Search results for "Coupling"
showing 10 items of 1862 documents
A Regio- and Diastereoselective Anodic Aryl-Aryl Coupling in the Biomimetic Total Synthesis of (-)-Thebaine.
2018
The biosynthesis of thebaine is based on the regioselective, intramolecular, oxidative coupling of (R)-reticuline. For decades, chemists have sought to mimic this coupling by using stoichiometric oxidants. However, all approaches to date have suffered from low yields or the formation of undesired regioisomers. Electrochemistry would represent a sustainable alternative in this respect but all attempts to accomplish an electrochemical synthesis of thebaine have failed so far. Herein, a regio- and diastereoselective anodic coupling of 3',4',5'-trioxygenated laudanosine derivatives is presented, which finally enables electrochemical access to (-)-thebaine.
The Nuclear Mean Field and Many-Nucleon Configurations
2007
After the two preceding chapters, throughout impregnated with messy-looking, though necessary mathematics, we are finally entering the realm of basic concepts of nuclear structure physics. While the preceding chapters may have been a shock to the reader not familiar with the fine details of angular momentum coupling, the present chapter should offer a soothing soft landing to the basic philosophy behind the nuclear shell model, namely the nuclear mean field.
The KeV Majoron as a dark matter particle
1993
We consider a very weakly interacting KeV majoron as dark matter particle (DMP), which provides both the critical density $\rho_{cr} = 1.88 \times 10^{-29} h^{2}$ $g/cm^{3}$ and the galactic scale $M_{gal}$ $\sim m^{3}_{Pl}/m^{2}_{J} \sim 10^{12} M_{\odot} (m_{J}/1 KeV)^{-2}$ for galaxy formation. The majoron couples to leptons only through some new "directly interacting particles", called DIPS, and this provides the required smallness of the coupling constants. If the masses of these DIPS are greater than the scale $V_s$ characterizing the spontaneous violation of the global lepton symmetry they are absent at the corresponding phase transition ($T \sim V_s$) and the majorons are produced d…
Analyses of the TRACE V5 capability for the simulation of natural circulation and primary/containment coupling in BDBA condition typical of the MASLWR
2014
In the short term period the use of advanced Small Modular Reactor (SMR) is one of the most promising options for the deployment of nuclear technology. The validation and assessment of the best estimate thermal hydraulic system code TRACE against SMR thermal hydraulic phenomena is a novel effort. In this framework the use of the natural circulation database developed at the OSU-MASLWR test facility, simulating the MASLWR reactor prototype, is of interest for analyses of the TRACE code capability in predicting natural circulation and primary/containment coupled behavior in SMR. The target of this paper is to analyze the TRACE V5 capability for the simulation of natural circulation phenomena,…
Numerical study of the accuracy of temperature measurement by thermocouples in small-scale reactors
2018
Proper temperature measurement is imperative in any laboratory study if reliable data are to be obtained, particularly in the field of chemical kinetics. In this paper we analyze in silico some typical thermowell configurations used in small-scale reactors by coupling computational fluid dynamics (CFD) with conjugated heat transfer phenomena. This allows us to identify deviations in measurements arising from thermal radiation and self-conductivity in mid and high temperature ranges, in addition to radial temperature gradients. A novel design is proposed and optimized by additional simulation, showing potential for faster and more accurate temperature measurements.
Fullerene-ionic-liquid conjugates: a new class of hybrid materials with unprecedented properties.
2015
A modular approach has been followed for the synthesis of a series of fullerene-ionic-liquid (IL) hybrids in which the number of IL moieties (two or twelve), anion, and cation have been varied. The combination of C60 and IL give rise to new unique properties in the conjugates such as solubility in water, which was higher than 800 mg mL(-1) in several cases. In addition, one of the C60 -IL hybrids has been employed for the immobilization of palladium nanoparticles through ion exchange followed by reduction with sodium borohydride. Surprisingly, during the reduction several carbon nanostructures were formed that comprised nano-onions and nanocages with few-layer graphene sidewalls, which have…
Through-space spin-spin coupling in acetylenic systems. Ab initio and DFT calculations
2003
Abstract: We have investigated, by means of ab initio and DFT calculations, the magnitude of through-space spin-spin couplings ( J CH and J HH ) in CH/π bonded van der Waals dimers involving acetylene, and in a structurally related covalent compound (4-ethynylphenanthrene). Within regions where the interaction is stabilizing J HH couplings are very small (< 0.1 Hz) for all complexes. In the acetylene-methane complex J CH is also very small, whereas in the acetylene-benzene complex and the acetylene dimer it shows a relatively large dependence on the tilt angle from the T-shaped arrangement, for which the smallest values are calculated, to a parallel slipped arrangement where J CH is ca. 0.5…
Detuning effects in STIRAP processes in the presence of quantum noise
2011
The Stimulated Raman adiabatic passage (STIRAP) in three-state systems in the presence of quantum noise is considered. A comparison is made between different models, one based on a phenomenological introduction of decays, one traceable back to a microscopic description of the system-environment interaction. Effects related, to off-resonance in the coupling between the involved states are considered.
Status of EU DEMO heat transport and power conversion systems
2018
Abstract DEMO in Europe is considered to be the nearest-term reactor design to follow ITER and capable of demonstrating production of electricity, operating with a closed fuel-cycle and to be a facilitating machine between ITER and a commercial reactor. The aim of this paper is to show the design progress of the complex system’s “chain” devoted to the extraction of the plasma generated pulsed thermal power and its conversion into electricity delivered to the grid, including the Primary Heat Transport System (PHTS), the Power Conversion System (PCS) and the Intermediate Heat Transport System (IHTS) – provided by an Energy Storage System (ESS) – in between PHTS and PCS, which is introduced fo…
Measurement of the W boson polarization in top quark decays with the ATLAS detector
2012
This paper presents measurements of the polarization of W bosons in top quark decays, derived from t¯t events with missing transverse momentum, one charged lepton and at least four jets, or two charged leptons and at least two jets. Data from pp collisions at a centre-of-mass energy of 7 TeV were collected with the ATLAS experiment at the LHC and correspond to an integrated luminosity of 1.04 fb−1. The measured fractions of longitudinally, left- and right-handed polarization are F0 = 0.67 ± 0.07, FL = 0.32 ± 0.04 and FR = 0.01 ± 0.05, in agreement with the Standard Model predictions. As the polarization of the W bosons in top quark decays is sensitive to the Wtb vertex Lorentz structure and…