Search results for "Crystallization"
showing 10 items of 774 documents
Spontaneous Resolution of an Electron‐Deficient Tetrahedral Fe4L4cage
2015
A highly electron-deficient C3-symmetric tris(bipyridyl) ligand was prepared in four steps and used for the coordination of Fe(OTf)2, thereby resulting in the homochiral assembly of a new family of robust tetrahedral M4L4 cages. This homochiral T-symmetric cage containing a relatively large cavity of 330 A(3) is capable of encapsulating an anionic guest, as was determined by mass spectrometry, (19)F NMR spectroscopy, and finally shown from its crystal structure. Moreover, crystallization of the cage from CH3CN led to crystals containing both (ΔΔΔΔ and ΛΛΛΛ) enantiomers, while crystallization from CH3 OH resulted in crystals containing only the right-handed (ΔΔΔΔ) cage. The difference in the…
Expression, purification, crystallization and preliminary X-ray analysis of perakine reductase, a new member of the aldo-keto reductase enzyme superf…
2006
Perakine reductase (PR) is a novel member of the aldo-keto reductase enzyme superfamily from higher plants. PR from the plant Rauvolfia serpentina is involved in the biosynthesis of monoterpenoid indole alkaloids by performing NADPH-dependent reduction of perakine, yielding raucaffrinoline. However, PR can also reduce cinnamic aldehyde and some of its derivatives. After heterologous expression of a triple mutant of PR in Escherichia coli, crystals of the purified and methylated enzyme were obtained by the hanging-drop vapour-diffusion technique at 293 K with 100 mM sodium citrate pH 5.6 and 27% PEG 4000 as precipitant. Crystals belong to space group C222(1) and diffract to 2.0 A, with unit-…
Equilibrium fluid-crystal interfacial free energy of bcc-crystallizing aqueous suspensions of polydisperse charged spheres
2015
The interfacial free energy is a central quantity in crystallization from the meta-stable melt. In suspensions of charged colloidal spheres, nucleation and growth kinetics can be accurately measured from optical experiments. In previous work, from this data effective non-equilibrium values for the interfacial free energy between the emerging bcc-nuclei and the adjacent melt in dependence on the chemical potential difference between melt phase and crystal phase were derived using classical nucleation theory. A strictly linear increase of the interfacial free energy was observed as a function of increased meta-stability. Here, we further analyze this data for five aqueous suspensions of charg…
Solution and recrystallisation processes and associated landforms in gypsum outcrops of Sicily
2003
Abstract Four small areas of Messinian (Upper Miocene) age gypsum, outcropping in western Sicily, are described. Messinian age evaporites are found in Sicily over a 1000-km 2 area. Here, gypsum outcrops extensively as a consequence of soil erosion induced by human impact. Geomorphological maps show how the rocky surfaces are characterized by a wide range of forms. There are large, medium, small, and microsized forms, which can be identified as belonging to different morphotypes. The morphotypes can be classified into two main categories: those that originated by solution and those that originated through recrystallisation. Four areas, illustrated by geomorphological maps, were specifically …
Intrusion age of Pan-African augen gneisses in the southern Menderes Massif and the age of cooling after Alpine ductile extensional deformation
1996
AbstractPb–Pb single zircon ages of 546.2 ± 1.2 Ma demonstrate that the augen gneisses in the southern Menderes Massif were generated from Pan-African intrusions. During the Alpine orogenic evolution of the Menderes Massif these granites were metamorphosed and transformed into augen gneiss in an extensional top-to-the-south shear zone, located between augen gneisses and overlying schists. Quartz fabrics suggest a pronounced static recrystallization that post-dates the ductile deformation in the shear zone. Ar–Ar muscovite ages of 43–37 Ma from augen gneisses and schists suggest that ductile deformation and subsequent cooling occurred in the Eocene. These results contradict previous models t…
