historical mortars while the fabric has relevant t…
Behavior of fiber-reinforced concrete columns under axially and eccentrically compressive loads
2010
An experimental investigation into the behavior of 16 short, confined, reinforced concrete columns with and without steel fibers was carried out. The columns with square sections had a concrete core 165 x 165 mm (6.49 x 6.49 in.) at the midsection and were hunched at the ends to apply eccentric loading and prevent boundary effects. The specimens were tested to failure at different strain rates under two loading schemes: concentric compression and eccentric compression with a constant eccentricity. The axial load and axial strains were obtained to evaluate the effects of the presence of steel fibers, the thickness of the cover concrete, and the eccentricity of the applied axial load. The com…
A strategy for the finite element modeling of FRP-confined concrete columns subjected to preload
2018
Abstract Compressive behavior of columns strengthened by means of an outer elastic confinement provided e.g. by fiber-reinforced polymer (FRP) jackets has become a main topic in the field of structural retrofitting. In details, the problem of the response assessment of strengthened columns is still under study. Many analytical formulations have been proposed to describe the compressive behavior of confined concrete under both monotonic and cyclic loads. However, the effect of a stress/strain level in the columns already present prior to apply the confinement has been generally neglected until now, also because of the lack of well defined strategies of modeling. In this frame, here, (1) a FE…
Analytical stress-strain law of FRP confined masonry in compression: Literature review and design provisions
2017
Abstract The use of Fibre Reinforced Polymer (FRP) wraps has become common in practical applications to retrofit existing columns with poor structural features. Wrapping the member with one or more FRP sheets makes it possible to induce confinement action and enhance strength and ductility. This application has been widely studied and adopted in reinforced concrete members for about twenty years, while its suitability to masonry columns and piers has been investigated during the last decade. The results of several studies were summarized in different design expressions for calculating effective confinement pressure, ultimate compressive stress and strain, and the overall trend of the stress…
Time evolution of size and polydispersity of an ensemble of nanoparticles growing in the confined space of AOT reversed micelles by computer simulati…
2005
The time dependence of size and polydispersity of an ensemble of nanoparticles growing in the confined space of water-containing AOT reversed micelles has been investigated by computer simulations. It has been found that, in a wide time range, the mean nanoparticle size can be described by power laws whose exponent is critically dependent on the efficiency of the intermicellar material exchange process while the nanoparticle polydispersity increases with time. From the analysis of all the disentangled effects arising from the variation of internal and external parameters provided by simulations, useful suggestions for a better and rationale control of the nanoparticle synthetic procedure ar…
Discontinuous FRP-Confinement of Masonry Columns
2020
Recent seismic events, all over the world, demonstrated that masonry constructions are prone to brittle collapses when shear or compression capacity is reached. It is clear that, in many real cases, masonry columns need to be strengthened for enhancing their load-carrying capacity and to develop a more ductile response. The Fiber Reinforced Polymers (FRPs) confinement of masonry columns is a well-known technique that may produce these advantages. Unfortunately, full-wrapping insulates the column from the environment; so interstitial humidity can easily occur and cause the acceleration of the masonry's decay. In order to prevent it, partial-confinement is commonly assessed instead of total-j…