Search results for "Crista"
showing 10 items of 180 documents
Weak Interactions Modulating the Dimensionality in Supramolecular Architectures in Three New Nickel(II)-Hydrazone Complexes, Magnetostructural Correl…
2011
Three different ONO donor acetyl hydrazone Schiff bases have been synthesized from the condensation of acetic hydrazide with three different carbonyl compounds: salicylaldehyde (HL(1)), 2-hydroxyacetophenone (HL(2)), and 2, 3-dihydroxybenzaldehyde (HL(3)). These tridentate ligands are reacted with Ni(OOCCF(3))(2)·xH(2)O to yield three new Ni(II) complexes having distorted octahedral geometry at each Ni center: [Ni(L(1))(OOCCF(3))(CH(3)OH)](2) (1), [Ni(L(2))(OOCCF(3))(H(2)O)](2) (2), and [Ni(L(3))(L(3)H)](OOCCF(3))(H(2)O)(1.65)(CH(3)OH)(0.35) (3). The ligands and the complexes have been characterized by elemental analysis and IR and UV-vis spectroscopy, and the structures of the complexes ha…
Crystal structure of 4-[(adamantan-1-yl)amino]naphthalene-1,2-dione
2019
The title compound, an example of a stable 1,2-naphthoquinone, illustrates steric buttressing of the adamantanyl group.
Azide Binding Controlled by Steric Interactions in Second Sphere. Synthesis, Crystal Structure, and Magnetic Properties of [Ni II 2 (L)(μ 1,1 -N 3 )]…
2016
International audience; The dinuclear Ni-II complex [Ni-2(L-2)][ClO4](2) (3) supported by the 28-membered hexaaza-dithiophenolate macro-cycle (L-2)(2-) binds the N-3(-) ion specifically end-on yielding [Ni-2(L-2)(mu(1,1)-N-3)] [ClO4] (7) or [Ni-2(L-2)(mu(1,1)-N-3)][BPh4] (8), while the previously reported complex [Ni2L1(mu(1,3)-N-3)][ClO4] (2) of the 24-membered macrocycle (L-1)(2-) coordinates it in the end-to-end fashion. A comparison of the X-ray structures of 2, 3, and 7 reveals the form-selective binding of complex 3 to be a consequence of its preorganized, channel-like binding pocket, which accommodates the azide anion via repulsive CH center dot center dot center dot pi interactions …
Trattamenti a base di TiO2 nanocristallina ad azione protettiva indiretta fotocatalitica applicati ai beni architettonici
2009
The research is focused on the definition of a diagnostic program to verify a protective product for stone surfaces. The objective is, in particular, to verify the treatments efficacy of nanocrystalline TiO2 (Titania) with indirect photocatalytic protective action, in the form of thin films made through the sol-gel method, and applied to the stone materials of the Monumental Heritage, through a poly-methodological scientific research, that allow to assess the innovative behaviour towards the fundamental principles of conservation and restoration of the architectural-artistic heritage. To define the research’s program have collaborated Department of Geosciences of University of Padova, ISTM-…
Estimación de dosis en aplicaciones radiológicas basada en la dosimetría por luminiscencia ópticamente estimulada
2016
La Comisión Internacional de Protección Radiológica (ICRP) ha recomendado una reducción del límite de dosis equivalente en cristalino para los trabajadores ocupacionalmente expuestos de 150 mSv por año (ICRP-2007, Publicación 103) a un promedio de 20 mSv por año durante cinco años o 50 mSv en un año (ICRP-2012, Publicación 118). Actualmente, no existe una dosimetría rutinaria y sistemática para medir la dosis equivalente en cristalino; sólo se hace una extrapolación de los valores medidos por los dosímetros personales. El objetivo de este estudio es estimar la dosis equivalente en superficie que recibe el personal sanitario en cristalino y manos para los procedimientos de cirugía de muñeca …
Estudio del tamaño de cristalito en porcelanas industriales.
2016
El objetivo de la presente tesis en el estudio mediante técnicas de difracción de rayos X, con el apoyo en microscopía electrónica, de la microestructura de la mullita que se desarrolla en porcelanas industriales de formulación triaxial (caolín, feldespato y cuarzo). La porcelana es un material de gran importancia en la industria debido a su uso en campos tecnológicamente muy diversos, tales como la cerámica ornamental, pavimento y revestimiento, aisladores eléctrico o piezas resistentes a agentes físicos y químicos tales como material de laboratorio o partes de motores. Pese a estas características tecnológicas la porcelana ha sido poco estudiada desde el punto de vista científico, si bien…
Paó reial, Pavo real (VER0000092)
Altres noms vulgars: Indian Peafowl (Anglès), Paon bleu (Francès), Pfau (Alemany) Gabinet de Vertebrats (Departament de Zoologia), Facultat de Ciències Biològiques (Campus de Burjassot), C/ Doctor Moliner, s/n, Bloque B. 5é plant, Burjassot (Valencia). Armari: 3-3 Macho Adulto Completo cristatus _
Food Caching By Willow and Crested Tits: A Test of Scatterhoarding Models
1995
In coniferous forests of Central Finland, Willow (Parus montanus) and Crest- ed Tits (P. cristatus) store seeds in a scattered distribution within their territory during the autumn. Individuals cache and recover food items while moving together as members of mixed-species flocks. The purpose of this study was to test certain predictions of scatter- hoarding models (Stapanian and Smith 1978, Clarkson et al. 1986), which predict how the animal should hoard food items from a superabundant source to maximize the number of caches recovered. Our field experiments gave support to most of the predictions of the models. Individual tits stored seeds closer to the food source when food had been availa…
A Brief Review of the Effects of Pressure on Wolframite-Type Oxides
2018
In this article, we review the advances that have been made on the understanding of the high-pressure (HP) structural, vibrational, and electronic properties of wolframite-type oxides since the first works in the early 1990s. Mainly tungstates, which are the best known wolframites, but also tantalates and niobates, with an isomorphic ambient-pressure wolframite structure, have been included in this review. Apart from estimating the bulk moduli of all known wolframites, the cation–oxygen bond distances and their change with pressure have been correlated with their compressibility. The composition variations of all wolframites have been employed to understand their different structural phase …
All polarization-maintaining passively modelocked ytterbium-doped fiber lasers, behavior under two different cavity configurations
2020
Fil: Cuadrado-Laborde, Christian. Universidad de Valencia. Departamento de Física Aplicada; España Fil: Cuadrado-Laborde, Christian. Consejo Nacional de Investigaciones Científicas. Instituto de Física Rosario; Argentina Fil: Cuadrado-Laborde, Christian. Pontificia Universidad Católica Argentina. Facultad de Química e Ingeniería del Rosario; Argentina Fil: Carrascosa, Antonio. Universidad de Valencia. Departamento de Física Aplicada; España Fil: Diez, Antonio. Universidad de Valencia. Departamento de Física Aplicada; España Fil: Cruz, J. L. Universidad de Valencia. Departamento de Física Aplicada; España Fil: Andrés, M. V. Universidad de Valencia. Departamento de Física Aplicada; España Abs…