Search results for "Crystal"

showing 10 items of 22886 documents

Inter-crystal scatter in positron emission tomography: Identification techniques and effects on reconstructed images for AX-PET demonstrator

2012

La PET es una técnica de imagen en medicina nuclear que permite la visualización in-vivo y en 3D de procesos funcionales en seres vivos. Un escáner PET mide los rayos gamma producidos al aniquilarse un positrón, el cual es emitido por un radioisótopo inyectado al paciente. La eficiencia del sistema es una característica crucial de los escáneres PET de alta resolución dedicados a la imagen del cerebro o de animales pequeños con el fin de obtener una imagen más fiel o de reducir la actividad del radiotrazador, y por consiguiente, la dosis inyectada al paciente. El objetivo de este trabajo de investigación es mejorar la eficiencia y calidad de imagen de un prototipo de escáner PET axial (AX-PE…

positron emission tomographyCompton effectUNESCO::CIENCIAS MÉDICASaxial PETbayesianUNESCO::FÍSICAinter-crystal scatter
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CCDC 1972055: Experimental Crystal Structure Determination

2020

Related Article: Andreas Heilmann, Jamie Hicks, Petra Vasko, Jose M. Goicoechea, Simon Aldridge|2020|Angew.Chem.,Int.Ed.|59|4897|doi:10.1002/anie.201916073

potassium (27-di-t-butyl-N4N5-bis[26-di-isopropylphenyl]-99-dimethyl-9H-xanthene-45-diamine)-({[26-di-isopropylphenyl]imino}acetato)-aluminium benzene solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1972054: Experimental Crystal Structure Determination

2020

Related Article: Andreas Heilmann, Jamie Hicks, Petra Vasko, Jose M. Goicoechea, Simon Aldridge|2020|Angew.Chem.,Int.Ed.|59|4897|doi:10.1002/anie.201916073

potassium (27-di-t-butyl-N4N5-bis[26-di-isopropylphenyl]-99-dimethyl-9H-xanthene-45-diamine)-benzyl-(trimethylsilylamide)-aluminium benzene solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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New high-pressure phase and equation of state of Ce2Zr2O8

2012

In this paper we report a new high-pressure rhombohedral phase of Ce2Zr2O8 observed from high-pressure angle-dispersive x-ray diffraction and Raman spectroscopy studies up to nearly 12 GPa. The ambient-pressure cubic phase of Ce2Zr2O8 transforms to a rhombohedral structure beyond 5 GPa with a feeble distortion in the lattice. Pressure evolution of unit-cell volume showed a change in compressibility above 5 GPa. The unit-cell parameters of the high-pressure rhombohedral phase at 12.1 GPa are ah = 14.6791(3) {\AA}, ch = 17.9421(5) {\AA}, V = 3348.1(1) {\AA}3. The structure relation between the parent cubic (P2_13) and rhombohedral (P3_2) phases were obtained by group-subgroup relations. All t…

powdersEquation of statePhase transitionMaterials scienceFOS: Physical sciencesGeneral Physics and AstronomyThermodynamicsCrystal structurePressure coefficientCondensed Matter::Materials Sciencesymbols.namesakefluoritePhase (matter)OxidationCondensed Matter - Materials ScienceRietveld refinementCrystal structureEquations of stateMaterials Science (cond-mat.mtrl-sci)phase transitionshigh pressurex-ray diffractionFISICA APLICADACompressibilitysymbolsraman spectraRaman spectroscopyrietveld refinement
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Multifacial Recognition in Binary and Ternary Cocrystals from 5-Halouracil and Aminoazine Derivatives

