Search results for "Cyclopropene"
showing 2 items of 12 documents
Effects of 1-methylcyclopropene on postharvest quality of white- and yellow-flesh loquat (Eriobotrya japonicaLindl.) fruit
2014
Introduction. The effects of 1-methylcyclopropene (1-MCP) were evaluated on white-flesh cv. Claudia and yellow-flesh cv. Nespolone di Trabia loquat fruit. Materials and methods. Application of 1-MCP ((0.5 to 1) µL⋅L -1 for 20 h)) was monitored at 20 °C (7 days) and 0 °C (7 days at 0 °C and then 7 days at 20 °C). Results. Treatments with 1-MCP slowed fruit softening, depending on the concentration. Softening inhibition was greatest in fruit treated and held at 20 °C. The optimum concentration for softening inhibition at 20 °C was 1µ L ⋅L -1 of 1-MCP, while 0.5 µL⋅L -1 of 1-MCP was more effective at 0 °C. Conclusion. Treatments with 1-MCP inhibited titratable acidity loss in both cultivars. 1…
A theoretical determination of the electronic spectrum of Methylenecyclopropene
1996
The vertical electronic spectrum of methylenecyclopropene, the prototype of the nonalternant hydrocarbons known as fulvenes, has been studied using multiconfigurational second-order perturbation theory. The calculations comprise three valence states and the 3s, 3p, and 3d members of the Rydberg series converging to the first π ionization limit. Vertical excitation energies to three valence states are found at 4.13, 6.12, and 6.82 eV. The second of them corresponds to an excitation from the highest occupied σ orbital to a π* orbital, while the other two are π → π* excitations. The third transition gives rise to the most intense feature in the electronic spectrum. The results are rationalized…