Search results for "Crystallization"
showing 10 items of 774 documents
Spin crossover in hexakis(1-(2-chloroethyl)-tetrazole)iron(II) complexes; synthesis and magnetic properties
2002
Abstract The spin-crossover complexes [Fe(teec)6](X)2 (with teec=1-(2-chloroethyl)-tetrazole and X=BF4, ClO4, PF6) possess two iron(II) sites each having a different spin-crossover behaviour. The magnetic behaviour of the complexes obtained by slow crystallisation differs strongly from those obtained by precipitation. This difference results in either a spin crossover of 50% (X=ClO4, crystalline), two gradual steps (X=BF4, PF6), or two steps, of which one is gradual and the other having a thermal hysteresis (X=ClO4 precipitated). Both 57Fe Mossbauer spectroscopy and magnetic susceptibility measurements have been recorded as a function of T. The crystal structure of [Fe(teec)6](BF4)2 has bee…
Formation of two-dimensional crystals of icosahedral RNA viruses.
2007
International audience; The formation of 2D arrays of three small icosahedral RNA viruses with known 3D structures (tomato bushy stunt virus, turnip yellow mosaic virus and bromegrass mosaic virus) has been investigated to determine the role of each component of a negative staining solution containing ammonium molybdate and polyethylene glycol. Virion association was monitored by dynamic light scattering (DLS) and virus array formation was visualised by conventional transmission electron microscopy and cryo-electron microscopy after negative staining. The structural properties of viral arrays prepared in vitro were compared to those of microcrystals found in the leaves of infected plants. A…
Controls on lineation development in low to medium grade shear zones: a study from the Cap de Creus peninsula, NE Spain
2002
Lineations composed of similarly oriented elongate mineral aggregates or grains are a common feature in deformed rocks, but it is unclear which factors control the development of such lineations. Field observations and microstructural analysis of samples, which were taken from discrete greenschist to lower amphibolite facies shear zones of the easternmost Variscan Pyrenees, show that strain is only one of several factors that control the strength and type of a lineation. Dynamic recrystallization, metamorphic reactions and rigid body rotation are also important controlling factors for the development of lineations. The most important of these is dynamic recrystallization. The way in which d…
Supramolecular architectures formed by co-crystallization of bile acids and melamine
2010
Supramolecular multicomponent crystals constructed from three different bile acids (viz. lithocholic, deoxycholic and cholic acid) and melamine have been prepared and the non-covalent interactions in the crystals studied. Both salts and co-crystals were found. While deoxycholic and cholic acid co-crystallized with melamine as a 1 : 1 isostructural molecular complexes in space group C2, lithocholic acid formed with melamine a 2 : 1 molecular complex in space group P21. This is the first report on a multicomponent crystal structure containing lithocholic acid.
Cubic and rhombohedral Ba4Lu3F17:Er3+ in transparent glass ceramics: Crystallization and upconversion luminescence
2018
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Protein mapping of calcium carbonate biominerals by immunogold
2007
The construction of metazoan calcium carbonate skeletons is finely regulated by a proteinaceous extracellular matrix, which remains embedded within the exoskeleton. In spite of numerous biochemical studies, the precise localization of skeletal proteins has remained for a long time as an elusive goal. In this paper, we describe a technique for visualizing shell matrix proteins on the surface of calcium carbonate crystals or within the biominerals. The technique is as follows: freshly broken pieces of biominerals or NaOCl then EDTA-etched polished surfaces are incubated with an antibody elicited against one matrix protein, then with a secondary gold-coupled antibody. After silver enhancement,…
Caspartin and calprismin, two proteins of the shell calcitic prisms of the Mediterranean fan mussel Pinna nobilis.
2005
We used the combination of preparative electrophoresis and immunological detection to isolate two new proteins from the shell calcitic prisms of Pinna nobilis, the Mediterranean fan mussel. The amino acid composition of these proteins was determined. Both proteins are soluble, intracrystalline, and acidic. The 38-kDa protein is glycosylated; the 17-kDa one is not. Ala, Asx, Thr, and Pro represent the dominant residues of the 38-kDa protein, named calprismin. An N-terminal sequence was obtained from calprismin. This sequence, which comprises a pattern of 4 cysteine residues, is not related to any known protein. The second protein, named caspartin, exhibits an unusual amino acid composition, …
Keyhole limpet hemocyanin (KLH), II: Characteristic reassociation properties of purified KLH1 and KLH2.
1997
Subunits of the two types of keyhole limpet hemocyanin (KLH1 and KLH2), purified by gel filtration chromatography and preparative polyacrylamide gel electrophoresis from Immucothel, have been used for macromolecular reassociation studies. In-vitro reassociation has been achieved with a standardized system using a Tris-saline stabilizing buffer at pH 7.4 containing 100 mM calcium and magnesium chloride at 4 degrees C. The relatively slow progress of reassociation has been monitored and the varying oligomeric forms of KLH1 and KLH2 produced have been studied by transmission electron microscopy, using specimens negatively stained with 5% ammonium molybdate containing 1% trehalose. Specimens ha…
Carbonate-coordinated metal complexes precede the formation of liquid amorphous mineral emulsions of divalent metal carbonates†
2011
During the mineralisation of metal carbonates MCO3 (M = Ca, Sr, Ba, Mn, Cd, Pb) liquid-like amorphous intermediates emerge. These intermediates that form via a liquid/liquid phase separation behave like a classical emulsion and are stabilized electrostatically. The occurrence of these intermediates is attributed to the formation of highly hydrated networks whose stability is mainly based on weak interactions and the variability of the metal-containing pre-critical clusters. Their existence and compositional freedom are evidenced by electrospray ionization mass spectrometry (ESI-MS). Liquid intermediates in non-classical crystallisation pathways seem to be more common than assumed.
Solid-State NMR, X-ray Diffraction, and Thermoanalytical Studies Towards the Identification, Isolation, and Structural Characterization of Polymorphs…
2009
Combined solid-state NMR, powder, and single crystal X-ray diffraction, as well as thermoanalytical studies were performed towards the identification, isolation, and structural characterization of ...