2018

A systematic analysis using single crystal X-ray diffraction was performed to explore the role exerted by potential intercomponent proton-transfer reactions in the supramolecular structures of A–B cocrystals formed by 5-haloderivatives of uracil (A), coupled with 2-aminoadenine simulants (aminoazines, B). Twelve new heterodimers were synthesized in different stoichiometries and cocrystallized by solvent cogrinding followed by solution crystallization. In the binary cocrystals, uracil or 1-methyluracil with halide modification at the 5 position (F, Cl, Br, I) was coupled with amino-aromatic N-heterocycles (melamine, 2,4,6-triaminopyrimidine, 2,6-diaminopyridine) as a multivalent site for pyr…

proton transferPyrimidineX ray diffractionSupramolecular chemistry010402 general chemistry01 natural sciencesaromatic compounds; hydrogen bonds; ionization; proton transfer; X ray diffractionNucleobaselaw.inventionchemistry.chemical_compoundlawionizationsingle crystal X-raysGeneral Materials ScienceCrystallizationta116orgaaniset yhdisteet010405 organic chemistryHydrogen bondChemistryaromatic compoundsUracilGeneral ChemistrykiteetCondensed Matter Physics0104 chemical sciencesCrystallographyhalogen bondinghydrogen bondsTernary operationSingle crystalCrystal Growth & Design
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Intramolecular Hydrogen Bond, Hirshfeld Analysis, AIM; DFT Studies of Pyran-2,4-dione Derivatives

2021

Intra and intermolecular interactions found in the developed crystals of the synthesized py-ron-2,4-dione derivatives play crucial rules in the molecular conformations and crystal stabili-ties, respectively. In this regard, Hirshfeld calculations were used to quantitatively analyze the different intermolecular interactions in the crystal structures of some functionalized py-ran-2,4-dione derivatives. The X-ray structure of pyran-2,4-dione derivative namely (3E,3′E)-3,3′-((ethane-1,2-diylbis(azanediyl))bis(phenylmethanylylidene))bis(6-phenyl-2H-pyran-2,4(3H)-dione) was determined. It crystallized in the monoclinic crystal system and C2/c space group with unit cell parameters: a = 14.0869(4) …

pyran-24-dioneGeneral Chemical Engineeringintramolecular hydrogen bondCrystal structure010402 general chemistryDFT01 natural sciencesInorganic Chemistrykemialliset sidoksetAIMMoleculeGeneral Materials Scienceorgaaniset yhdisteetCrystallography010405 organic chemistryHydrogen bondChemistryChemical shiftAtoms in moleculesIntermolecular forceHirshfeld analysiskiteetCondensed Matter Physics0104 chemical sciencesatomitCrystallographyQD901-999Intramolecular forceMonoclinic crystal systemCrystals
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CCDC 1576743: Experimental Crystal Structure Determination

2019

Related Article: Arkalekha Mandal, Kari Rissanen, Prasenjit Mal|2019|CrystEngComm|21|4401|doi:10.1039/C9CE00561G

pyrene 35-dinitrobenzoic acid 14-dioxane solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1893191: Experimental Crystal Structure Determination

2019

Related Article: Esa Kukkonen, Henri Malinen, Matti Haukka, Jari Konu|2019|Cryst.Growth Des.|19|2434|doi:10.1021/acs.cgd.9b00119

pyridin-4-amine 4-aminopyridin-1-ium iodideSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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2-(3,5-Dimethyl-1H-pyrazol-1-yl)-2-hydroxyimino-N0-[1-(pyridin-2-yl)ethylethylidene]

2012

In the title compound, C14H16N6O2, the dihedral angles formed by the mean plane of the acetohydrazide group [maximum deviation 0.0629 (12) A˚ ] with the pyrazole and pyridine rings are 81.62 (6) and 38.38 (4) respectively. In the crystal, molecules are connected by N—HO and O—HN hydrogen bonds into supramolecular chains extending parallel to the c-axis direction. peerReviewed

pyridine ringsacetohydrazide groupsingle-crystal X-ray studydihedral anglessupramolecular chains
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(E)-1-(Pyridin-4-yl)propan-1-one oxime

2016

The asymmetric unit of the title compound, C8H10N2O, contains two crystallographically independent molecules of slightly different conformation, which are linkedviaan intermolecular O—H...N hydrogen bond. The dihedral angle between the pyridine ring and the oxime plane of moleculeA[2.09 (19)°] is smaller than in moleculeB[16.50 (18)°].

pyridinecrystal structure010405 organic chemistryChemistryStereochemistryHydrogen bondGeneral MedicineCrystal structureDihedral angle010402 general chemistryOximeRing (chemistry)01 natural sciencesoxime0104 chemical sciencesCrystallographychemistry.chemical_compoundPyridinelcsh:QD901-999lcsh:CrystallographyIUCrData
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