Search results for "Cyclotron resonance"
showing 10 items of 171 documents
Theoretical investigations of different excitation modes for Penning trap mass spectrometry
2013
Abstract In Penning trap mass spectrometry the motion of trapped ions is manipulated by external radio-frequency fields. This paper describes a general theoretical framework to classify the various types of excitation of the ion's motional modes, to identify the resonance frequencies, and to find the effective interaction Hamiltonians which are valid in the vicinity of the resonances. Instead of Cartesian or cylindrical coordinates and momenta our theoretical approach uses the complex oscillator amplitudes of the cyclotron, magnetron, and axial oscillators as its basic dynamical variables. Equations of motion are set up, which can be simplified in the vicinity of resonances by the resonatin…
Precision Determination of Cyclotron Frequencies of Free Electrons and Ions
1982
Within the last two decades the electrodynamical storage of electrons and ions developed into an experimental method of great versatility. That this method is now being used in so many different fields of physics and chemistry results primarily from the long storage times which nowadays can be achieved. Under ultrahigh vacuum conditions and in sufficiently strong electromagnetic fields the particles can easily be trapped for hours or even days. This really long storage time offers the possibility of studying reactions of very slow rate to the chemist and of precision measurement of photon-ion interactions to the physicist. The accuracy of photon-ion interaction measurement is finally limite…
The influence of the trapping potential on the attachment of a second electron to stored metal cluster and fullerene anions
2002
Abstract Singly charged anionic clusters are exposed to a bath of simultaneously stored electrons in ion cyclotron resonance (Penning) traps and thus, dianions are produced. The dianion yield is found to be a function of the potential well depth. As an example, the attachment of electrons to size-selected gold cluster anions Au 25 1− from a laser vaporization source has been studied in detail by time-of-flight mass analysis after ejection of all ions from the trap. Furthermore, the investigation is extended to fullerene anions C 70 1− that are produced by laser desorption from a fullerene target in the external source of a Fourier-transform ion cyclotron resonance (FT-ICR) mass spectrometer…
Recent gold cluster studies in a Penning trap
2002
Abstract A progress report is given on the investigation of metal clusters with an ion cyclotron resonance (Penning) trap. The examples are taken from the recent studies on gold clusters. In particular, the monomer and dimer evaporation is monitored as a function of cluster size. For the particular case of Au 7 + this study is expanded to include the energy dependence of the branching ratio. In connection with the sequential decay of Au 8 + the information can be used for a model-free determination of the dissociation energy of Au 8 + . A second line of studies concerns the production, properties and storage behavior of polyanionic gold clusters. Such species have recently been produced by …
The dissociation channels of silver clusters Agn+, 3 ≤ n ≤ 20
1996
Abstract The low energy dissociation channels of silver cluster ions Agn+, 3 ≤ n ≤ 20 are determined by collision-induced dissociation (CID) in a Penning trap. While for most cluster sizes the first fragment cluster ion is produced by monomer evaporation, the fragment ion of small odd-sized clusters has two atoms less than their precursors indicating an evaporation of dimers. The results are compared to similar CID studies on gold cluster ions, photofragmentation patterns, abundance spectra for various silver-cluster production techniques and calculated binding energies.
ESI-FTICR investigation of triethylammonium ion-driven resorcin[4]arene dimer formation and structure
2002
In the course of mass spectrometric measurements a self-assembled hydrogen bonded resorcinarene dimer was observed, the formation of which was driven by the binding of triethylammonium ion as a guest and as an ionic label.
Carbon nanotubes embedded in a polyimide foil for proton acceleration with a sub-ns laser
2021
A series of thin films made of aligned carbon nanotubes (CNTs) embedded in a polyimide substrate was designed, fabricated and used for the first time to accelerate protons and C ions by interaction with a sub-nanosecond, high power laser beam (600 J energy and 300 ps pulse width) with peak intensity of about 3 × 1016 W/cm2 on target. Each target was 5 μm thick, and the composite material contained CNTs aligned in different directions in the substrate. The results obtained from the analysis of a Thomson Parabola spectrometer, and of the spots imprinted by ions on a series of PM355 nuclear track detectors, indicate high energies (up to 3 MeV for protons and 9 MeV for C ions) and a marked infl…
Mass Spectrometric Investigation of Noncovalent Complexation between a Tetratosylated Resorcarene and Alkyl Ammonium Ions
2004
Noncovalent complexation between tetratosylated tetraethyl resorcarene (1) and primary, secondary, and tertiary alkyl ammonium ions (mMe, dMe, tMe, mEt, dEt, tEt, dBu, and dHex) was studied by electrospray ionization Fourier transform ion cyclotron resonance (ESI-FTICR) mass spectrometry. Interactions of the noncovalent complexes were investigated by means of competition experiments, collision-induced dissociation (CID) experiments, ion-molecule reactions with tripropylamine and gas phase H/D-exchange reactions with deuteroammonia. Gas phase ion-molecule reactions gave especially valuable information about the structure and properties of the complexes. Resorcarene 1 formed relatively stable…
The Inchworm as a precision translator in a high magnetic field and UHV environment
1989
Abstract A new set-up has been designed and tested for on-line, high-precision mass measurements of short-lived radioactive isotopes via a determination of the ion cyclotron resonance. Ions delivered by the on-line isotope separator ISOLDE at CERN/Geneva are stored in a Penning trap installed in a superconducting solenoid. Due to severe space limitations in the bore of the solenoid, it is impossible to use conventional mechanical feedthroughs for the necessary manipulations inside the uhv chamber. Instead, a number of Inchworms, a high-precision positioning device based on the piezo-electric effect are employed. This publication reports on the first application of this device in a uhv envir…
Major results from the first plasma campaign of the Wendelstein 7-X stellarator
2017
After completing the main construction phase of Wendelstein 7-X (W7-X) and successfully commissioning the device, first plasma operation started at the end of 2015. Integral commissioning of plasma start-up and operation using electron cyclotron resonance heating (ECRH) and an extensive set of plasma diagnostics have been completed, allowing initial physics studies during the first operational campaign. Both in helium and hydrogen, plasma breakdown was easily achieved. Gaining experience with plasma vessel conditioning, discharge lengths could be extended gradually. Eventually, discharges lasted up to 6 s, reaching an injected energy of 4 MJ, which is twice the limit originally agreed for t…