Search results for "Crystallization"
showing 10 items of 774 documents
Charge-Induced Deformation of the 4He Solid-Superfluid Interface
1984
The interface between solid and superfluid 4He has revealed unusual dynamic properties. Characteristic of this quantum system are the very high thermal conductivity of the superfluid phase, and an extremely small heat of fusion below temperatures of about 1 K. As a result, equilibrium at the solid-superfluid 4He interface is established quite rapidly, which gives rise, e.g., to melting — crystallization waves [1,2] — similar in appearance to surface waves on a free liquid surface — and to anomalous transmission of sound [3].
Ripening-dominated crystallization in polydisperse hard-sphere-like colloids
2009
We report on the crystal growth scenario in gravity-matched, polydisperse hard-sphere-like colloids at increasing particle concentration. In the fluid-crystal coexistence region, the crystal size as a function of time shows two separate regimes corresponding to crystal growth and crystal ripening. At higher supersaturation the crystal size grows according to the same power law through the whole experimental window of a few days: crystal growth and ripening merge together. We show that our observations cannot be explained by considering the slowing down of single-particle dynamics due to increasing volume fraction. We suggest that size fractionation occurring at the crystal-fluid interface i…
Porphyroblast crystallization kinetics: the role of the nutrient production rate
2011
The mechanisms that govern porphyroblast crystallization are investigated by comparing quantitative textural data with predictions from different crystallization models. Such numerical models use kinetic formulations of the main crystallization mechanism to predict textural characteristics, such as grain size distributions. In turn, data on porphyroblast textures for natural samples are used to infer which mechanism dominated during their formation. Whereas previous models assume that the rate-limiting step for a porphyroblast producing reaction is either transport or growth, the model advanced in this study considers the production of nutrients for porphyroblasts as a potentially rate-limi…
Supramolecular chirality and symmetry breaking of fluoride complexes of achiral foldamers
2017
Aromatic oligoamide foldamers containing a central pyridine-2,6-dicarbonyl motif are partially preorganized to favor the binding of fluoride anions. In the solid state, the foldamer-fluoride complexes form achiral, polar and chiral crystal structures depending on the chemical structure of the foldamer. One of the six foldamers studied here, a C2v symmetrical foldamer (1), formed repeatedly chiral crystal structures when crystallized with tetra-butylammonium fluoride, showing supramolecular bulk chirality and symmetry breaking in crystallization.
Influence of surface morphology on melting of polymer crystals II. Loops of random length and partially random reentry
1972
Abstract The melting behavior of single crystals with loops of random length and partially random reentry has been calculated under two different assumptions: (1) at each temperature the loops have an equilibrium end-to-end distance distribution and (2) a certain end-to-end distance distribution of the loops, ω(h), determined by the kinetics of the crystallization is frozen in and maintained during the whole heating process. The ω(h) is calculated by considering the loop formation process during crystallization and by introducing a parameter λ which expresses the tendency of the chains for adjacent reentry. In both cases a melting range is obtained. In case 2, the melting range depends stro…
Control of CaCO3 Crystallization by Demixing of Monolayers
2006
In this paper we describe how to template a demixed monolayer into a spatially patterned inorganic replica. For this purpose a new amphiphilic monomer was synthesized which can be polymerized both in solution and in the monolayer of a Langmuir-Blodgett (LB) trough. Since it inhibits the crystallization of CaCO3, it can be used--in combination with stearic acid (nucleation-promotor)--to control CaCO3 crystals formed under the monolayer. Investigations of the two-component monolayer (Langmuir isotherms and AFM measurements of transferred films) show--in the biphasic region--demixing in solid analogue stearic acid domains and the liquid analogue phase of the monomer. Crystallization of CaCO3 s…
Different Dissolution Media Lead to Different Crystal Structures of Talinolol with Impact on Its Dissolution and Solubility
2003
During the performance of dissolution tests with immediate and controlled-release talinolol tablets it was detected that the type of the buffer used as dissolution medium had a strong influence on the solubility and the dissolution behavior of the drug. It was proven that talinolol appeared in different crystal structures with strongly differing solubilities when pure water, acetate, or phosphate buffers were employed as dissolution media. The resulting crystal structures were characterized by means of light microscopy, differential scanning calorimetry, and X-ray powder diffraction. All methods were adjuvant to detect changes in talinolol crystal structures. The different solubility and di…
Preparation and properties of poly(L-lactic acid) scaffolds by thermally induced phase separation from a ternary polymer-solvent system
2004
Poly(L-lactic acid) (PLLA) foams for tissue engineering were prepared via thermally induced phase separation of a ternary system PLLA/dioxane/tetrahydrofuran (THF) followed by double solvent exchange (water and ethyl alcohol) and drying. An extension to solidification from solution of a previously developed method for solidification from the melt was adopted. The technique is based on a continuous cooling transformation (CCT) approach, consisting in recording the thermal history experienced by rapidly cooled samples and then analyzing the resulting sample morphology. Different foams were produced by changing the relative amount of dioxane and THF in the starting solution while the amount of…
Study of the ZnO crystal growth by vapour transport methods
2004
Abstract The crystal growth of ZnO by vapour transport is classically made with the assistance of additional species that produce a gaseous mixture, the role of which remains often uncertain in the transport and growth process. Initially, in order to study the mass transport process, a numerical simulation is made to analyse which are the requirements to have an effective transport. As the pressure of each gaseous species is generally unknown, the numerical study has been performed for different total pressures. It is found that, if congruent and equilibrium conditions are assumed at the sublimation and crystallisation interfaces, effective growth conditions can only be attained for a narro…
Investigation of thermal stability of ethylene copolymers with POSS - Study under static and dynamic conditions
2018
Abstract In the paper there was studied thermal stability of a series of ethylene copolymers with monoalkenylsiloxy- or monoalkenylsilsesquioxanes (POSS) under dynamic and static conditions. The copolymers proved to be more thermally stable than neat polyethylene and neat silsesquioxane comonomers. The kind and the content of the POSS units significantly affected degradation of the copolymers. Thermal oxidation process resulted in structural changes of the (co)polymers as it was evidenced by the variations in the kind and content of carbonyl, as well as by unsaturated end groups. Depending on the structure of the POSS comonomer incorporated into the polymer chain, the silsesquioxane units o…