Search results for "DF"

Developing mindful organizing in teams: a participation climate is not enough, teams need to feel safe to challenge their leaders

2020

ABSTRACT Mindful organizing (also known as collective mindfulness) is a collective capability that allows teams to anticipate and swiftly recover from unexpected events. This collective capability is especially relevant in high-risk environments where reliability in performance is of utmost importance. In this paper, we build on current mindful organizing theory by showing how two front-line communication and participatory conditions (perceived safety for upward dissent and climate for employee engagement) interact to predict mindful organizing. We shed light on the controversy around mindful organizing’s effect on team’s subjective experience at work by showing that it leads to…

Carbon–Phosphorus Coupling from C^N Cyclometalated Au III Complexes

2020

Abstract With the aim of exploiting new organometallic species for cross‐coupling reactions, we report here on the AuIII‐mediated Caryl−P bond formation occurring upon reaction of C^N cyclometalated AuIII complexes with phosphines. The [Au(C^N)Cl2] complex 1 featuring the bidentate 2‐benzoylpyridine (CCON) scaffold was found to react with PTA (1,3,5‐triaza‐7‐phosphaadamantane) under mild conditions, including in water, to afford the corresponding phosphonium 5 through C−P reductive elimination. A mechanism is proposed for the title reaction based on in situ 31P{1H} NMR and HR‐ESI‐MS analyses combined with DFT calculations. The C−P coupling has been generalized to other C^N cyclometalated Au…

New light on an old debate: Does the RCN-PtCl2 bond include any back-donation? RCN←PtCl2 backbonding: Vs. the IR ν CN blue-shift dichotomy in organon…

2019

For a series of organonitrile [RCN (R = Me, CF3, Ph, CH3Ph, CF3Ph)] ligands, the nature of the N-Pt bond in the related cis-/trans-(RCN)2PtCl2 complexes has been computationally investigated by Density Functional Theory. A fragment based bond analysis has been performed in the canonical Kohn-Sham molecular orbitals framework, and it has been ultimately assessed that this bond is characterized both by N→Pt σ and by N←Pt π contributions. Voronoi Deformation Density charges further confirms the occurrence of N←Pt π interactions. Moreover, the Energy Decomposition Analysis-Natural Orbital for Chemical Valence (EDA-NOCV) method shows that the strength of the N←Pt π interaction is not negligible …

Influence of Vertical Dimension of Occlusion on Peak Force During Handgrip Tests in Athletes

2018

Background: In contact sports, such as martial arts, protection from oral injuries is generally recommended. Several authors have focused on the effects of wearing such oral protective gear on sports performances and, in particular, occlusal devices. Although many studies have shown improvements in athletic performance, especially in maximal isometric strength, to date there is still no consensus on the issue. Objectives: The aim of our study was to evaluate differences in isometric handgrip before and after the application of an occlusal splint (OS) in martial arts athletes. Methods: A repeated measures within-subjects design was adopted for the study. Twenty-five young martial arts athlet…

ON THE WAVE-U-OWC INTERACTION IN A NUMERICAL 2D WAVE FLUME

Several wave energy conversion techniques have been patented all over the world. Despite this large variation in design, the Wave Energy Converters (WECs) are generally categorized by location, type and modes of operation. An Oscillating Water Column consists of a chamber with an opening to the sea below the water line. An OWC consists of a box with a big vertical opening in the front wall. Waves enter through this opening with only some small diffraction effects from the front wall (and they propagate on the water surface in the box. On the roof of the box there is a tube connecting the atmosphere with the air pocket enclosed between the water surface and the roof. This tube contains one o…

Picco di massa ossea ed attività fisica: confronto tra giovani adulti sedentari, attivi e atleti

2009

OBIETTIVO - Valutare, nel periodo di raggiungimento del picco di massa ossea, gli effetti dell’attività fisica sulla mineralizzazione ossea in età giovanile. MATERIALI E METODI - Allo studio hanno partecipato 43 soggetti maschi, sani, con età media di 25 anni, suddivisi in tre gruppi in relazione all’intensità dell’attività fisica svolta dall’età di dieci anni in poi: il primo composto da 17 soggetti sedentari, il secondo da 16 soggetti attivi e il terzo da 15 soggetti atleti. Ogni soggetto è stato sottoposto a mineralometria ossea computerizzata (DEXA). La misurazione della densità ossea (BMD, g/cm2) dei soggetti ha riguardato: corpo intero (Total Body), collo femore dx e sx e tratto rachi…

Observation of s-Channel Production of Single Top Quarks at the Tevatron

2014

We report the first observation of single-top-quark production in the s channel through the combination of the CDF and D0 measurements of the cross section in proton-antiproton collisions at a center-of-mass energy of 1.96 TeV. The data correspond to total integrated luminosities of up to 9.7fb-1 per experiment. The measured cross section is σs=1.29-0.24+0.26pb. The probability of observing a statistical fluctuation of the background to a cross section of the observed size or larger is 1.8×10-10, corresponding to a significance of 6.3 standard deviations for the presence of an s-channel contribution to the production of single-top quarks. © 2014 American Physical Society.

Utilizzo di strumenti free e open source per la fruizione di modelli 3D di siti archeologici basati sul formato PDF

2013

Inductive inference of recursive functions: Complexity bounds

2005

This survey includes principal results on complexity of inductive inference for recursively enumerable classes of total recursive functions. Inductive inference is a process to find an algorithm from sample computations. In the case when the given class of functions is recursively enumerable it is easy to define a natural complexity measure for the inductive inference, namely, the worst-case mindchange number for the first n functions in the given class. Surely, the complexity depends not only on the class, but also on the numbering, i.e. which function is the first, which one is the second, etc. It turns out that, if the result of inference is Goedel number, then complexity of inference ma…

Preparation of pH sensitive poly(vinilydenefluoride) porous membranes by grafting of acrylic acid assisted by supercritical carbon dioxide

2012

Free radical grafting of acrylic acid (AA) on poly(vinilydenefluoride) (PVDF) porous membranes was studied at 65°C using supercritical carbon dioxide (scCO 2) as a solvent and delivery agent. The process was initiated by the thermal decomposition of benzoylperoxide (BPO). Spectroscopic analyses confirmed the presence of poly(AA) chains linked to treated membranes. The mass fraction of grafted AA increased with grafting time and BPO concentration while it decreased when the density of the fluid phase was enhanced. A not-monotonic trend was obtained when the effect of the initial AA concentration was studied. The grafting process was accompanied by a reduction of the crystallinity of the PVDF…