Search results for "Crystallization"

Toward potent antibiofilm degradable medical devices: A generic method for the antibacterial surface modification of polylactide

2013

International audience; The effects of biomaterials on their environment must be carefully modulated in most biomedical applications. Among other approaches, this modulation can be obtained through the modification of the biomaterial surface. This paper proposes a simple and versatile strategy to produce non-leaching antibacterial polylactide (PLA) surfaces without any degradation of the polyester chains. The method is based on a one-pot procedure that provides a "clickable" PLA surface via anionic activation which is then functionalized with an antibacterial quaternized poly(2-(dimethylamino)ethyl methacrylate) (QPDMAEMA) by covalent immobilization on the surface. The anti-adherence and an…

Heterogeneous crystallization of zinc hydroxystannate on galvanized steel for enhancing the bond strength at the rebar/concrete interface

2021

Abstract Zinc hydroxystannate (ZnSn(OH)6) coatings were deposited on galvanized carbon steel samples by an electroless heterogeneous crystallization process. Structural and morphological features of the coatings as a function of the immersion time were determined by X-ray diffraction, Raman Spectroscopy and Scanning Electron Microscopy revealing the presence of truncated octahedrons of crystalline ZnSn(OH)6. Electrochemical characterization in a simulated concrete pore solution without and with addition of chloride ions proved that the cathodic protection is preserved and that ZnSn(OH)6 improved the corrosion resistance of the rebars. Pull-out tests demonstrated an enhanced bond strength at…

Structural investigation of crystallized Ge-Ga-Se chalcogenide glasses

2018

H. Klym thanks to the Ministry of Education and Science of Ukraine for support and Dr. P. Demchenko for the assistance in XRD experiments.

Microwave-induced electromigration in multicomponent metallic alloys

2010

The crystallization of amorphous FeCoCuZrAlSiB alloy ribbons during microwave heating was investigated in situ using time-resolved X-ray powder diffraction. The formation of the nanocrystalline α-(Fe,Co)(SiAl) phase during the primary crystallization stage is followed by the crystallization of the residual glassy matrix. Scanning electron microscopy analysis after microwave exposure reveals the formation of nanosized hillocks evenly distributed over the ribbon surfaces. Local chemical composition analysis by energy-dispersive spectroscopy shows that the surface clusters are enriched in Cu and Al. The occurrence of this typical electromigration effect imposes a strong restriction on the dura…

Measurement of the self-intermediate scattering function of suspensions of hard spherical particles near the glass transition

1998

Dynamic light-scattering measurements are reported for suspensions at concentrations in the vicinity of the glass transition. In a mixture of identically sized but optically different particles having hard-sphere-like interactions, we project out the incoherent (or self-) intermediate scattering functions by adjusting the refractive index of the suspending liquid until scattering from the structure is suppressed. Due to polydispersity, crystallization is sufficiently slow so that good estimates of ensemble-averaged quantities can be measured for the metastable fluid states. Crystallization of the suspensions is still exploited, however, to set the volume fraction scale in terms of effective…

Speciation of Substituted Benzoic Acids in Solution: Evaluation of Spectroscopic and Computational Methods for the Identification of Associates and T…

2021

Crystal Inclusions in Diamonds and Other Crystals

2013

Single crystal inclusions in natural single crystals bear a lot of information on the genesis and phase stabilities between host and guest crystals. Not only parameters of the natural environment of crystallization may be elucidated, also the history of up-rise within the earth to the surface and the development during procedures, eventually applied by mankind to enhance the physical properties of crystals, may be detectable. Structural reactions resulting in phase separation due to chemical stress during change of physical parameters shed light on the borders of solid solution and exsolution domains. Natural crystals of proper quality allow us to evaluate a time factor in phase stabilities…

Nucleus-driven crystallization of amorphous Ge2Sb2Te5: A density functional study

2012

Early stages of nucleus-driven crystallization of the prototype phase change material Ge${}_{2}$Sb${}_{2}$Te${}_{5}$ have been studied by density functional/molecular dynamics simulations for amorphous samples (460 and 648 atoms) at 500, 600, and 700 K. All systems assumed a fixed cubic seed of 58 atoms and 6 vacancies. Crystallization occurs within 600 ps for the 460-atom system at 600 and 700 K, and signs of crystallization (nucleus growth, percolation) are present in the others. Crystallization is accompanied by an increase in the number of ``$ABAB$ squares'' ($A$: Ge, Sb, $B$: Te), and atoms of all elements move significantly. There is no evidence of cavity movement to the crystal-glass…

Recrystallization in subsurface zone seen by positron annihilation

2010

Abstract The paper presents studies of the defect distribution, detected by the positron annihilation method in the subsurface zone (SZ) of copper samples after dry sliding wear. It takes advantage of a new experimental technique based on scanning of the positron implantation profile. It allowed us to detect the defect profile in copper to the depth of 200 μm in a nondestructive way and study isochronal annealing behavior of this profile. We determined that annealing induces a recrystallization process which runs faster close to the surface than in deeper regions. After sliding, the complete recrystallization of the substructure takes place at temperature c.a. 600 °C. Some changes in the de…

Dynamics of crystallization in hard-sphere suspensions.

1996

Density fluctuations are monitored by small-angle light scattering during the crystallization of 0.22-\ensuremath{\mu}m-radius, hard colloidal spheres. Measured structure factors show an intensity maximum at finite-scattering vectors. The shape of the intensity distribution scales at early times during nucleation and growth and again at large times during ripening. At intermediate times there is a crossover region where scaling ceases to be valid. Both the amplitude and the position of the maximum intensity show quasi-power law behavior in time. The values of the observed exponents are within the range expected for classical growth models. The breadth of the intensity distribution increases…