Search results for "Copolymer"
showing 10 items of 1003 documents
Micromechanics of “raspberry” morphology in PPE/SAN polymer blends compatibilized with linear ABC triblock terpolymers
2015
Abstract The effect of compatibilization with a symmetrical polystyrene- block -polybutadiene- block -poly(methyl methacrylate) (SBM) triblock terpolymer on the morphological and mechanical properties (specifically toughness) of immiscible poly(2,6-dimethyl-1,4-phenylene ether)/poly(styrene- co -acrylonitrile) (PPE/SAN) blends with different blend (w/w) ratios is investigated. We study the effect of blend viscosity on the localization of the compatibilizer at the blend interface, influencing the mechanical properties of the macroscopic material. The impact of the specific morphology of the blends, known as “raspberry morphology”, on the final material will be explained using thermomechanica…
Tapered Multiblock Star Copolymers: Synthesis, Selective Hydrogenation, and Properties
2020
Two series of well-defined multiblock four-arm tapered star copolymers with “arms” of the type poly(styrene)-block-poly(isoprene-grad-styrene), (SI/S)₄, were synthesized on a multigram scale with short reaction times. Targeted molecular weight (M) values ranged from 80 to 240 kg mol–¹ with polystyrene (PS) compositions of 40 and 60 wt %. Narrowly distributed (Đ = 1.04–1.12) copolymers were obtained regardless of M and without additional purification beyond precipitation. At sufficiently high M, members of the 40 wt % PS series possessed either a cylindrical or bicontinuous morphology, whereas the 60 wt % PS series yielded lamellae. The star copolymers outperformed their corresponding linear…
Synergistic effects of Janus particles and triblock terpolymers on toughness of immiscible polymer blends
2017
Abstract By influencing both the interfacial adhesion and the morphology, compatibilizers determine the mechanical properties of polymer blends. Here, we study the mechanical properties, in particular the fatigue crack propagation (FCP) of immiscible blends of poly(2,6-dimethyl-1,4-phenylene ether)/poly(styrene- co -acrylonitrile) (PPE/SAN), compatibilized with Janus nanoparticles (JPs) and linear polystyrene- block -polybutadiene- block -poly(methyl methacrylate) (SBM) triblock terpolymers. Synergistic effects of a mixture of both compatibilizers improve the FCP behavior and reveal the important role of interface stiffness and flexibility on the mechanical properties of polymer blends. The…
Interaction of the Alternating Double Stranded Copolymer poly(dA-dT)·poly(dA-dT) with NiCl2and CdCl22: Solution Behavior
2007
The thermal denaturation of the synthetic high molecular weight double stranded polynucleotide poly(dA-dT) x poly(dA-dT) has been studied in aqueous buffered solution (Tris 1.0 mM; pH 7.8+/-0.2) in the presence of increasing concentrations of either Ni(2+) (borderline cation) or Cd(2+) (soft cation) at four different constant ionic strength values (NaCl), making use of UV and circular dichroism (CD) spectroscopies. The experimental results show that the B-type double helix of the polymer is stabilized against thermal denaturation in the presence of both cations at low concentrations, relative to the systems where only NaCl is present, in the same conditions of ionic strength and pH. The eff…
Inverse Thermogelation of Aqueous Triblock Copolymer Solutions into Macroporous Shear-Thinning 3D Printable Inks
2020
Amphiphilic block copolymers that undergo (reversible) physical gelation in aqueous media are of great interest in ditIerent areas including drug delivery, tissue engineering, regenerative medicine, and biofabrication. We investigated a small library of ABA-type triblock copolymers comprising poly(2-methyl-2-oxazoline) as the hydrophilic shell A and different aromatic poly(2-oxazoline)s and poly(2-oxazine)s cores B in an aqueous solution at different concentrations and temperatures. Interestingly, aqueous solutions of poly(2-methyl-2-oxazoline)-block-poly(2-phenyl-2-oxazine)-block-poly(2-methyl-2-oxazoline) (PMeOx-b-PPheOzi-b-PMeOx) undergo inverse thermogelation below a critical temperatur…
