Search results for "DF"
showing 10 items of 1699 documents
Oxadiazolyl-pyridines and perfluoroalkyl-carboxylic acids as building blocks for protic ionic liquids: crossing the thin line between ionic and hydro…
2012
A series of 18 samples has been prepared in order to obtain fluorinated materials as Protic Ionic Liquids (PILs). These were synthesized by appropriately mixing 1,2,4-oxadiazoles derivatised with two pyridines, or one pyridine and a fluorinated chain, and perfluoroalkyl-carboxylic acids, either mono- or dicarboxylic, leading to symmetric and non-symmetric materials. Many of them showed low melting points. However, the possibility of classifying the synthesized materials as PILs is discussed in terms of effective ionicity of the systems by the combination of Density Functional Theory (DFT) calculation and IR spectroscopy. The important outcome of our investigation is that the complete proton…
Hierarchical structure and cytocompatibility of fish scales from Carassius auratus
2014
Abstract To study the structure and the cytocompatibility of fish scales from Carassius auratus , scanning electron microscopy (SEM) was used to observe the morphology of fish scales treated with different processing methods. Based on varying morphologies and components, the fish scales can be divided into three regions on the surface and three layers in vertical. The functions of these three individual layers were analyzed. SEM results show that the primary inorganic components are spherical or cubic hydroxyapatite (HA) nanoparticles. The fish scales have an ~ 60° overlapped plywood structure of lamellas in the fibrillary plate. The plywood structure consists of co-aligned type I collagen …
LinkedSaeima: A Linked Open Dataset of Latvia’s Parliamentary Debates
2019
This paper describes the LinkedSaeima dataset that contains structured data about Latvia’s parliamentary debates from 1993 until 2017. This information is published at http://dati.saeima.korpuss.lv as Linked Open Data. It is a part of the Corpus of Saeima (the Parliament of Latvia) released as open data for multidisciplinary research. The data model of LinkedSaeima follows the data structure of the LinkedEP dataset with a few modifications. The dataset is augmented with links to the Wikidata knowledge base that provide additional information about the speakers and named entities mentioned in the corpus.
DFT study on the cycloreversion of thietane radical cations.
2011
The molecular mechanism of the cycloreversion (CR) of thietane radical cations has been analyzed in detail at the UB3LYP/6-31G* level of theory. Results have shown that the process takes place via a stepwise mechanism leading to alkenes and thiobenzophenone; alternatively, formal [4 + 2] cycloadducts are obtained. Thus, the CR of radical cations 1a, b(center dot+) is initiated by C2-C3 bond breaking, giving common intermediates INa,b. At this stage, two reaction pathways are feasible involving ion molecule complexes IMCa,b (i) or radical cations 4a,b(center dot+) (ii). Calculations support that 1a(center dot+) follows reaction pathway (leading to the formal [4 + 2] cycloadducts 5a). By cont…
Through-space spin-spin coupling in acetylenic systems. Ab initio and DFT calculations
2003
Abstract: We have investigated, by means of ab initio and DFT calculations, the magnitude of through-space spin-spin couplings ( J CH and J HH ) in CH/π bonded van der Waals dimers involving acetylene, and in a structurally related covalent compound (4-ethynylphenanthrene). Within regions where the interaction is stabilizing J HH couplings are very small (< 0.1 Hz) for all complexes. In the acetylene-methane complex J CH is also very small, whereas in the acetylene-benzene complex and the acetylene dimer it shows a relatively large dependence on the tilt angle from the T-shaped arrangement, for which the smallest values are calculated, to a parallel slipped arrangement where J CH is ca. 0.5…
Quantum correlation of electron and ion energy in the dissociative strong-field ionization of H2
2023
We report on the strong field ionization of H2 by a corotating two-color laser field. We measure the electron momentum distribution in coincidence with the kinetic energy release (KER) of dissociating hydrogen molecules. In addition to a characteristic half-moon structure, we observe a low-energy structure in the electron momentum distribution at a KER of about 3.5 eV. We speculate that the outgoing electron interacts with the molecular ion, despite the absence of classical recollisions under these conditions. Time-dependent density functional theory simulations support our conclusions.
Combination of measurements of the top-quark pair production cross section from the Tevatron Collider
2014
We combine six measurements of the inclusive top-quark pair (tt̄) production cross section (σtt̄) from data collected with the CDF and D0 detectors at the Fermilab Tevatron with proton-antiproton collisions at s=1.96TeV. The data correspond to integrated luminosities of up to 8.8fb-1. We obtain a value of σtt̄=7.60±0.41pb for a top-quark mass of mt=172.5GeV. The contributions to the uncertainty are 0.20 pb from statistical sources, 0.29 pb from systematic sources, and 0.21 pb from the uncertainty on the integrated luminosity. The result is in good agreement with the standard model expectation of 7.35-0.33+0.28pb at next-to-next-to-leading order and next-to-next-to leading logarithms in pert…
Combined Forward-Backward Asymmetry Measurements in Top-Antitop Quark Production at the Tevatron
2018
The CDF and D0 experiments at the Fermilab Tevatron have measured the asymmetry between yields of forward- and backward-produced top and antitop quarks based on their rapidity difference and the asymmetry between their decay leptons. These measurements use the full data sets collected in proton-antiproton collisions at a center-of-mass energy of √s=1.96 TeV. We report the results of combinations of the inclusive asymmetries and their differential dependencies on relevant kinematic quantities. The combined inclusive asymmetry is At¯tFB=0.128±0.025. The combined inclusive and differential asymmetries are consistent with recent standard model predictions.
A GIS-based approach for gully erosion susceptibility modelling: a test in Sicily, Italy
2013
The aim of this study is to analyze the susceptibility conditions to gully erosion phenomena in the Magazzolo River basin and to test a method that allows for driving the factors selection. The study area is one of the largest (225 km2) watershed of southern Sicily and it is mostly characterized by gentle slopes carved into clayey and evaporitic sediments, except for the northern sector where carbonatic rocks give rise to steep slopes. In order to obtain a quantitative evaluation of gully erosion susceptibility, statistical relationships between the spatial distributions of gullies affecting the area and a set of twelve environmental variables were analyzed. Stereoscopic analysis of aerial …
Gis-analysis to assess landslide susceptibility in a fluvial basin of NW Sicily (Italy).
2008
Abstract Landslide hazard assessment, effected by means of geostatistical methods, is based on the analysis of the relationships between landslides and the spatial distributions of some instability factors. Frequently such analyses are based on landslide inventories in which each record represents the entire unstable area and is managed as a single instability landform. In this research, landslide susceptibility is evaluated through the study of a variety of instability landforms: landslides, scarps and areas uphill from crown . The instability factors selected were: bedrock lithology, steepness, topographic wetness index and stream power index. The instability landform densities computed f…