Search results for "Crack"
showing 10 items of 209 documents
Cracking Activity and Hydrothermal Stability of MCM-41 and Its Comparison with Amorphous Silica-Alumina and a USY Zeolite
1996
It has been found that the cracking activity of MCM-41 for a reaction catalyzed by strong acids site, such asn-heptane cracking, is much lower than that of a USY zeolite, and similar to that of amorphous silica-alumina. The higher activity of USY is due to the presence of stronger Bronsted acid sites in the zeolite. In the case of gas oil cracking, the greater accessibility of the large molecules to acid sites in MCM-41 relative to USY makes the difference in activity between these two catalysts much smaller than for the pure hydrocarbon. In the calcined state MCM-41 is more active and gives more gasoline and less gases and coke than amorphous silica-alumina. However, when the catalysts wer…
Mechanical Behavior of Concrete Columns Confined by Laterally Pre-Tensioned FRP
2011
This paper presents the results of an experimental investigation of concrete columns confined by a wound pre-tensioned carbon filament yarn. Yarn winding equipment was developed in the Institute of Polymer Mechanics with the ability to set the desired pre-tension force and thereby producing confined concrete specimens with different initial lateral pressure. It is shown that initial lateral pressure increases the axial stress at which intense internal cracking of the concrete develops.
Influence of the process variables on the product distribution and catalyst decay during cracking of paraffins
1986
Abstract The influence of the partial pressure of the hydrocarbon, reaction temperature, time on stream and the presence of olefins on the product distribution and the kinetics and decay during the cracking of n-heptane on an REHY zeolite were studied. It was found that the isomerization to cracking ratio depends on the hydrocarbon partial pressure. The active sites for cracking and isomerization are not the same and those for cracking decay faster, the selectivity changing with the degree of decay of the zeolite. The protolytic to β-cracking ratio, and therefore the paraffin to olefin ratio, are a function of the partial pressure of n-heptane. Both reactants and products have a marked infl…
Performance-based characterization of recycled polymer modified asphalt mixture
2021
Due to the introduction of secondary materials, the asphalt mixtures to be designed and tested in our laboratories are constantly becoming much more complex than traditional asphalt mixtures making difficult to use conventional laboratory procedure and/or predict expected results. This study proposes a comprehensive characterization of asphalt mixture modified with recycled polymer compound by using both wet and dry process proposing adjustments to laboratory mixing and sample compaction procedure. Accordingly, three AC20 Hot Asphalt Mixture (HMA) were designed and their conventional and performance related properties were assessed by looking at a) Indirect Tensile test (ITS) a) moisture da…
The influence of branching isomerization on the product distribution obtained during cracking of n-heptane on acidic zeolites
1985
Abstract The initial selectivities for the primary products occurring during the cracking of n-heptane on a rare-earth (RE)-HY ultrastable zeolite up to 470°C have been calculated. The activation energies for the cracking of n-heptane and its branched isomers in the fraction C4 + C3 have been obtained by molecular orbital calculations, and these values and the predicted product distribution have been compared with those obtained experimentally. It is concluded that the cracking of n-heptane on large-pore zeolites may take place by different parallel routes involving protolytic and β-cracking of n-heptane and β-cracking of the readily formed branched carbenium ions. The relative importance o…
Steel Fibres: Effective Way to Prevent Failure of the Concrete Bonded with FRP Sheets
2016
Although the efficiency of steel fibres for improving mechanical properties (cracking resistance and failure toughness) of the concrete has been broadly discussed in the literature, the number of studies dedicated to the fibre effect on structural behaviour of the externally bonded elements is limited. This experimental study investigates the influence of steel fibres on the failure character of concrete elements strengthened with external carbon fibre reinforced polymer sheets. The elements were subjected to different loading conditions. The test data of four ties and eight beams are presented. Different materials were used for the internal bar reinforcement: in addition to the conventiona…
Postbuckling analysis of cracked stiffned plates by pb–2 Rayleigh-Ritz method
2015
A Rayleigh-Ritz approach for the analysis of buckling and post-buckling behavior of cracked composite stiffened plates is presented. The structure is thought as the assembly of plate elements modeled by the first order shear deformation theory. Continuity along the edges common to contiguous elements are enforced by using penalty techniques, which also allow to straightforwardly implement efficient crack modeling strategies. General symmetric and unsymmetric stacking sequences are considered and numerical procedures have been developed and used to validate the present solution by comparison with FEA results. Original results are also presented for post-buckling solution of multilayered stif…
A fast dual boundary element method for 3D anisotropic crack problems
2009
In the present paper a fast solver for dual boundary element analysis of 3D anisotropic crack problems is formulated, implemented and tested. The fast solver is based on the use of hierarchical matrices for the representation of the collocation matrix. The admissible low rank blocks are computed by adaptive cross approximation (ACA). The performance of ACA against the accuracy of the adopted computational scheme for the evaluation of the anisotropic kernels is investigated, focusing on the balance between the kernel representation accuracy and the accuracy required for ACA. The system solution is computed by a preconditioned GMRES and the preconditioner is built exploiting the hierarchical …
Analysis of thin film cracking and buckling on compliant substrate by fragmentation test
2007
Application of coating fragmentation test for determination of coating properties is considered. A probabilistic model of coating fragmentation under uniaxial tensile loading is applied for coating and interface property identification of thin brittle coating/polymer substrate system. A finite element model is developed to simulate the process of buckle formation in coating strips during fragmentation test. The measured buckle geometry parameters and buckle density evolution as a function of the applied strain is used to estimate the interface toughness.
Free vibrations analysis of cracked variable stiffness composite plates by the eXtended Ritz method
2022
Variable stiffness composite laminates show advantageous structural features related to their enlarged design space. They are attractive candidates for advanced engineering applications where the assessment of static and dynamic behavior and strength in the presence of cracks is often required. In the present work, a single-domain extended Ritz formulation is proposed to study the free vibrations of cracked variable stiffness composite plates. The plate model is based on the first-order shear deformation theory whose primary variable, i.e. displacements and rotations, are approximated via a set of orthogonal polynomial trial functions enriched with a set of special crack functions. These fu…