Search results for "Crystal"

showing 10 items of 22886 documents

Poly[[tetramethanolbis[4-oxo-3-(pyridin-4-yl)-1-(2,4,6-trichlorophenyl)-4,5-dihydro-1H-pyrazolo[3,4-d]pyrimidin-6-olato]disodium]–diethyl ether–metha…

2016

In the title compound, [Na2(C16H7Cl3N5O2)2(CH3OH)4]·C4H10O·2CH3OH, the central pyrazolo[3,4-d]pyrimidine system makes dihedral angles of 82.98 (7)° with the trichlorophenyl ring and 13.11 (15)° with the pyridine ring. The sodium ion has an octahedral environment, being coordinated by four methanol molecules and one O and one N atom of two different heterocyclic ring systems.

pyridinecrystal structure246-trichlorophenylPyrimidineStereochemistryCrystal structureDihedral angle010403 inorganic & nuclear chemistryRing (chemistry)01 natural sciencesMedicinal chemistrychemistry.chemical_compoundPyridinelcsh:QD901-999sodiumbiology010405 organic chemistrypyrazolo[34-d]pyrimidin-6-olateGeneral Medicinebiology.organism_classification0104 chemical scienceschemistryTetralcsh:CrystallographyMethanolDiethyl etherIUCrData
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(E)-1-(Pyridin-4-yl)propan-1-one O-tosyl oxime

2017

The title compound, C15H16N2O3S, was obtained by the reaction of (E)-1-(pyridin-4-yl)propan-1-one oxime andpara-toluenesulfonic acid. The pyridine ring makes a dihedral angle of 54.70 (10)° with the benzene ring. In the crystal, molecules are linked by C—H...O hydrogen bonds, forming a chain along thec-axis direction.

pyridinecrystal structureHydrogen bondCrystal structureDihedral angle010402 general chemistry010403 inorganic & nuclear chemistryRing (chemistry)Oximehydrogen bonding01 natural sciences0104 chemical sciencesCrystalchemistry.chemical_compoundCrystallographytosyl oximechemistryTosylPyridinelcsh:QD901-999lcsh:CrystallographyIUCrData
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Crystal structure of the pyridine–diiodine (1/1) adduct

2015

In the title adduct, C5H5N·I2, the N—I distance [2.424 (8) Å] is remarkably shorter than the sum of the van der Waals radii. The line through the I atoms forms an angle of 78.39 (16)° with the normal to the pyridine ring.

pyridinecrystal structureNanotechnology02 engineering and technologyCrystal structure010402 general chemistryRing (chemistry)01 natural sciencesAdductlcsh:Chemistrysymbols.namesakechemistry.chemical_compoundPyridineGeneral Materials ScienceVan der Waals radiusta116Halogen bondChemistryGeneral Chemistry021001 nanoscience & nanotechnologyCondensed Matter PhysicsData Reports3. Good health0104 chemical sciencesCrystallographylcsh:QD1-999halogen bondingsymbols0210 nano-technologydiiodine
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3-(2,4-Difluorophenyl)-1-(pyridin-4-yl)benzo[4,5]imidazo[1,2-d][1,2,4]triazin-4(3H)-one

2016

In the title compound, C20H11F2N5O, the central 13-membered ring system (r.m.s. deviation = 0.028 Å) makes a dihedral angle of 53.13 (7)° with the difluorophenyl ring and 79.98 (7)° with the pyridine ring. The crystal packing features aromatic π–π interactions between the 13-membered rings [shortest distance between ring centroids = 3.5682 (8) Å].

pyridinecrystal structureShortest distanceStereochemistryChemistryGeneral MedicineCrystal structuredifluorophenylDihedral angle010402 general chemistry010403 inorganic & nuclear chemistryRing (chemistry)01 natural sciences124-triazinone0104 chemical sciencesbenzoimidazoleCrystalCrystallographychemistry.chemical_compoundPyridinelcsh:QD901-999lcsh:CrystallographyIUCrData
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Halogen Bonds in 2,5-Dihalopyridine-Copper(I) Halide Coordination Polymers

