Search results for "DF"

showing 10 items of 1699 documents

Calculation of magnetic coupling constants with hybrid density functionals

2013

The currently available computational methods for the calculation of magnetic coupling constants with density functional theory have been reviewed. These methods include modern approximations to the exchangecorrelation functional, such as hybrid, range-separated and double-hybrid functionals, as well as approaches to treat the severe spin symmetry problems encountered in density functional calculations of magnetic interactions. In addition to the commonly used unrestricted Kohn–Sham formalism, density functional methods based on multireference wave functions and ensemble densities are also discussed. Performance of these models based on various studies has been summarized. The results indic…

kytkentämagnetic couplingmagnetic coupling constantsDFThybrid functionals
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Semanttiset verkot ja niiden web-sovellukset

2003

Semanttiset verkot ovat formalismeja tietämyksen esittämiseen. Semanttisia verkkoja on sovellettu asiantuntijajärjestelmissä, luonnollisen kielen käsittelyssä ja muissa tekoälyä hyödyntävissä sovelluksissa. Semanttinen web on joukko teknologioita, joiden tarkoitus on saada WWW:n sisältö ja merkitykset helpommin tietokoneen ymmärrettävään muotoon. Tutkielma selvittää semanttisen webin suhdetta olemassaoleviin tietämystekniikan sovelluksiin erityisesti semanttisten verkkojen näkökulmasta.

käsitegraafittietämystekniikkaontologiattietämyksen esittäminensemanttiset verkotlogiikkaaihekartatXMLsemanttinen webtekoälyRDF
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Influence of Distance from the Host on Parasitisation by

2019

The olive fruit fly, Bactrocera oleae, is considered the main olive pest worldwide, and has been the target of biological control programmes through the release of the braconid parasitoid Psyttalia concolor. Laboratory tests were performed to evaluate the influence of distance from the host on parasitisation, placing larvae of the substitute host Ceratitis capitata at seven distances (0, 0.5, 1, 1.5, 2, 2.5, 3 mm) and four different time periods (7, 15, 30, 60 min). Moreover, field collected olives of Ogliarola Barese cultivar infested by B. oleae were exposed to P. concolor females to confirm its ability to parasitise B. oleae in small olives. Psyttalia concolor oviposition was inhibited a…

laboratory hostparasitoid rearingmedflyolive fruit flyArticleovipositor lengthInsects
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Laika perspektīvas, apzinātības un apzinātības prakses saistības

2017

Pētījums “Laika perspektīvas, apzinātības un apzinātības prakses saistība” ir veltīts laika perspektīvas un apzinātības saistībai, kā arī pārmaiņām, pēc apzinātības prakses. Pētījumā piedalījās 66 respondenti, vecumā no 18 līdz 28 gadiem. Pētījumā tika izmantotās Apzinātības piecu aspektu aptauja (Five Facet Mindfulness Scale, Baer, Smith, Hopkins, Krietmeyer, Toney, 2006), un Zimbardo laika perspektīvas aptauja (Zimbardo Time Perspective Inventory, Zimbardo & Boyd, 1999). Noskaidrots, ka zems apzinātības līmenis var būt saistīts ar negatīvu orientāciju uz pagātni (rs=-0,48, p<0,005), fatālistisku attieksmi pret tagadni (rs=-0,33, p<0,005). Atkārtotā mērījuma dati parāda, ka apzinātības pra…

laika perspektīvaapzinātībatime perspektivemindfulnessapzinātības ikdienas praksePsiholoģija
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MODELLING BIOGAS GENERATION AND RELEASE FROM MUNICIPAL SOLID WASTE LANDFILLS

2015

MSW sanitary landfills represent nowadays one of the most important issue related to the waste management cycle. In particular, knowledge about biogas production is a key aspect for a proper exploitation of this energy source, even in the after-care phase. In the present study, a simple mathematical model was proposed for the simulation of biogas production. The model is based on 1st order biodegradation kinetic and takes also into account the temperature variation in time and depth and the landfill settlement. The model was applied to a real landfill located in Sicily (ITALY) and its simulation result was compared with experimental data (volumes of biogas collected by the recovery system a…

landfill lifetimebiogas modellingSettore ICAR/03 - Ingegneria Sanitaria-Ambientalelandfill ga
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DEVELOPMENT TRENDS OF BIOGAS

