Search results for "Conversion"

The Effect of Electric Field Configuration on the Thermo-Chemical Conversion of Straw Pellets

2020

Abstract With the aim to control and improve the thermo-chemical conversion of straw pellets, the experimental investigations of the DC electric field effect on the combustion dynamics and heat energy production were made. The electric field effect on the gasification/combustion characteristics was studied using three different positions of the positively charged electrode in flame. First, the electrode was positioned coaxially downstream the flame flow. Next, the electrode was positioned coaxially upstream the flame flow and, finally, the electrode was positioned across the downstream flow. The bias voltage of the electrode varied in the range from 0.6 up to 1.8 kV, while the ion current i…

The Role Played by Ionic Liquids in Carbohydrates Conversion into 5-Hydroxymethylfurfural: A Recent Overview

2022

Obtaining industrially relevant products from abundant, cheap, renewable, and low-impacting sources such as lignocellulosic biomass, is a key step in reducing consumption of raw fossil materials and, consequently, the environmental footprint of such processes. In this regard, a molecule that is similar to 5-hydroxymethylfurfural (5-HMF) plays a pivotal role, since it can be produced from lignocellulosic biomass and gives synthetic access to a broad range of industrially important products and polymers. Recently, ionic liquids (ILs) have emerged as suitable solvents for the conversion of biomass and carbohydrates into 5-HMF. Herein, we provide a bird’s-eye view on recent achievements about t…

Desiderio, crudeltà e conversione nell’«Agnes» di Rosvita di Gandersheim

2015

In her last hagiographical poem, «Agnes», Hrotsvit of Gandersheim (935-973) elaborates in 459 rhymed hexameters a story already told in many hagiographical an hymnological texts, the story of young roman virgin Agnes (it was told by pope Damasus, Prudentius, Ambrosius, Beda, and the anonymous «Passio Agnetis»). The paper presents and analizes Hrotsvit’s «Agnes» in his literary, historical, hagiographical, religious components and particularly insists on the themes of “desire”, “cruelty”, “conversion” and “martyrdom” which occur in it.

Research on conversion of Carrizo citrange [C. sinensis (L.) Osb. × P. trifoliata (L.) Raf.] synthetic seeds.

2008

MISURE BASATE SULLA CONVERSIONE ANALOGICO-DIGITALE:IDENTIFICAZIONE DEI PARAMETRI PER LA VALUTAZIONE DELL’ INCERTEZZA

2009

Theoretical study of neutrino scattering off the stable even Mo isotopes at low and intermediate energies

2011

A systematic study of the cross sections of neutral-current neutrino scattering off the stable even Mo isotopes (mass number A = 92, 94, 96, 98, 100), at low and intermediate neutrino energies (E(nu) <= 130 MeV), is presented and discussed. The required wave functions for the initial (ground state) and all accessible final nuclear states are constructed in the context of the quasi-particle random-phase approximation (QRPA) and tested against data on the low-lying energy spectra of the isotopes in question. The individual contributions coming from the polar-vector and axial-vector components of the hadronic current for the coherent and incoherent channels of each isotope are investigated. Th…

Fe-doped Beta zeolite from organotemplate-free synthesis for NH3-SCR of NOx

2016

Two types of Beta zeolites, one from organotemplate-free synthesis with a Si/Al ratio of 9 and the other from a commercial one with a Si/Al ratio of 19, were employed here to dope Fe for NH3-SCR of NOx. Fe-Beta (Si/Al = 9) exhibits much higher activity than Fe-Beta (Si/Al = 19), especially at low-temperature regions (<250 °C). In addition, it also exhibits better hydrothermal stability as compared with Fe-Beta (Si/Al = 19), which demonstrates that it is a promising SCR catalyst with good activity as well as hydrothermal stability. The correlation between the quantitative calculation of the content of isolated Fe3+ in Beta zeolites and the NO conversion rate at 150 °C shows a linear relation…

Understanding the Stability and Recrystallization Behavior of Amorphous Zinc Phosphate

2021

Zinc phosphate, an important pigment in phosphate conversion coatings, forms protective films on rubbing surfaces. We have simulated the underlying reactions under shear by ball-milling zinc phosphate and monitored the reaction of hopeite (Zn3(PO4)2·4H2O) and the retarded recrystallization of the amorphous reaction product by powder X-ray diffraction (PXRD) and quantitative infrared (IR) spectroscopy. Abrasion of stainless steel was simulated by addition of pure 57Fe. The results provide insight into the chemistry of phosphate conversion coatings or during battery cycling of metal phosphates and give theoretical guidance for the preparation of amorphous phosphates. Thermal analysis revealed…

Ionic liquid binary mixtures: Promising reaction media for carbohydrate conversion into 5-hydroxymethylfurfural

2014

Abstract The conversion of carbohydrates into 5-hydroxymethylfurfural (5-HMF) has been studied in binary mixtures of ionic liquids (ILs), using strongly acidic resin Amberlyst 15 as the catalyst. In particular, both mono- and disaccharides, such as fructose, glucose and sucrose have been investigated. Considering the favorable effect exerted by chloride-based ionic liquids in the dissolution of carbohydrates, we used binary mixtures of 1-butyl-3-methylimidazolium chloride ([bmim][Cl]) with [bmim + ] based ionic liquids differing in size, shape and coordination ability of the anion ([bmim][BF 4 ], [bmim][N(CF 3 SO 2 ) 2 ], [bmim][N(CN) 2 ], [bmim][SbF 6 ] and [bmim][CF 3 SO 3 ]). Carbohydrat…

Ligand-Centred Fluorescence and Electronic Relaxation Cascade at Vibrational Time Scales in Transition-Metal Complexes

2015

Using femtosecond-resolved photoluminescence up-conversion, we report the observation of the fluorescence of the high-lying ligand-centered (LC) electronic state upon 266 nm excitation of an iridium complex, Ir(ppy)(3), with a lifetime of 70 +/- 10 fs. It is accompanied by a simultaneous emission of all lower-lying electronic states, except the lowest triplet metal-to-ligand charge-transfer ((MLCT)-M-3) state that shows a rise on the same time scale. Thus, we observe the departure, the intermediate steps, and the arrival of the relaxation cascade spanning similar to 1.6 eV from the (LC)-L-1 state to the lowest 3MLCT state, which then yields the long-lived luminescence of the molecule. This …