Search results for "DIAGENESI"
showing 10 items of 130 documents
Bulk carbonate isotope stratigraphy from CRP-3 core (Victoria Land Basin, Antarctica): evidence for Eocene–Oligocene palaeoclimatic evolution
2005
Bulk carbonate isotope compositions and carbonate petrography from upper Eocene and lower Oligocene siliciclastic sediments of the CRP-3 sediment core (Victoria Land Basin, Antarctica) have been investigated with the aim of contributing to reconstruction of the Antarctic Cenozoic palaeoclimate. Most of the carbonate is calcite cement occurring as patches, nodules and horizons and consisting of equant and/or drusy sparry calcite, pervasive blocky calcite and rare poikilotopic calcite spar. 18O-depleted values (from −17 to −8 δ‰) of the CRP-3 carbonates suggest that the precipitating fluids were a mixing between marine and meteoric waters from melting glaciers. The δ18O record exhibits a numb…
The beast burrowed, the fluid followed – Crustacean burrows as methane conduits
2015
Abstract An extensive pockmark field with associated methane-seep carbonates has recently been reported from the late Albian (Lower Cretaceous) Ubidepea Mudstone of the Black Flysch Group in the Basque Country, northern Spain, but the exact pathways of the migrating methane-rich fluids remained elusive. Here we provide petrographic, stable carbon and oxygen isotope evidence that abundant crustacean burrows in the surrounding mudstone, preserved as the trace fossil Thalassinoides, and the seep carbonates themselves have acted as long-lasting fluid conduits in this system. The Thalassinoides infill generations show a diagenetic parasequence often starting with a distinctive lining, followed b…
Calcitic radial palisadic fabric in freshwater stromatolites: diagenetic and recrystallized feature or physicochemical sinter crust?
1999
Abstract When favorable conditions occur for carbonate precipitation (physicochemical processes) in tufas and travertines, organisms intervene either directly (the framework created by organisms acts as a crystal support) or indirectly (organic products influencing the mineralogy, nucleation, growth and habit of primary crystals). In the literature, fluvial and travertine crystalline sparite crusts with palisadic or prismatic crystals are generally interpreted as the result of early recrystallization of micrite in algal buildups (mostly composed of Schizothrix). Therefore, biological mediation is essential for the construction of continental bioherms and biostromes, even if organic remains …
Microbially-induced Fe and Mn oxides in condensed pelagic sediments (Middle -Upper Jurassic, Western Sicily)
2011
Abstract This article presents a petrographic comparison of the Rosso Ammonitico facies of Western Sicily and the original Rosso Ammonitico Veronese of Northern Italy based on a total of 27 sections. The Rosso Ammonitico has been the subject of numerous controversies that range from bathyal to shallow-water platform sedimentation. Therefore it seemed interesting to verify if the term Rosso Ammonitico has the same geologic connotation from region to region. The Middle-Upper Jurassic Rosso Ammonitico of Western Sicily is a condensed succession formed during a period of extensional synsedimentary tectonics related to the spreading of the Ionian Ocean. Slope-to-basin or pelagic carbonate deposi…
Fungi and Sediments
2000
Fungi are saprophytic organisms that can form lichens in symbiosis with an alga. Along with lichens, they excrete large quantities of organic acids, contributing to rock dissolution and neoformation of crystals, mainly oxalates and carbonates. Fungi contribute to the accumulation of manganese and iron as desert varnish and play a major role in the calcium cycle inside calcretes and carbonate soils in arid zones. Fungi constitute an important part of calcified filaments found in calcretes. They are covered with calcium oxalate crystals, which can transform into calcite during early diagenesis. They can also precipitate needle-fiber calcite, a common form of CaCO3 found in soils and calcretes…
Geochemistry and mineralogy of travertine deposits of the SW flank of Mt. Etna (Italy): Relationships with past volcanic and degassing activity
