Search results for "Crossing"
showing 10 items of 167 documents
Between school and working life: Vocational teachers’ agency in boundary-crossing settings
2009
Abstract This paper investigates agency among vocational teachers with reference to boundary-crossing between school and working life. Our study utilised interviews with sixteen Finnish vocational teachers. Adopting a narrative analysis approach, we found that the teachers had a variety of forms of exercising agency in terms of decisions deliberately taken, and the discourse and actions following these decisions. These forms were: (i) restricted agency, (ii) extensive agency, (iii) multifaceted balancing agency, (iv) situationally diverse agency, and (v) relationally emergent agency. The exercising of agency was intertwined with the main resources and constraints emerging from the teachers’…
Modèles quantiques à deux états avec croisements de niveaux décrits par les fonctions de Heun
2019
The thesis is devoted to the fundamental problem of excitation and manipulation of quantum systems, having discrete energy spectrum, via external laser fields. We examine the semiclassical time- dependent quantum two-state problem, when the external electromagnetic field is resonant or quasi-resonant for some two of many levels of the system. The focus of the thesis is on the analytic description of the non- adiabatic evolution of quantum systems subject to excitation by level-crossing field configurations. In the present thesis we classify the complete set of the semiclassical time-dependent quantum two-state models solvable in terms of the five function of the Heun class.Main results of t…
Land use functions — a multifunctionality approach to assess the impact of land use changes on land use sustainability
2008
Part 5. Regional and local evaluation - 17; International audience; The dramatic changes in land use observed in Europe in the last fifty years have generally resulted in improvement of human welfare and economic development. On the other hand, they have caused serious environmental problems. There is therefore a need for approaches that help to understand in an integrative way the economic, environmental and societal impacts that land use changes have on sustainability. Sustainability Impact Assessment(SIA), which assesses the impact of policies on sustainability, addresses this challenge. SIA partly builds on the concept of the multifunctionality of land which helps to deal with the compl…
Inland navigation on French rivers
2020
DOI: https://doi.org/10.22032/dbt.40680 (pdf), https://doi.org/10.22032/dbt.40683 (csv), https://doi.org/10.22032/dbt.40682 (excel).; International audience
Welcome aboard: are birds migrating across the Mediterranean Sea using ships as stopovers during adverse weather conditions?
2022
Birds use stopovers during migration to interrupt endurance flight in order to minimize immediate and/or future fitness costs. Stopovers on ships is considered an exceptional and anecdotal event in the ornithological literature. This does not match the experience we had in the summer of 2021, during an oceanographic campaign in the Central Mediterranean, when we regularly observed on average 2.8 birds, of at least 13 species, stopping on board during the 25 days of the campaign. The median stopping time was 42 min, ranging from a few minutes to overnight stays on board. The probability of finding a bird stopping aboard increased with wind force and cloud cover. Birds also stopped more often…
Genetic basis of speed of development in Senecio vulgaris L var. vulgaris, S. vulgaris ssp. denticulatus (O.F. Muell.) P.D. Sell, and Senecio vernali…
1996
The genetic basis of differences in speed of development from germination to first bud formation was investigated in Senecio vulgaris var. vulgaris and S. vulgaris ssp. denticulatus, and also in S. vernalis sampled from Israel and Germany. In the case of S. vulgaris, F2 segregation analysis and the recovery of very late and very early lines from extreme F2 phenotypes showed that differences can be explained by a single major gene model, whereas segregation data from F2 and backcross progenies in S. vernalis are not incompatible with a digenic model of inheritance. Senecio vernalis from Israel and S. vulgaris var. vulgaris reached the different developmental stages in a substantially shorter…
BORDERS AND BORDER CROSSING BETWEEN ART WORLDS. Successful attempts and epic failures to enter new domains in recent British art
2016
The paper attempts to answer, whether it is possible for successful artists in one specific sector to access the domain of another artistic field at their free will. In doing so, this contribution analyses the possible existence of borders and gatekeepers between different art worlds. The aim is not just finding or defining boundaries between art fields, but rather understanding, if boundaries can be pierced through, as well as the conditions that might hinder acceptance. Moving from an art theoretical and philosophical perspective, the present paper will discuss the thesis of Pierre Bourdieu, Howard Becker, Berys Gaut and Joseph Margolis on boundary conditions in the arts. Subsequently the…
Between school and working life: Vocational teachers agency in boundary-crossing settings
2009
This paper investigates agency among vocational teachers with reference to boundary-crossing between school and working life. Our study utilised interviews with sixteen Finnish vocational teachers. Adopting a narrative analysis approach, we found that the teachers had a variety of forms of exercising agency in terms of decisions deliberately taken, and the discourse and actions following these decisions. These forms were: (i) restricted agency, (ii) extensive agency, (iii) multifaceted balancing agency, (iv) situationally diverse agency, and (v) relationally emergent agency. The exercising of agency was intertwined with the main resources and constraints emerging from the teachers’ sense of…
The triplet excited state of the biocative compound thiabendazole. Characterization and suitability as reporter for cyclodextrin complexation
2012
Fluorescence spectroscopy, laser flash photolysis (LPF), and density functional theory calculations have been performed to characterize the photobehavior of thiabendazole (1). Direct LFP of 1 results in the generation of a transient absorbing at λmax = 570 nm identified as the triplet excited state (31∗). The intersystem crossing quantum yield is 0.91, and the triplet energy is 288 kJ mol−1. The singlet–triplet energy gap is 84 kJ mol−1. The behavior of thiabendazole within CDs results in a marked enhancement of the triplet lifetime, this change is attributed to the mobility restrictions of included 1 imposed by the cyclodextrin cavities.
Quantum Chemistry of Excited States in Polyhedral Boranes
2015
In this Chapter we describe the electronic structure of ground states and excited states of the two isomers of octadecaborane (22), anti- and syn-B18H22, and the new derivative of anti-B18H22, the polyhedral substituted borane 4,4′-(HS)2-anti-B18H20. A theoretical interpretation is given on the fluorescence of the anti-B18H22 isomer, and the non-radiative decay of the syn-B18H22 isomer, an unsolved problem since 1962. For the new derivative of anti-B18H22, substitution of hydrogen atoms in positions 4 and 4′ by SH groups allows the tuning of the photophysical properties in 4,4′-(HS)2-anti-B18H20, facilitating intersystem crossing from the excited singlet state to the triplet state.