The Proterozoic P–T–t Evolution of the Kemp Land Coast, East Antarctica; Constraints from Si-saturated and Si-undersaturated Metapelites
2007
Integrated metamorphic and geochronological data place new constraints on the metamorphic evolution of a Neoproterozoic orogen in east Antarctica. Granulite-facies rocks from a 150 km stretch of the Kemp Land coast reflect peak conditions involving T � 870^9908 Ca t P� 7� 4^10 kbar, with pressure increasing westward towards an Archaean craton. Electron microprobe-derived (Th þ U)^Pb monazite ages from metapelitic assemblages indicate that the major mineral textures in these rocks developed during the c. 940 Ma Rayner Orogeny. Complex compositional zoning in monazite suggests high-T recrystallization over c. 25 Myr. Diversity in metapelitic reaction textures reflects silica and ferromagnesia…
The olivine macrocryst problem: New insights from minor and trace element compositions of olivine from Lac de Gras kimberlites, Canada
2015
This study presents detailed petrographical and geochemical investigations on remarkably fresh olivines in kimberlites from the EKATI Diamond Mine™ located in the Tertiary/Cretaceous Lac de Gras kimberlite field within the Slave craton of Canada. Olivine, constituting about 42 vol.% of the analyzed samples, can be divided into two textural groups: (i) macrocrystic olivines, > 100 μm sub-rounded crystals and (ii) groundmass olivines, < 100 μm subhedral crystals. Olivines from both populations define two distinct chemical trends; a “mantle trend” with angular cores, showing low Ca (< 0.1 wt.% CaO) and high Ni (0.3–0.4 wt.% NiO) at varying Mg# (0.86–0.93), contrasts with a “melt trend” typifie…
Late Neoarchean synchronous TTG gneisses and potassic granitoids in southwestern Liaoning Province, North China Craton: Zircon U-Pb-Hf isotopes, geoc…
2019
Abstract Abundant late Neoarchean granitoids occur in southwestern Liaoning Province, part of the Eastern Ancient Terrane of the North China Craton. These rocks include intermediate gneiss, TTG gneisses and potassic granitoids, and we report on the geochemistry and zircon SHRIMP ages as well as Hf-in-zircon isotopes of these granitoids in order to determine their petrogenesis. Field relationships suggest that most of these granitoids experienced widespread metamorphism and deformation, associated with anatexis at some localities. The intermediate gneisses, TTG gneisses and potassic granitoids were all emplaced at the end of the Neoarchean (2.50–2.53 Ga), and CL images document widespread re…
Reworking of Archaean and Palaeoproterozoic crust in the Mozambique belt of central Tanzania as documented by SHRIMP zircon geochronology
2005
Abstract New SHRIMP zircon ages for high-grade rocks from the Pan-African Mozambique belt (MB) of central Tanzania document reworking of Archaean–Palaeoproterozoic crust during the formation of this Neoproterozoic collisional orogen. Several gneisses and granulites from the Great Ruaha river area yielded late Archaean emplacement ages of 2575–2680 Ma for their magmatic precursors. Core-rim relationships in some zircons revealed new zircon growth during relatively short episodes of granitoid magmatism. Metamorphic zircons, dated at 1925 Ma, provide new evidence for high-grade metamorphism during formation of the Palaeoproterozoic Usagaran mobile belt. Metamorphic rims around magmatic cores i…
Evolution of intermolecular contacts with temperature and pressure in bromoethane and iodoethane – a comparative study
2022
At ambient conditions two liquids, bromoethane, C2H5Br (MBE, m.p. 154.6 K) and iodoethane, C2H5I (MIE, m.p. 162.1 K), have been crystallized under both isobaric and isochoric conditions using in situ low-temperature and high-pressure techniques. The single-crystal X-ray diffraction studies, supported by the isothermal compressibility and isobaric differential scanning calorimetry measurements, allowed the monitoring and analysis at low temperature and high pressure of the effects of externally induced changes in MBE and MIE. The monoclinic MBE and MIE crystals are found to be isostructural. They are stable, in the investigated regimes, i.e. down to 100 K/0.1 MPa and up to ∼295 K/3.7 GPa, …