Search results for "Copolymer"

Quantum dot-block copolymer hybrids with improved properties and their application to quantum dot light-emitting devices.

2009

To combine the optical properties of CdSe@ZnS quantum dots (QDs) with the electrical properties of semiconducting polymers, we prepared QD/polymer hybrids by grafting a block copolymer (BCP) containing thiol-anchoring moieties (poly(para-methyl triphenylamine-b-cysteamine acrylamide)) onto the surfaces of QDs through the ligand exchange procedure. The prepared QD/polymer hybrids possess improved processability such as enhanced solubility in various organic solvents as well as the film formation properties along with the improved colloidal stability derived from the grafted polymer shells. We also demonstrated light-emitting diodes based on QD/polymer hybrids, exhibiting the improved device …

DNA Block Copolymer Micelles – A Combinatorial Tool for Cancer Nanotechnology

2008

Selective drug targeting of a specific organ or tissue is a challenging task. This holds especially true for chemotherapeutic cancer treatment because most of the available anticancer agents cannot distinguish between cancerous and healthy cells, leading to systemic toxicity and undesirable side effects. One effective approach to address this problem is the application of polymeric nanoparticles equipped with targeting units for tumor-specific delivery. For instance dendrimers, highly branched macromolecules, can be equipped with targeting units as well as with anticancer drugs because of their large number of surface functionalities. Amphiphilic block copolymers, which self-assemble in dil…

Switchable surface structured hydrogel coatings

2017

Switchable surface structures based on hydrogels are an emerging field in material science, microfluidics, soft robotics and anti-fouling. Here, we describe a novel method that uses a photo-cross-linkable terpolymer to create a hydrogel coating with a switchable surface structure. The terpolymer is based on poly(N-isopropylacrylamide) (PNIPAm) and it is shown that simple coating technologies like slit die coating can be used under ambient conditions. It is also shown that the swelling ratio of the coating is controlled by the energy dose of ultraviolet (UV) light. Simple and complex surface structures were created using respectively single or multiple UV illumination steps through masks and…

High molecular arborescent polyoxyethylene with hydroxyl containing shell

2004

Abstract Arborescent polyoxyethylene of high molar mass (2×10 5  g/mol) and narrow molar mass distribution was synthesized in a three-stage process. In the first stage a triblock copolymer of ethylene oxide (central block, DP ca. 90) and 2,3-epoxypropanol-1 (short flanking blocks, DP ca. 5) was synthesized. The potassium alcoholate derived from this copolymer was used to initiate the polymerization of ethylene oxide and the subsequent addition of protected glycidol (1-etoxyethyl glycidyl ether). After deprotection the short polyglycidol blocks were used as branching units for the next generation. Repeated step by step process leads to the ‘pom-pom like’ branched polyoxyethylene macromolecul…

One-Step Anionic Copolymerization Enables Formation of Linear Ultrahigh-Molecular-Weight Block Copolymer Films Featuring Vivid Structural Colors in t…

2018

Ultrahigh-molecular-weight (UHMW) tapered block copolymers (BCPs) consisting of polyisoprene-block-poly(4-methylstyrene) featuring overall molar masses in the range of 1101–2033 kg mol–1 (Mw) are synthesized via a convenient one-step anionic copolymerization protocol. The obtained UHMW BCPs are investigated by differential scanning calorimetry, size exclusion chromatography, and 1H NMR spectroscopy. Microphase separation for the UHMW BCPs in the bulk state is investigated by transmission electron microscopy (TEM) measurements and scanning electron microscopy (SEM), revealing well-ordered lamellar and spherical domains with large domain sizes in the range of 100–200 nm. Excellent order and p…

Splitting of Surface-Immobilized Multicompartment Micelles into Clusters upon Charge Inversion

2016

International audience; We investigate a morphological transition of surface-immobilized triblock terpolymer micelles: the splitting into well-defined clusters of satellite micelles upon pH changes. The multicompartment micelles are formed in aqueous solution of ABC triblock terpolymers consisting of a hydrophobic polybutadiene block, a weak polyanionic poly(methacrylic acid) block, and a weak polycationic poly(2-(dimethylamino)ethyl methacrylate) block. They are subsequently immobilized on silicon wafer surfaces by dip-coating. The splitting process is triggered by a pH change to strongly basic pH, which goes along with a charge reversal of the micelles. We find that the aggregation number…

Cylindrical morphologies in asymmetric ABC triblock copolymers

1997

In asymmetric ABC triblock copolymers with C being the matrix-forming majority component, the formation of cylindrical morphologies is governed by the sum of the volume fractions of the components A and B (Φ A + Φ B ) as well as by their ratio (Φ B /Φ A ). The paper describes the morphologies of various polystyrene-block-polybutadiene-block-poly(methyl methacrylate) (SBM) and polystyrene-block-poly(ethylene-co-butylene)-block-poly(methyl methacrylate) block copolymers (SEBM) in dependence on these parameters. In addition to previously reported cylinder in cylinder (c i c, core shell) and helical (hel) morphologies, new microphase separated structures as cylinders at cylinder (c a c), undula…

Building Bridges by Blending: Morphology and Mechanical Properties of Binary Tapered Diblock/Multiblock Copolymer Blends

2021

“Ball at the wall” — A new lamellar multiphase morphology in a polystyrene-block-polybutadiene-block-poly(methyl methacrylate) triblock copolymer

1994

Structural Characterization of the “Knitting Pattern” in Polystyrene-block-poly(ethylene-co-butylene)-block-poly(methyl methacrylate) Triblock Copoly…

1998

In a polystyrene-block-polybutadiene-block-poly(methyl methacrylate) triblock copolymer (SBM) a morphological transition from a lamellar (ll) morphology (with sequence ABCB) to the knitting pattern (kp) morphology occurs upon hydrogenation of the center PB block. Structural information of the nonhydrogenated and the hydrogenated material is provided from small angle X-ray scattering (SAXS) and transmission electron microscopy (TEM). For the nonhydrogenated SBM sample the SAXS profile correlates well with a simple periodic lamellar structure. The hydrogenated sample forming the kp morphology displays a more complex SAXS pattern. From the TEM images of the knitting pattern the two-dimensional…