Tri-alkenyl polyhedral oligomeric silsesquioxanes as comonomers and active center modifiers in ethylene copolymerization catalyzed by bis(phenoxy-imi…
2018
Abstract In copolymerization of ethylene (E) with tri-alkenyl-silsesquioxanes (POSS-6-3 and POSS-10-3) were used bis(phenoxy-imine) titanium, zirconium and vanadium catalysts, as well as salen-type vanadium catalysts. There were obtained copolymers with POSS-R-3 units as side branches of polymer chains. The type of employed bis(phenoxy-imine) titanium, zirconium and vanadium catalysts and salen-type catalyst of vanadium determined the copolymer chain termination reactions, as well as the mechanism of modification of the active species by the POSS-R-3 comonomer. POSS-R-3 comonomers caused selective poisoning of bis(phenoxy-imine) zirconium catalyst and they provided protection against tight …
Vascular Endothelial Growth Factor-Releasing Microspheres Based on Poly(ε-Caprolactone-PEG-ε-Caprolactone)-b-Poly(L-Lactide) Multiblock Copolymers In…
2020
Pancreatic islet transplantation is a promising advanced therapy that has been used to treat patients suffering from diabetes type 1. Traditionally, pancreatic islets are infused via the portal vein, which is subsequently intended to engraft in the liver. Severe immunosuppressive treatments are necessary, however, to prevent rejection of the transplanted islets. Novel approaches therefore have focused on encapsulation of the islets in biomaterial implants which can protect the islets and offer an organ-like environment. Vascularization of the device’s surface is a prerequisite for the survival and proper func- tioning of transplanted pancreatic islets. We are pursuing a prevascularization s…
Dielectric and dynamic-mechanical behaviour of ethylene-vinyl alcohol copolymers
1983
Abstract Dynamic-mechanical and dielectric measurements on ethylene-vinyl alcohol copolymers with two different vinyl alcohol contents and, for comparison on polyvinylalcohol and low density polyethylene, have been carried out in order to clarify the nature of the relaxation peak. The relaxation peak observable in the dielectric loss curves of the copolymers has been assigned to the interfacial polarization, MWS type, occurring between hydrogen bonded hydroxyl groups and the apolar polyethylene segments. The shoulder also present in the e″-T curves of the copolymers seems to correspond to the glass transition peak which is hidden since the dielectric loss curve increases quickly because of …
PHA Latex Composite Films: Mechanical Properties and Surface Visualization
2013
Homopolymer PHB and copolymer PHB/HV containing granules were isolated from Azotobacter chroococcum cells and used for latexes formation. Composite latex films were formed from the PHB and PHB/HV latexes with different content of poly (vinyl alcohol) and glycerol and a hydrophobic fluorescent benzanthrone derivated dye 3-piperidinobenzanthrone, possessed high fluorescence intensity in a system with PHA granules. Fluorescence based methods were used for characterization of the elaborated latex film by their stability at high temperature and for visualization of the film surfaces PHA granules distribution. Film stability in phosphate buffered saline was evaluated by dye migration activity in …
Microgels of polyaspartamide and poly(ethylene glycol) derivatives obtained by γ-irradiation
2002
Abstract The copolymer PHG based on α , β -poly( N -2-hydroxyethyl)- dl -aspartamide (PHEA) functionalized with glycidyl methacrylate has been exposed in aqueous solution to a γ -ray source at different irradiation doses (2, 2.5 and 3.5 kGy), alone or in combination with poly(ethylene glycol)dimethacrylate (PEGDMA) or poly(ethylene glycol)diacrylate (PEGDA). The irradiation produces microgel systems that have been characterized by viscosity measurements. Lyophilization of microgels gives rise to samples able to swell instantaneously in water whereas their treatment with acetone produces swellable microparticles that have been characterized.