2007
Abstract Travertine deposits outcropping in the lower SW flank of Mt. Etna were studied for their mapping, as well as for their chemical, mineralogical and isotopic compositions. These deposits are dated to about 24 to 5 ka in the Adrano area, located at the western limit of the study area. In this area travertines show high Mg contents and are composed mostly of dolomite, thus apparently ruling out any primary deposition in favour of a diagenetic origin. Travertines outcropping near Paterno, in the east part of the study area, should be younger than 18 ka. Those located to the SSW of Paterno (Paterno–Diga) show high Sr contents and aragonite as dominant mineralogical phase, thus suggesting…
The origin and timing of multiphase cementation in carbonates: Impact of regional scale geodynamic events on the Middle Jurassic Limestones diagenesi…
2009
The Middle Jurassic carbonates of the eastern part of the Paris Basin display surprisingly low values of porosity and permeability (Φ < 15‰ and K < 0.5 mD). The main objective of this study is to determine the causes and timing of the cementation that altered the petrophysical properties of these carbonates thereby destroying their potential as oil reservoirs; a fate that did not befall their equivalents in deeper, central parts of the Paris Basin. Using petrographic and geochemical analyses (stable O and C isotopes, Sr isotopes, major elements), we identify six calcitic spar stages, two dolomite stages, and several episodes of fracturing and stylolitization ordered in paragenetic sequence.…
Carbon-isotope record and palaeoenvironmental changes during the early Toarcian oceanic anoxic event in shallow-marine carbonates of the Adriatic Car…
2013
AbstractGeochemical (δ13C, δ18O and Mn) compositions of Lower Jurassic shallow-water carbonates cropping out in Croatia were analyzed to elucidate the impact of the early Toarcian oceanic anoxic event (T-OAE) on the Adriatic Carbonate Platform (AdCP). The bulk-rock carbon-isotope records through the studied sections (Velebit-A, Velebit-B and Gornje Jelenje) are characterized by two significant excursions: (i) an initial positive trend interrupted by a pronounced negative shift (c. 2.5‰) that is followed by (ii) an increasing trend of positive values (up to 4.5‰). A comparison with δ13C trends obtained from well-calibrated sections from other localities in Europe shows that the overall chara…
Characterization and origin of permeability-porosity heterogeneity in shallow-marine carbonates: from core scale to 3D reservoir dimension (Middle Ju…
2014
21 pages; International audience; Nuclear magnetic resonance (NMR), stable isotope geochemistry of micro-sampled cores, NMR well-logs and 3D modeling are used to investigate the carbonate permeability-porosity heterogeneity along 230 m-thick limestones of the Paris Basin. Despite the global low porosity and permeability of the limestones, two aquifers units with porosity greater than 15% were identified. These two aquifers are very different in terms of pore through radii and NMR signal. The first one (A1: Aquifer 1) is a 7 m-thick mudstone unit, dominated by extended microporosity with pore throat radii of 0.25 μm to 0.3 μm. The second one (A2: Aquifer 2) is a 15 m-thick oolitic grainstone…
Diagénesis, análisis de procedencia y ambiente tectónico de rocas siliciclásticas. Un caso de estudio en el Devónico Superior de la Cordillera Ibéric…
2022
This paper describes the petrography and infers the provenance of siliciclastic rocks from the Upper Devonian of the Iberian Chains (Tabuenca, NE Spain), and outlines the tectonic setting associated with the Ebro Massif. These Devonian deposits are constituted by four different siliciclastic units: the Rodanas, Bolloncillos, Hoya and Huechaseca Formations. The provenance and diagenesis of over 400 sedimentary rocks samples are studied with a combination of petrographic polarizing microscope, scanning electron microscopy, atomic absorption spectroscopy, X-ray fluorescence and X-ray diffraction. In this sense, AAS and XRF analysis were used to determine the content of Ca, Mg, Fe, Mn, Na, K an…