Search results for "Coupling"
showing 10 items of 1862 documents
Characterization of the Dynamic Interaction between Chassis and Powertrain of a Vehicle Using the Coupling Matrix
2013
International audience; This study is concerned with the vibration transmission between two subsystems of a vehicle: the chassis which is considered as an elastic structure and the powertrain which is considered as a rigid body. The study is carried out based on a new coupling matrix constructed from equations of dynamic behavior of each subsystems. This matrix depends only on the impedance matrices of the two subsystems and the mechanical characteristics of the linking mounts. Under some assumptions, a simplified expression to obtain the overall behaviour of the entire system is proposed. Despite its sensitivity to the degree of coupling between the subsystems, this method can be applied t…
Time-dependent screening explains the ultrafast excitonic signal rise in 2D semiconductors
2020
We calculate the time evolution of the transient reflection signal in an MoS$_2$ monolayer on a SiO$_2$/Si substrate using first-principles out-of-equilibrium real-time methods. Our simulations provide a simple and intuitive physical picture for the delayed, yet ultrafast, evolution of the signal whose rise time depends on the excess energy of the pump laser: at laser energies above the A- and B-exciton, the pump pulse excites electrons and holes far away from the K valleys in the first Brillouin zone. Electron-phonon and hole-phonon scattering lead to a gradual relaxation of the carriers towards small $\textit{Active Excitonic Regions}$ around K, enhancing the dielectric screening. The acc…
Extending existential feeling through sensory substitution
2023
AbstractIn current philosophy of mind, there is lively debate over whether emotions, moods, and other affects can extend to comprise elements beyond one’s organismic boundaries. At the same time, there has been growing interest in the nature and significance of so-called existential feelings, which, as the term suggests, are feelings of one’s overall being in the world. In this article, I bring these two strands of investigation together to ask: can the material underpinnings of existential feelings extend beyond one’s skull and skin? To begin, I introduce and adopt a componential-systemic view of extended affectivity. In doing so, I specify the vehicle externalist criteria for extension em…
Iron‐Catalyzed C(sp2)−C(sp3) Cross‐Coupling of Chlorobenzamides with Alkyl Grignard Reagents: Development of Catalyst System, Synthetic Scope, and Ap…
2019
Direct preparation of alkylated amide‐derivatives by cross‐coupling chemistry using sustainable protocols is challenging due to sensitivity of the amide functional group to reaction conditions. Herein, we report the synthesis of alkyl‐substituted amides by iron‐catalyzed C(sp2)−C(sp3) cross‐coupling of Grignard reagents with aryl chlorides. The products of these reactions are broadly used in the synthesis of pharmaceuticals, agrochemicals and other biologically‐active molecules. Furthermore, amides are used as versatile intermediates that can participate in the synthesis of valuable ketones and amines, providing access to motifs of broad synthetic interest. The reaction is characterized by …
Sequential Iron-Catalyzed C(sp2)–C(sp3) Cross-Coupling of Chlorobenzamides/Chemoselective Amide Reduction and Reductive Deuteration to Benzylic Alcoh…
2023
Benzylic alcohols are among the most important intermediates in organic synthesis. Recently, the use of abundant metals has attracted significant attention due to the issues with the scarcity of platinum group metals. Herein, we report a sequential method for the synthesis of benzylic alcohols by a merger of iron catalyzed cross-coupling and highly chemoselective reduction of benzamides promoted by sodium dispersion in the presence of alcoholic donors. The method has been further extended to the synthesis of deuterated benzylic alcohols. The iron-catalyzed Kumada cross-coupling exploits the high stability of benzamide bonds, enabling challenging C(sp2)–C(sp3) cross-coupling with alkyl Grign…
ATLAS Inner Detector alignment and analysis of the Wtb vertex structure with single top quarks
2018
Esta tesis puede ser dividida en dos partes diferentes: La primera trata sobre el alineamiento del detector interno de ATLAS, y la segunda sobre el estudio de la estructura del vértice Wtb mediante el uso de quarks top producidos en solitario. La primera parte presenta las técnicas utilizadas para alinear el detector interno de ATLAS, así como las mejoras implementadas en algoritmo de alineamiento durante el Run-II del LHC. Durante la toma de datos, tienen lugar en el detector interno diversos movimientos y deformaciones dinámicos que comprometen la calidad de los datos recogidos. Los dos más relevantes son un movimiento vertical del detector de Píxeles, y el combado del IBL. En el alineami…
Ecology and extent of freshwater browning - What we know and what should be studied next in the context of global change
2022
Water browning or brownification refers to increasing water color, often related to increasing dissolved organic matter (DOM) and carbon (DOC) content in freshwaters. Browning has been recognized as a significant physicochemical phenomenon altering boreal lakes, but our understanding of its ecological consequences in different freshwater habitats and regions is limited. Here, we review the consequences of browning on different freshwater habitats, food webs and aquatic-terrestrial habitat coupling. We examine global trends of browning and DOM/DOC, and the use of remote sensing as a tool to investigate browning from local to global scales. Studies have focused on lakes and rivers while seldo…
Observation of Higgs boson production in association with a top quark pair at the LHC with the ATLAS detector
2018
Physics letters / B 784, 173 - 191 (2018). doi:10.1016/j.physletb.2018.07.035
The 1-way on-line coupled atmospheric chemistry model system MECO(n) – Part 2: On-line coupling with the Multi-Model-Driver (MMD)
2012
A new, highly flexible model system for the seamless dynamical down-scaling of meteorological and chemical processes from the global to the meso-γ scale is presented. A global model and a cascade of an arbitrary number of limited-area model instances run concurrently in the same parallel environment, in which the coarser grained instances provide the boundary data for the finer grained instances. Thus, disk-space intensive and time consuming intermediate and pre-processing steps are entirely avoided and the time interpolation errors of common off-line nesting approaches are minimised. More specifically, the regional model COSMO of the German Weather Service (DWD) is nested on-line into the …
Systematic approach to β and 2vββ decays of mass A=100-136 nuclei
2015
In this work we perform a systematic study of pairs of single-β-decaying nuclei in the mass region A = 100–136 to extract information on the effective value of the axial-vector coupling constant gA. As the many-body framework we use the quasiparticle random-phase approximation (QRPA) and its proton-neutron variant (pnQRPA) in singleparticle valence bases with Woods-Saxon-calculated single-particle energies. It is found that, to a reasonable approximation, gA is a linear function of the mass number A, with a slightly different parametrization below and above the mass A = 121. Using the values of gA extracted from the linear fit, as well as an average constant value of gA, we calculate the tw…