Search results for "Continuum"
showing 10 items of 477 documents
Supercontinuum generation with 532 nm quasi-continuum pulses in photonic crystal fibre tapers
2007
We report experimental results on supercontinuum generation in PCF tapers using quasi-continuous pump pulses of 7 ns duration at 532 nm. SC generation in normal and anomalous dispersion regimes are presented. Introduction Supercontinuum generation (SC) in photonic crystal fibres (PCF), fibre tapers, and PCF tapers has been demonstrated in the past with pump pulses of fs, ps, and tenths of ns duration [1-2]. Here, we present experimental results on SC generation in PCF tapers using quasi-continuous pump pulses of 7 ns duration at 532 nm. Fabrication of the PCF tapers The PCF from which the tapers were made, was a large-air-hole PCF ("cobweb" PCF) with two rings of air holes around a solid si…
White light supercontinuum generation in a Y-shaped microstructured tapered fiber pumped at 1064 nm.
2010
We report the generation of supercontinuum in a Ge-doped Y-shape tapered fiber pumped at 1064 nm in the ns pump regime. The taper was designed to have long taper transitions and a taper waist with a core diameter of 0.9 mum. The large air-filling fraction and diameter of the air-hole microstructure reduces the confinement loss at long wavelengths so, enabling the extension of the spectrum to longer wavelengths. Along the taper transition the zero-dispersion wavelength decreases as the diameter of the taper becomes smaller. The spectral components generated along the taper transition pump the taper waist, enhancing the generation of short wavelengths. A flat spectrum spanning from 420 nm to …
ELDAR, a new method to identify AGN in multi-filter surveys: the ALHAMBRA test case
2017
We present ELDAR, a new method that exploits the potential of medium- and narrow-band filter surveys to securely identify active galactic nuclei (AGN) and determine their redshifts. Our methodology improves on traditional approaches by looking for AGN emission lines expected to be identified against the continuum, thanks to the width of the filters. To assess its performance, we apply ELDAR to the data of the ALHAMBRA (Advance Large Homogeneous Area Medium Band Redshift Astronomical) survey, which covered an effective area of 2.38 deg2 with 20 contiguous medium-band optical filters down to F814W ≃ 24.5. Using two different configurations of ELDAR in which we require the detection of at lea…
A simple scheme for the direct calculation of ionization potentials with coupled-cluster theory that exploits established excitation energy methods
1999
Vertical ionization potentials can be obtained from existing computer programs for the high-level treatment of excited states by simply including a continuum orbital in the basis set. Exploiting this feature easily allows final state energies for ionized states to be calculated at several previously untested levels of theory that go beyond the equation-of-motion coupled-cluster singles and doubles model. Values obtained for N2, CO, and F2 with the most theoretically complete approximations studied here (those based on the CCSDT-3 and CC3 parametrizations of the neutral ground state) are in excellent agreement with experiment when a large basis set is used.
Death and Rebirth: Images of Death in Sicily
2015
Photographs were often taken during funerary ceremonies in Sicily. Local photographers were commissioned to document funerals as if they were christenings, communions or wedding ceremonies; and it is no mere coincidence that in funeral portraits the relatives arranged around the coffin assumed postures similar to those seen in photos of festivities. This tradition of taking photos during such “mixed occasions” gives the images a profound significance and highlights the archaic roots of the popular ideology of death as a continuum of life.
The domino reaction between 4,6-dinitrobenzofuroxan and cyclopentadiene. Insights on the nature of the molecular mechanism
2004
Abstract The molecular mechanism of the domino reaction between 4,6-dinitrobenzofuroxan, 1 , and cyclopentadiene, Cp, to give the adduct 11 is examined through density functional theory (DFT) calculations at B3LYP/6-31G* level. This domino reaction comprises two consecutive formally [4+2] cycloadditions. The first one is a two-center addition initialized by the nucleophilic attack of Cp to the more electrophilic center of 1 . The subsequent cyclization can take place along two competitive channels associated to the formation of a second C–C bond yielding the formally [2+4] cycloadduct 9 , or a C–O bond yielding the formally [4+2] cycloadduct 10 . The second cycloaddition is a stepwise proce…
Upper bounds for the tightness of the $$G_\delta $$-topology
2021
We prove that if X is a regular space with no uncountable free sequences, then the tightness of its $$G_\delta $$ topology is at most the continuum and if X is, in addition, assumed to be Lindelof then its $$G_\delta $$ topology contains no free sequences of length larger then the continuum. We also show that, surprisingly, the higher cardinal generalization of our theorem does not hold, by constructing a regular space with no free sequences of length larger than $$\omega _1$$ , but whose $$G_\delta $$ topology can have arbitrarily large tightness.
Ligand dynamics of tert-butyl isocyanide oxido complexes of molybdenum(IV).
2014
The six-coordinate molybdenum(IV) oxido isocyanide complex 1 [Δ,Λ-OC-6-2-3-[MoO(N(p)∩N(i))2(CN(t)Bu)]; N(p)∩N(i) = 4-tert-butylphenyl(pyrrolato-2-ylmethylene)amine] is obtained in diastereomerically pure form in the solid state, as revealed by single-crystal X-ray diffraction. In solution, this stereoisomer equilibrates with the Δ,Λ-OC-6-2-4 diastereomer 2 at ambient temperature. The stereochemistry of both isomers has been elucidated by NMR, IR, and UV/vis spectroscopy in combination with density functional theory (DFT)/polarizable continuum model and time-dependent DFT calculations. The isomerization 1 → 2 is suggested to proceed via a dissociative trigonal twist with dissociation of the …
A note on rank 2 diagonals
2020
<p>We solve two questions regarding spaces with a (G<sub>δ</sub>)-diagonal of rank 2. One is a question of Basile, Bella and Ridderbos about weakly Lindelöf spaces with a G<sub>δ</sub>-diagonal of rank 2 and the other is a question of Arhangel’skii and Bella asking whether every space with a diagonal of rank 2 and cellularity continuum has cardinality at most continuum.</p>
Thermodynamic approach of supercontinuum generation
2009
International audience; This paper is aimed at providing an overview on recent theoretical and experimental works in which a thermodynamic description of the incoherent regime of supercontinuum generation has been formulated. On the basis of the wave turbulence theory, we show that this highly nonlinear and quasi-continuous-wave regime of supercontinuum generation is characterized by two different phenomena. (i) A process of optical wave thermalization ruled by the four-wave mixing effects: The spectral broadening inherent to supercontinuum generation is shown to result from the natural tendency of the optical field to reach its thermodynamic equilibrium state, i. e., the state of maximum n…