Search results for "Cu2"
showing 5 items of 15 documents
Redshift of absorption threshold of TiO2 Nanotubes due to Cu2O electrodeposition
2013
Rare Crystal Structure of Open Spirolactam Ring along with the Closed-Ring Form of a Rhodamine Derivative : Sensing of Cu2+ Ions from Spinach
2019
Crystal structures of a rhodamine derivative in its closed and open spirolactam ring forms were developed, which allows selective and sensitive detection of Cu2+ ions at a micromolar range in neutral medium. The chemosensing properties of the probe through a pentacoordinate Cu2+ ions were proven by spectroscopic and theoretical analysis. The spirolactam ring opening as the Cu2+selective sensor was applied to spinach (Spinacia oleracea) to estimate the accumulation of copper as copper(II) in the plant. peerReviewed
Cu2+-Induced formation of cage-like compounds containing pyrazole macrocycles
2002
The crystal structure of the complex [Cu4(H22L)2(H2O)2- (ClO4)2](ClO4)2·2H2O where L is a new pyrazole ligand containing 1,5-diaminopentane spacers represents a new form of obtaining metal ion-induced inorganic–organic cages. Escarti Alemany, Francisco, franesa@alumni.uv.es ; Latorre Saborit, Julio, Julio.Latorre@uv.es ; Garcia-España Monsonis, Enrique, Enrique.Garcia-Es@uv.es
Binuclear Cu2+ complex mediated discrimination between L-glutamate and L-aspartate in water.
2005
L-Glutamate and L-aspartate selectivity is achieved by the action of two Cu2+ metal ions rightly disposed in a cyclophanetype macrocyclic framework; electrochemical sensing of glutamate has been achieved by adsorption of the copper complexes on graphite electrodes. Verdejo Viu, Begoña, Begona.Verdejo@uv.es ; Domenech Carbo, Antonio, Antonio.Domenech@uv.es ; Jimenez Garcia, Hermas Rafael, Hermas.Jimenez@uv.es ; Soriano Soto, Concepción, Concepcion.Soriano@uv.es ; Garcia-España Monsonis, Enrique, Enrique.Garcia-Es@uv.es
Bi-2212 and Y123 highly curved single-crystal-like objects: whiskers, bows and ring-like structures
2012
High-temperature superconducting objects of Bi2Sr2CaCu2O8 and Y Ba2Cu3O7 highly curved in the ab-plane, such as curved/kinked whiskers, bows and ring-like structures, were obtained within a solid?liquid?solid (SLS) grass-like growth mechanism. As-grown objects are crystals with three-dimensional epitaxy similar to conventional single crystals: they can be viewed as crystal parts ?cut? from a conventional rectangular crystal. Between our curved objects and conventional crystals, whiskers or thin films there are some differences in the superconducting properties induced only by the shape factors and no new physics is observed. Some details of the growth mechanism are discussed, emphasizing cu…