Search results for "DIPOLE"
showing 10 items of 982 documents
Dipolar superferromagnetism in monolayer nanostripes of Fe(110) on vicinal W(110) surfaces
1998
By epitaxial growth of Fe on a vicinal W~110! substrate, densely spaced and continuous monolayer stripes of Fe~110! were prepared, directed along @001#. They exhibit a sharp phase transition to ferromagnetic order, free from relaxations. The magnetic easy axis is in the plane, but along @110# that means across the stripes. This cross magnetization induces ferromagnetic dipolar coupling between the spin blocks in adjacent stripes, which are preformed by exchange interactions. The resulting superferromagnetic phase transition is therefore driven by dipolar interactions. @S0163-1829~98!52002-4#
Isostructural phase transition, quasielastic neutron scattering and magnetic resonance studies of a bistable dielectric ion-pair crystal [(CH3)2NH2]2…
2019
We have synthesised and characterised a novel organic–inorganic hybrid crystal, [(CH3)2NH2]2KCr(CN)6. The thermal DSC, TMA, DTG and DTA analyses indicate two solid-to-solid structural phase transitions (PTs). According to the X-ray diffraction experiments, the first PT at 220 K is isostructural, since it does not involve a change of the space group. This transition occurs between the states, where the (CH3)2NH2+ cations are orientationally disordered and ordered (frozen). The other reversible PT at 481 K leads to a melt-like phase similar to the one observed in plastic crystals or polar liquids. Dielectric spectroscopy has been used to characterise the switching properties of the dipole mom…
Tunable Optical Antennas Using Vanadium Dioxide Metal-Insulator Phase Transitions
2019
Here, we investigate the possibility of exploiting the insulator-to-metal transition in vanadium dioxide (VO2) to tune and optically control the resonances of dipole nanoantennas in the visible near-infrared region. We compare the results obtained in the case of antennas completely made by VO2 with those of previous works and highlight the key role of the substrate to perform dynamical tuning. We also present a highly efficient configuration composed of dipole gold antenna loaded with VO2 and give some general guidelines to optimally exploit phase transitions to tune nanodevices.
Orientation and Dynamics of ZnO Nanorod Liquid Crystals in Electric Fields.
2010
ZnO nanorod polymer hybrids (i.e., ZnO nanorods coated with a block copolymer with a short anchor block (dopamine) and a longer solubilizing block of polystyrene (PS)) form liquid crystalline (LC) phases if they are dispersed at high concentration e.g., in a PS oligomer matrix. Due to the high mobility of the low T(g)-matrix the nanorod polymer hybrids show a switching behavior under an applied AC electric field. Hence, the orientation of the nanorod mesogens can be changed from planar (parallel to the substrate) to homeotropic (perpendicular) in full analogy to the switching of low molecular liquid crystals in an electric field. Dielectric measurements show that such a switching is mainly …
Pressure effect on the magnetism of layered copper(II) compounds with interlayer spacing up to 40.7 Å: Nature of the magnetic ordering
2002
The influence of pressure on the structure and magnetic properties of the layered hybrid compounds Cu 2 (OH) 3 (n-C m H 2 m + 1 CO 2 ), zH 2 O is investigated for m = 10 and 12. It is shown that the distance between magnetic copper(II) layers, up to 40.7 A, is not significantly modified and that the temperature of the ferromagnetic ordering decreases linearly with pressure increase. We present a new analysis of the susceptibility data, based on the scaling theory of phase transitions, which clearly shows up a crossover from a high-temperature two-dimensional (2D) behavior to a 3D regime at about 30 K, around 10 K above the long-range ordering temperature. A model of quantum ferromagnetic la…
Intramolecular charge transfer in elongated donor-acceptor conjugated polyenes
1995
Abstract Intramolecular charge transfer (ICT) has been investigated by electro-optical absorption measurements for two series of donor-acceptor polyenes of increasing length. Each molecule undergoes an increase in dipole moment upon photoexcitation. The experimental results indicate that lengthening the polyenic chain linking the donor and acceptor end groups results in a bathochromic shift of the ICT absorption band and induces marked increases of both excited state and transition dipoles, whereas the ground-state dipole is relatively unaffected. As a result, marked photoinduced changes in the dipole moment (up to 33 D) were obtained with the longest molecules (up to 27 A) leading to highl…
Bis(arylimidazole) Iridium Picolinate Emitters and Preferential Dipole Orientation in Films
2018
The straightforward synthesis and photophysical properties of a new series of heteroleptic iridium(III) bis(2-arylimidazole) picolinate complexes are reported. Each complex has been characterized by nuclear magnetic resonance, UV-vis, cyclic voltammetry, and photoluminescent angle dependency, and the emissive properties of each are described. The preferred orientation of transition dipoles in emitter/host thin films indicated more preferred orientation than homoleptic complex Ir(ppy)3.
Roadmap on STIRAP applications
2019
STIRAP (stimulated Raman adiabatic passage) is a powerful laser-based method, usually involving two photons, for efficient and selective transfer of populations between quantum states. A particularly interesting feature is the fact that the coupling between the initial and the final quantum states is via an intermediate state, even though the lifetime of the latter can be much shorter than the interaction time with the laser radiation. Nevertheless, spontaneous emission from the intermediate state is prevented by quantum interference. Maintaining the coherence between the initial and final state throughout the transfer process is crucial. STIRAP was initially developed with applications in …
QUADRUPOLAR CHARACTER OF THE Ti K-EDGE PREPEAKS IN TiO2 BY RESONANT AUGER
2002
Resonant spectroscopies offer a new opportunity to get more insight into excited electronic states by studying line shapes and intensities of decay processes. For photon excitations in the pre-K-edge region, the Ti KL 2,3 L 2,3 Auger spectra in TiO 2 show additional peaks when an electron is promoted in localized d-like states via a quadrupolar transition. This resonant process is used to unravel the respective contributions of quadrupolar and dipolar transitions to the absorption edge prepeaks.
Directionality of light emission in three-dimensional opal-based photonic crystals (Invited Paper)
2005
Experimental and theoretical studies of the emission directionality diagrams of a perylene dye covering the inner surface of three-dimensional opal-based photonic crystals with incomplete photonic bandgap are reported. Directionality diagram of emission intensity is interpreted in terms of the spontaneous emission suppression by photonic band gap and the emission enhancement due to photon focusing phenomenon. A theoretical model is based on the classical analysis of an angular distribution of the radiated power of a point dipole.