Search results for "DAS"
showing 10 items of 4164 documents
Conformational relaxation of a low-temperature protein as probed by photochemical hole burning. Horseradish peroxidase
1991
For the first time, conformational relaxation processes have been measured in a small protein, mesoporphyrin-horseradish peroxidase via their influence on spectral diffusion broadening of holes burnt in the fluorescence excitation spectrum of free base mesoporphyrin. Holes were burnt in three 0----0 bands of different tautomeric forms of the chromophore at 1.5 and 4 K, and the spectral diffusion broadening was measured in temperature cycling experiments between 4 and 30 K. The inhomogeneous linewidth for the tautomeric 0----0 bands was estimated to be 60-70 cm-1; the hole width was found narrow, being in the order of 350 MHz (10(-2) cm-1) at 1.5 K what allowed for an extremely sensitive det…
Deep-blue thermally activated delayed fluorescence (TADF) emitters for light-emitting electrochemical cells (LEECs)
2017
The authors acknowledge the University of St Andrews for financial support. The authors also acknowledge financial support from the European Union H2020 project INFORM (grant 675867), the Spanish Ministry of Economy and Competitiveness (MINECO) via the Unidad de Excelencia María de Maeztu MDM-2015-0538, MAT2014-55200 and the Generalitat Valenciana (Prometeo/2016/135). MLP acknowledges support from a Grisolia grant (GRISOLIA/2015/A/146). Two deep blue thermally activated delayed fluorescence (TADF) emitters ( imCzDPS and imDPADPS ) that contain charged imidazolium groups tethered to the central luminophore were designed and synthesized as small molecule organic emitters for light-emitting e…
Enhancing the photoluminescence quantum yields of blue-emitting cationic iridium(iii) complexes bearing bisphosphine ligands
2016
EZ-C acknowledges the University of St Andrews for financial support. We thank Johnson Matthey and Umicore AG for the gift of materials and Cihang Yu for the preparation of isopropxantphos. We thank Dr. Nail Shaveleev for the synthesis of NMS25. IDWS and AKB acknowledge support from EPSRC (EP/J01771X). This work has been supported by the Spanish Ministry of Economy and Competitiveness (MINECO) MAT2014-55200. Herein we present a structure-property relationship study of thirteen cationic iridium (III) complexes of the form of [Ir(C^N)2(P^P)]PF6 in both solution and the solid state through systematic evaluation of six bisphosphine (P^P) ligands (xantphos, dpephos, dppe, Dppe, nixantphos and is…
Green phosphorescence and electroluminescence of sulfur pentafluoride-functionalized cationic iridium(III) complexes
2015
EZ-C acknowledges the University of St Andrews for financial support. We report four cationic iridium(III) complexes [Ir(C^N)2(dtBubpy)](PF6) that have sulfurpentafluoride-modified 1-phenylpyrazole and 2-phenylpyridine cyclometalating (C^N) ligands (dtBubpy = 4,4'-di-tert-butyl-2,2'-bipyridyl). Three of the complexes were characterized by single-crystal X-ray structure analysis. In cyclic voltammetry, the complexes undergo reversible oxidation of iridium(III) and irreversible reduction of the SF5 group. They emit bright green phosphorescence in acetonitrile solution and in thin films at room temperature, with emission maxima between 482–519 nm and photoluminescence quantum yields of up to 7…
Reconnection nanojets in the solar corona
2020
P.A. acknowledges STFC support from grant numbers ST/R004285/2 and ST/T000384/1 and support from the International Space Science Institute, Bern, Switzerland to the International Teams on ‘Implications for coronal heating and magnetic fields from coronal rain observations and modeling’ and ‘Observed Multi-Scale Variability of Coronal Loops as a Probe of Coronal Heating’. This project has received funding from the European Research Council (ERC) under the European Union’s Horizon 2020 research and innovation programme (grant agreement no. 647214). P.T. was also supported by contracts 8100002705 and SP02H1701R from Lockheed-Martin to the Smithsonian Astrophysical Observatory (SAO), and NASA c…
Nonlinear rocking of rigid blocks on flexible foundation: Analysis and experiments
2017
Abstract Primarily, two models are commonly used to describe rocking of rigid bodies; the Housner model, and the Winkler foundation model. The first deals with the motion of a rigid block rocking about its base corners on a rigid foundation. The second deals with the motion of a rigid block rocking and bouncing on a flexible foundation of distributed linear springs and dashpots (Winkler foundation). These models are two-dimensional and can capture some of the features of the physics of the problem. Clearly, there are additional aspects of the problem which may be captured by an enhanced nonlinear model for the base-foundation interaction. In this regard, what it is adopted in this paper is …
Travelling Panels Made of Viscoelastic Material
2013
In this chapter, our focus is to analyse the behaviour of moving panels using viscoelastic materials. As the reader will have noticed, all the models discussed in previous chapters have concerned the case of a purely elastic material. The deformation of an elastic material depends only on the applied forces; it has no explicit time dependence. Paper, however, is a more complicated material: it is viscoelastic. In addition to elastic properties, it has also time-dependent viscous properties, which cause the phenomena of creep and relaxation (see, e.g., Alava and Niskanen 2006). One of the simplest models for a viscoelastic solid is the Kelvin–Voigt model, which consists of a linear spring an…
Electrical analogous in viscoelasticity
2014
In this paper, electrical analogous models of fractional hereditary materials are introduced. Based on recent works by the authors, mechanical models of materials viscoelasticity behavior are firstly approached by using fractional mathematical operators. Viscoelastic models have elastic and viscous components which are obtained by combining springs and dashpots. Various arrangements of these elements can be used, and all of these viscoelastic models can be equivalently modeled as electrical circuits, where the spring and dashpot are analogous to the capacitance and resistance, respectively. The proposed models are validated by using modal analysis. Moreover, a comparison with numerical expe…
Fractional Tajimi–Kanai model for simulating earthquake ground motion
2014
The ground acceleration is usually modeled as a filtered Gaussian process. The most common model is a Tajimi–Kanai (TK) filter that is a viscoelastic Kelvin–Voigt unit (a spring in parallel with a dashpot) carrying a mass excited by a white noise (acceleration at the bedrock). Based upon the observation that every real material exhibits a power law trend in the creep test, in this paper it is proposed the substitution of the purely viscous element in the Kelvin Voigt element with the so called springpot that is an element having an intermediate behavior between purely elastic (spring) and purely viscous (dashpot) behavior ruled by fractional operator. With this choice two main goals are rea…
Regulation of aerobic and anaerobic D-malate metabolism of Escherichia coli by the LysR-type regulator DmlR (YeaT).
2010
ABSTRACT Escherichia coli K-12 is able to grow under aerobic conditions on d -malate using DctA for d -malate uptake and the d -malate dehydrogenase DmlA (formerly YeaU) for converting d -malate to pyruvate. Induction of dmlA encoding DmlA required an intact dmlR (formerly yeaT ) gene, which encodes DmlR, a LysR-type transcriptional regulator. Induction of dmlA by DmlR required the presence of d -malate or l - or meso -tartrate, but only d -malate supported aerobic growth. The regulator of general C 4 -dicarboxylate metabolism (DcuS-DcuR two-component system) had some effect on dmlA expression. The anaerobic l -tartrate regulator TtdR or the oxygen sensors ArcB-ArcA and FNR did not have a m…