Search results for "Decomposition"
showing 10 items of 766 documents
Production and turnover of organic matter in three southern European Fagus sylvatica L
1999
Above-ground biomass, litterfall and litter accumulation and decomposition at the soil surface were studied within three Mediterranean beech forests from Italy, France and Spain in order to better understand the recycling of elements associated with the turnover organic matter Above-ground tree biomass amounted to 131.9 Mg ha-1 at Etna (Italy), 134.2 Mg ha-1 at Sierra de la Demanda (Spain) and 223.9 Mg ha-1 at Mont Lozère (France). The highest amount of total litterfall was observed at Sierra de la Demanda (4.7 Mg ha-1 year-1), followed by the Mont Lozère (4.4 Mg ha-1 year-1) and Etna (3.9 Mg ha-1 year-1). Total organic matter accumulated on the soil surface in the three beech forests amoun…
Simulation of Order-Disorder Phenomena and Diffusion in Metallic Alloys
1991
The application of the Monte Carlo method to lattice-statistics problems in metallurgy is reviewed. Examples are given for the prediction of phase diagrams from simple model assumptions for effective interatomic potentials and for the calculation of parameters describing long- and short-range order, ordering energy, etc., both for face-centered cubic (fcc) and body-centered cubic (bcc) lattices. Applications to real systems such as Cu—Au and Fe—Al alloys are discussed.
Influence of a continuous quenching procedure on the initial stages of spinodal decomposition
1986
Instead of the standard assumption in the theory of phase separation where an instantaneous quench from an initial equilibrium state to the final state in the two-phase region is assumed, we consider the more realistic situation that the change of the external control parameter (e.g. temperature) can only be performed with finite rates. During the initial stages of spinodal decomposition the system then has some “memory” of the states intermediate between the initial and the final one. This influence of the finite quench rate in continuous quenching procedures is studied within the linearized theory of spinodal decomposition, with the Langer-Baron-Miller decoupling, and with Monte Carlo sim…
Thermal decomposition of chromite spinel with chlorite admixture
2008
Abstract The behaviour of minerals in a South African chromite ore during the increasing of the temperature has been studied. Firstly, the changes produced during the ignition process have been examined by means of thermal and differential analysis (TGA–DTA) until 1200 °C. The characterization of the initial mineral and those obtained after heating at several temperatures in room atmosphere has been performed by X-ray diffraction (XRD). Moreover, voltammetric analyses have allowed to determine the variation of the iron oxidation degree in the studied materials. Light microscopy was applied to find more information about the different phases by their colour. During the heating, a wide range …
Decomposition of Microbial Necromass Is Divergent at the Individual Taxonomic Level in Soil
2021
The turnover of microbial biomass plays an important part in providing a significant source of carbon (C) to soil organic C. However, whether the decomposition of microbial necromass (non-living microbial biomass) in the soil varies at the individual taxa level remains largely unknown. To fill up these gaps, we compared the necromass decomposition of bacterial and archaeal taxa by separating live microbial biomass with 18O-stable isotope probing from dead microbial biomass in soil. Our results showed that most of the microbial necromass at the operational taxonomic unit level (88.51%), which mainly belong to Acidobacteria, Actinobacteria, Gemmatimonadetes, and Proteobacteria, decomposed sig…
On the pyrolytic decomposition of cadmium carbonate
1996
The pyrolytic decomposition of cadmium carbonate was studied by thermogravimetry (TG), derivative thermogravimetry (DTG), differential thermoanalysis (DTA) and exoemission of electrons (EEE).
Geometric quality and appearance of surfaces : local and global approaches
2012
Accounting for customers' perception of manufactured goods has become a major challenge for the industry. This process is to be established from early design to retail. Customers are nowadays more aware and detail oriented about perceived quality of products. This allows one to set not only an estimated price but also the expected quality of the product. Surface appearance analysis has therefore become a key industrial issue. Two approaches are proposed here to formalize the detection methodology and provide objective criteria for experts to evaluate surface anomalies. The first proposed approach is based on surface metrology. It consists in analyzing the measured topologies in order to bin…
Mixed integer optimal compensation: Decompositions and mean-field approximations
2012
Mixed integer optimal compensation deals with optimizing integer- and real-valued control variables to compensate disturbances in dynamic systems. The mixed integer nature of controls might be a cause of intractability for instances of larger dimensions. To tackle this issue, we propose a decomposition method which turns the original n-dimensional problem into n independent scalar problems of lot sizing form. Each scalar problem is then reformulated as a shortest path one and solved through linear programming over a receding horizon. This last reformulation step mirrors a standard procedure in mixed integer programming. We apply the decomposition method to a mean-field coupled multi-agent s…
Ligand-Stabilized Au13Cux (x = 2, 4, 8) Bimetallic Nanoclusters: Ligand Engineering to Control the Exposure of Metal Sites
2013
Three novel bimetallic Au-Cu nanoclusters stabilized by a mixed layer of thiolate and phosphine ligands bearing pyridyl groups are synthesized and fully characterized by X-ray single crystal analysis and density functional theory computations. The three clusters have an icosahedral Au13 core face-capped by two, four, and eight Cu atoms, respectively. All face-capping Cu atoms in the clusters are triply coordinated by thiolate or pyridyl groups. The surface ligands control the exposure of Au sites in the clusters. In the case of the Au13Cu8 cluster, the presence of 12 2-pyridylthiolate ligands still leaves open space for catalysis. All the 3 clusters are 8-electron superatoms displaying opti…
Decarboxylation and alkaline colour fading reactions in presence of humic substances.
2002
Humic substances (HSs) can substantially influence velocity of reactions in the environment as shown on example of decarboxylation and alkaline colour (e.g., malachite green and crystal violet) fading reactions. In colour fading and decarboxylation reactions of 6-nitrobenzisoxazole-3-carboxylic acid HS act as inhibitors, but additions of surfactants change the pattern of reaction. The inhibitory activity of HSs much depends on their origin. The velocity of studied reactions depends also on pH, temperature and concentration of HS used. Possible micellar catalysis mechanism has been suggested.