Search results for "Decane"
showing 10 items of 204 documents
CCDC 694346: Experimental Crystal Structure Determination
2010
Related Article: J.Suarez-Varela, J.M.Moreno, I.B.Maimoun, F.Lloret, J.Mrozinski, R.Kivekas, E.Colacio|2009|Cryst.Growth Des.|9|4102|doi:10.1021/cg9003438
CCDC 154870: Experimental Crystal Structure Determination
2002
Related Article: F.Bellouard, M.Clemente-Leon, E.Coronado, J.R.Galan-Mascaros, C.Gimenez-Saiz, C.J.Gomez-Garcia, T.Woike|2001|Polyhedron|20|1615|doi:10.1016/S0277-5387(01)00662-3
CCDC 1997473: Experimental Crystal Structure Determination
2020
Related Article: Christian Mevissen, Carel Kwamen, Leonard Himmel, Xiaofei Chen, Matthias Brückner, Saskia Huda, Christian Göb, Judith Jenniches, Iris Oppel, James Ward, Kari Rissanen, Markus Albrecht|2020|Eur.J.Org.Chem.|2020|5161|doi:10.1002/ejoc.202000843
New perspectives on diastereoselective determination of hexabromocyclododecane traces in fish by ultra high performance liquid chromatography-high re…
2014
a b s t r a c t A new analytical method is presented for diastereoisomer-specific identification and quantitation of hexabromocyclododecanes (HBCD) in fish samples. The method is based on extraction of the target analytes from samples with a mixture of organic solvents, with further three-stage clean-up includ- ing destructive removal of matrix components with sulphuric acid and acid-impregnated silica gel, and Florisil adsorption column chromatography. Ultra high performance liquid chromatography (UPLC) cou- pled with high resolution (HR) Orbitrap mass spectrometry featuring heated electrospray ionization (HESI-II) interface operated in negative ion mode was employed for the identification…
Catalytic and anticancer activities of sawhorse-type diruthenium tetracarbonyl complexes derived from fluorinated fatty acids
2013
The reaction of fluorinated fatty acids, perfluorobutyric acid (C3F7CO2H), and perfluorododecanoic acid (C11F23CO2H), with dodecacarbonyltriruthenium (Ru3(CO)12) under reflux in tetrahydrofuran, followed by addition of two-electron donors (L) such as pyridine, 1,3,5-triaza-7-phosphatricyclo[3.3.1.1]decane, or triphenylphosphine, gives stable diruthenium complexes Ru2(CO)4(μ2-η2-O2CC3F7)2(L)2 (1a, L = C5H5N; 1b, L = PTA; 1c, L = PPh3) and Ru2(CO)4(μ2-η2-O2CC11F23)2(L)2 (2a, L = C5H5N; 2b, L = PTA; 2c, L = PPh3). The catalytic activity of the complexes for hydrogenation of styrene under supercritical carbon dioxide has been assessed and compared to the analogous triphenylphosphine complexes w…
Novel Ni(II) Mixed Ligand Complex Modified Electrode: Catalytic Effect on Anodic Oxidation of Phenol
2004
Cyclic voltammetry, using graphite paste electrode (GPE) and chemically modified GPE with Ni(II) mixed ligand complex (MGPE), is described for sensing and detoxification of phenol. A novel mixed ligand complex of nickel with 1,4,8,11-tetraaza cyclotetradecane (cyclam) and thiocyanate in the molar ratio of 1 : 2 : 5 is synthesized and characterized by spectroscopic and electrochemical studies. The Ni(II)-cyclam-thiocyanate complex behaves as a fast electron-transfer mediator, as nickel ions exist in higher oxidation state of Ni(III) on applying a potential of 1.25 V (vs. Ag/AgCl), which catalyses the oxidation of the target species. The mixed ligand complex, when incorporated in the graphite…
Surface properties of Saccharomyces cerevisiae lees during sparkling wine ageing and their effect on flocculation
2009
Cell surface properties were determined for the first time for lees of Saccharomyces cerevisiae, and they proved to be significantly dependent on the time of sparkling wine ageing on lees. Cell surface hydrophobicity decreased from approximately 44% to 11% of affinity to hexadecane. Electron acceptor capacity (calculated as % affinity to ethyl acetate-% affinity to decane) increased from approximately -27% to 10 % and zeta potential from approximately -4 to 6mV. Mannoproteins are released from the external cell wall layer during the autolytic process, as confirmed by TOF-SIMS analysis of the cell wall chemical composition. This could explain the modifications of lees cell surface properties…
Phase separation of an asymmetric binary fluid mixture confined in a nanoscopic slit pore: Molecular-dynamics simulations
2008
As a generic model system of an asymmetric binary fluid mixture, hexadecane dissolved in carbon dioxide is considered, using a coarse-grained bead-spring model for the short polymer, and a simple spherical particle with Lennard-Jones interactions for the carbon dioxide molecules. In previous work, it has been shown that this model reproduces the real phase diagram reasonable well, and also the initial stages of spinodal decomposition in the bulk following a sudden expansion of the system could be studied. Using the parallelized simulation package ESPResSo on a multiprocessor supercomputer, phase separation of thin fluid films confined between parallel walls that are repulsive for both types…
Improved co-oxidation of β-carotene to β-ionone using xanthine oxidase-generated reactive oxygen species in a multiphasic system
2007
beta-Ionone, an aroma compound exhibiting flower notes, can be obtained from beta-carotene in a cooxidation system utilizing xanthine oxidase-generated reactive oxygen species (ROS). ROS have to be controlled as, although they can give rise to beta-ionone, they may also degrade it. In this work, the biotransformation of beta-carotene into beta-ionone was investigated in systems containing variable proportions of decane to extract beta-ionone before degradation. The use of 50% or 90% decane resulted in increased production yields. Tween 80, which was added to further improve the production, slightly decreased the reactivity of the medium and the extraction of beta-carotene, but increased the…
Tungsten oxide thin films sputter deposited by the reactive gas pulsing process for the dodecane detection
2015
International audience; The DC reactive magnetron sputtering of a metallic tungsten target was performed in an argon + oxygen atmosphere for depositing tungsten oxide thin films. In order to control the oxygen concentration in the films, the reactive gas pulsing process, namely RGPP, was implemented. Rectangular pulses were used with a constant pulsing period T = 16 s whereas the duty cycle α (time of oxygen injection to pulsing period T ratio) was systematically changed from 0 to 100% of T. This pulsing injection of the reactive gas allowed a gradual evolution of the films composition from pure metallic to over-stoichiometric WO3+ɛ’ compounds. These WOx films were sputter deposited on comm…