2015

All over the world, researches are made in order to improve the technologies, the operational and process stability and performance of biogas plants, because the world markets for biogas increased considerably in Europe and all over the world. In this paper we studied the most important parameters related to a biogas plant, starting from the ecologic landfill of Cristian, Sibiu, a landfill which storages industrial and household waste. In this respect, we studied operational parameters, such as organic load and hydraulic retention time, and parameters for evaluation of a biogas plant. Also, we made a case study concerning the evaluation of used waters in the landfill described above under t…

landfillbiogaslcsh:Agriculture (General)lcsh:S1-972operational parametersScientific Papers Series : Management, Economic Engineering in Agriculture and Rural Development
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Direct detection of 17O NMR in [Gd(DOTA)]- by NMR Spectroscopy

2015

The 17O NMR spectrum of the non-coordinated carboxyl oxygen in the GdIII-DOTA (DOTA = tetraazacyclododecanetetraacetic acid) complex has been observed experimentally. Its line width is essentially unaffected by paramagnetic relaxation due to gadolinium, and is only affected by the quadrupole pathway. The results are supported by the relevant parameters (hyperfine and quadrupole coupling constants) calculated by relativistic DFT methods. This finding opens up new avenues for investigating the structure and reactivity of paramagnetic GdIII complexes used as contrast agents in magnetic resonance imaging.

lanthanide complexesLanthanideGadoliniumchemistry.chemical_elementImaging agentsCatalysisNMR spectroscopy; Density functional calculations; lanthanide complexes; gadolinium; O-17 nmrParamagnetismchemistry.chemical_compoundNMR spectroscopyNuclear magnetic resonanceLanthanidesDOTAHyperfine structureChemistryOrganic ChemistryRelaxation (NMR)General ChemistryNuclear magnetic resonance spectroscopyDensity functional calculationsSettore CHIM/03 - Chimica Generale E InorganicaQuadrupole17O NMR Lanthanides DFTCondensed Matter::Strongly Correlated ElectronsgadoliniumO-17 nmr
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Structural and electronic properties of ion-exchangeable layered perovskites

2013

The modification of metal oxide surfaces with organic moieties has been widely studied as a method of preparing organic-inorganic hybrid materials for various applications. Among inorganic oxides, the ion-exchangeable layered perovskites, materials composed by perovskite-like slabs (ABO3, in which B is a small transition metal cation and A is a larger s-, d- or f-block cation) and intercalated cations, stimulated authors’ interest in reason of some encouraging electronic and reactive properties. In particular it is well known that the interlayer surface of layered-perovskites in their protonated form can be easily functionalized with organic groups, such as alcohols, organophosphonic acids,…

layered perosvkite DFT
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Yoga en España. Proceso de regulación profesional

2015

New approaches to spirituality go hand in hand with emerging physical, psychological and spiritual movements that have had a clear impact on many areas, and in particular on health and well-being. It is increasingly common to find nurses teaching yoga or doctors prescribing mindfulness. Use of socalled Complementary and Alternative Medicine (CAM) is becoming mainstream. Health centres, medical practices and even schools are offering a growing number of alternative therapies, resulting in the need for effective legal regulation of these activities, both in terms of professional recognition and training. In Spain, recent legislation represents a significant breakthrough in the regulation of y…

lcsh:Ethnology. Social and cultural anthropologyCultural StudiesLinguistics and Languagemedicine.medical_specialtyMindfulnessAlternative medicineregulación profesionalLegislationmedicinas alternativas y complementarias (mac)Language and LinguisticsGN301-674SpiritualitymedicineMainstreamSociologyDret del treballComplementary and Alternative Medicine (CAM)Literaturenew ageDivergence (linguistics)business.industryProfessional RegulationPublic relationsEthnology. Social and cultural anthropologylcsh:GN301-674yogabusinessRevista de Dialectología y Tradiciones Populares
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Sustainable financing through crowdfunding

2019

The phenomenon of crowdfunding has been widely studied, while the sustainability of crowdfunded ventures is attracting growing interest from academia and society. In light of this interest, we conducted bibliometric analysis to study the relationship between crowdfunding and crowdfunded ventures&rsquo

lcsh:GE1-350lcsh:TD194-195crowdfundinglcsh:Environmental effects of industries and plantslcsh:TJ807-830lcsh:Renewable energy sourcesUNESCO::CIENCIAS ECONÓMICASsocialsustainability:CIENCIAS ECONÓMICAS [UNESCO]lcsh:Environmental sciencesenvironmental
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