Search results for "Cracking"
showing 10 items of 102 documents
Increasing the stability of the Ge-containing extra-large pore ITQ-33 zeolite by post-synthetic acid treatments
2018
[EN] Extra-large pore ITQ-33 zeolite (ITT, 18 x 10 x 10-rings) is a very promising catalyst for the catalytic cracking of gasoil but, unfortunately, this material shows a limited hydrothermal stability due to the large germanium content present in the ITQ-33 structure. Taking this into account, the Ge-containing ITQ-33 has been post synthetically modified using different acid procedures with the aim of studying the effect of these treatments on the overall hydrothermal stability of this extra-large pore zeolite. In this sense, the as-prepared ITQ-33 has been treated with different HCl solutions in ethanol (from 0.1 to 1 M), containing also tetraethylorthosilicate (TEOS) as silicon precursor…
Electrochemistry for Mechanically-assisted Corrosion
2019
Abstract: This chapter will not discuss the basics of electrochemistry; these aspects have been largely developed in the previous corrosion thematic school on stress corrosion cracking (SCC).
Engineering Zeolites for Catalytic Cracking to Light Olefins
2017
Propene is a key building block for the petrochemical industry whose demand is increasing strongly in recent years, even faster than that of ethene. The availability of propene is limited, and therefore, efforts to optimize its production are being pursued. On the occasion of the 75th anniversary of the first FCC unit, we analyze some recent advances that have been achieved in the understanding and development of zeolites aiming to increase the production of light olefins as petrochemical building blocks by means of catalytic cracking. We discuss a selected group of emerging strategies in zeolite engineering that have great prospects for research and that we consider could impact the sector…
Simple Plastic Model for Shear Critical SFRC Beams
2010
A simple physical model, for prediction of ultimate shear strength of steel fiber reinforced concrete (SFRC) beams is developed on the basis of a plastic approach originally proposed for reinforced concrete (RC) beams without stirrups. It is founded on the hypothesis that cracks can be transformed into yield lines, and thus is know as Crack Sliding Model (CSM). First, the CSM is improved in order to take into account the shear strength increase for deep beams, due to the arch effect. Then, the effectiveness factors for fibrous concrete under biaxial stresses are evaluated, taking into account the post-cracking tensile strength of SFRC and its ability to control slippage along shear cracks. …
A theoretical and experimental study to point out the notion of loading mode in damage mechanicsApplication to the identification and validation of a…
2002
A model of fatigue-induced intralaminar cracking in strongly anisotropic laminates is presented. The features of the microscopic phenomenon are explicitly taken into account at the macroscopic level by the use of two variables, which define a new concept in Damage Mechanics that results not only in a coherent model of crack density evolution, but also in a coherent treatment of damage deactivation. Damage evolution indeed is strongly dependent on the local loading mode in each ply where cracking occurs. Experiments on complex lay-ups provided sufficient data for complete calibration of the model. These tests also allowed to validate the theoretical choice of the damage variable. Finally, nu…
Flexural response of FRC corbels
2009
Abstract A strut-and-tie macro-model is proposed to determine the flexural response of fiber reinforced concrete (FRC) corbels, reinforced with longitudinal bars and subjected to vertical load. The effects of the corbel geometry, the percentage of steel fibers, and grades of concrete and steel bars are also included. The model, which is specific for FRC corbels with hooked steel fibers, allows the determination of load levels, and corresponding displacements, associated with the first cracking, yielding of the main steel bars and crushing of the concrete strut. The sequential occurrence of these phenomena is established, depending on the amounts of steel fibers and reinforcing steel. The si…
Steel fiber-reinforced concrete corbels:experimental behavior and shear strength prediction
2007
Corbels are structural members often used in reinforced concrete structures to transfer vertical and horizontal forces to principal members. This paper presents experimental research regarding the flexural behavior of corbels in plain and fibrous concrete and in the presence of steel bars. The study considers the influence of the type of concrete grade (normal- and high-strength concretes), of the fiber percentage and of the arrangement and percentage of the steel bars on the flexural behavior of the corbels. The results in terms of load-deflection curves and crack patterns show the effectiveness in using fibrous reinforced concrete corbels as well as in the presence of stirrups ensuring ad…
Micro-cracking of brittle polycrystalline materials with initial damage
2016
In this paper, the effect of pre-existing damage on brittle micro-cracking of polycrystalline materials is explored. The behaviour of single and multiple cracks randomly distributed within a grain scale polycrystalline aggregate is investigated using a recently developed grain boundary 3D computational framework. Each grain is modelled as a single crystal anisotropic domain. Opening, sliding and/or contact at grain boundaries are modelled using nonlinear cohesive-frictional laws. The polycrystalline micro-morphologies are generated using Voronoi tessellation algorithms in combination with a regularisation scheme to avoid the presence of unnecessary small geometrical entities (edges and face…
Radial cracks around inclusions: A program to calculate P-T paths with respect to elastic properties of minerals
1994
Abstract Radial cracking around inclusions in a matrix originated by their differential elastic behavior allows the development of a new method for reconstructing the evolution of P-T paths during metamorphism. The appearance of radial cracking is a function of the variation of the elastic parameters between the matrix and inclusion, the initial P-T conditions of inclusion entrapment and the component of isothermal decompression characteristic for a retrograde path. The program RADCRA is written in FORTRAN 77 and presents a general form to calculate the different P-T evolutions for a matrix and an inclusion during metamorphism. Necessary input data are the elastic properties of each mineral…
Nonlinear Analysis of Beams Reinforced in Shear with Stirrups and Steel Fibers
2012
The modified compression field theory (MCFT) and the disturbed stress field model (DSFM) are often used to predict the nonlinear behavior of reinforced concrete structures. This study presents several extensions of the MCFT and DSFM to the case of high-strength steel fiber-reinforced concrete beams subjected to transverse loads. Experimental four-point bending tests were conducted on 12 concrete beams with a different percentage of fibers and/or stirrups. To validate the updates introduced in the analytical models, numerical analysis was performed using nonlinear finite element software. Modeling of the post-peak softening branch of the tensile and compressive constitutive curves of fibrous…