2019

Two series of 2,5-dihalopyridine-Cu(I)A (A = I, Br) complexes based on 2-X-5-iodopyridine and 2-X-5-bromopyridine (X = F, Cl, Br and I) are characterized by using single-crystal X-ray diffraction analysis to examine the nature of C2&minus

pyridinedihalopyridineSupramolecular chemistrychemistry.chemical_elementHalidekupari010402 general chemistry01 natural scienceslcsh:TechnologyArticlechemistry.chemical_compoundkemialliset sidoksetPyridineGeneral Materials Sciencelcsh:Microscopypolymeeritlcsh:QC120-168.85chemistry.chemical_classificationHalogen bondlcsh:QH201-278.5010405 organic chemistrylcsh:TPolymerkompleksiyhdisteetCopper3. Good health0104 chemical sciencesCrystallographyhalopyridineschemistrylcsh:TA1-2040copperHalogenFluorinehalogeenisidoksetlcsh:Descriptive and experimental mechanicshalogen bondlcsh:Electrical engineering. Electronics. Nuclear engineeringlcsh:Engineering (General). Civil engineering (General)lcsh:TK1-9971
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CCDC 1938866: Experimental Crystal Structure Determination

2020

Related Article: S. Maryamdokht Taimoory, Kwaku Twum, Mohadeseh Dashti, Fangfang Pan, Manu Lahtinen, Kari Rissanen, Rakesh Puttreddy, John F. Trant, Ngong Kodiah Beyeh|2020|J.Org.Chem.|85|5884|doi:10.1021/acs.joc.0c00220

pyridinium trifluoroacetateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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Superconducting tunnel junction fabrication on three-dimensional topography based on direct laser writing

2020

Superconducting junctions are widely used in a multitude of applications ranging from quantum information science and sensing to solidstate cooling. Traditionally, such devices must be fabricated on flat substrates using standard lithographic techniques. In this study, we demonstrate a highly versatile method that allows for superconducting junctions to be fabricated on a more complex topography. It is based on maskless direct laser writing and two-photon lithography, which allows writing in 3D space. We show that high-quality normal metal–insulator–superconductor tunnel junctions can be fabricated on top of a 20-lm-tall three-dimensional topography. Combined with conformal resist coating m…

quantum informationspin coatingcryogenicsnanoelektroniikkaphononic crystalsuperconductor-insulator-superconductor tunnel junctionnanotekniikkatemperature metrologymultiphoton lithographyrefrigeratorselectron tunnelingsuprajohteet
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Practical Strategies for Stable Operation of HFF-QCM in Continuous Air Flow

2013

Currently there are a few fields of application using quartz crystal microbalances (QCM). Because of environmental conditions and insufficient resolution of the microbalance, chemical sensing of volatile organic compounds in an open system was as yet not possible. In this study we present strategies on how to use 195 MHz fundamental quartz resonators for a mobile sensor platform to detect airborne analytes. Commonly the use of devices with a resonant frequency of about 10 MHz is standard. By increasing the frequency to 195 MHz the frequency shift increases by a factor of almost 400. Unfortunately, such kinds of quartz crystals tend to exhibit some challenges to obtain a reasonable signal-to…

quartz crystal microbalance; high fundamental frequency; allan deviation; turbulences; laminar flow element; acceleration sensitivity; temperature gradientSensors; Volume 13; Issue 9; Pages: 12012-12029
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CCDC 642893: Experimental Crystal Structure Determination

2007

Related Article: C.Peifer, D.Schollmeyer, M.Tschertsche, S.Laufer|2007|Acta Crystallogr.,Sect.E:Struct.Rep.Online|63|o1551|doi:10.1107/S1600536807009300

rac-(3E3aR6aR)-3-(Hydroxymethylene)-33a66a-tetrahydro-2H-cyclopenta(b)furan-2-oneSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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Crystal field and magnetism with Wannier functions: Rare-earth doped aluminum garnets

2015

Using the recently developed method we calculate the crystal field parameters in yttrium and lutetium aluminum garnets doped with seven trivalent Kramers rare-earth ions. We then insert calculated parameters into the atomic-like Hamiltonian taking into account the electron-electron, spin-orbit and Zeeman interactions and determine the multiplet splitting by the crystal field as well as magnetic $\hat{g}$ tensors. We compare calculated results with available experimental data.

rare earthsWannier functionZeeman effectStrongly Correlated Electrons (cond-mat.str-el)Condensed matter physicsMagnetismab initio calculationsFOS: Physical scienceschemistry.chemical_elementGeneral ChemistryYttriumLutetiumIongarnetssymbols.namesakeCondensed Matter::Materials ScienceCondensed Matter - Strongly Correlated ElectronschemistryGeochemistry and PetrologysymbolsCondensed Matter::Strongly Correlated ElectronsHamiltonian (quantum mechanics)crystal fieldMultiplet
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