Search results for "Defectivity"
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Proton sponge lead halides containing 1D polyoctahedral chains
2021
Hybrid one-dimensional lead halides, containing the protonated 1,8-bis(dimethylamino)naphthalene moiety (C14H19N2, monoprotonated "proton sponge"), were prepared by simple one-pot methods and investigated in terms of crystal structure, morphology, thermal stability and electronic properties. The as-precipitated (C14H19N2)PbBr3 and (C14H19N2)PbI3 species are isostructural and crystallize in the orthorhombic Pbca space group, resulting in 1D crystal phases with ([PbX3](-))(infinity) chains (built by face-sharing [PbX6] octahedra; X = Br, I), among which the (C14H19N2)(+) cations are inserted. The two compounds display complete miscibility in the solid state: both (C14H19N2)PbI2Br and (C14H19N…
Defectivitat morfològica i variació sintàctica
2021
This paper discusses a case of parametric variation between Catalan and Spanish that concerns the fronting possibilities within the CP domain (the so-called ÇLeft PeripheryÈ). In particular, attention is paid to Catalan’s weak left peripheral activity, which prevents it from generating sentences that involve a Çmild focalizationÈ pattern very common in Spanish (e.g., «Mucha tontería dice el Gobierno» vs. *«Molta ximpleria diuel Govern»), first noted by Torrego (1980) and further explored by Uriagereka (1988). Interestingly, the same behavior is observed in the v*P domain, which accounts for the fact that VSO sentences (generated through movement of the subject to a specifier position, as Or…