Search results for "Detailed balance"
showing 3 items of 13 documents
Application of thermodynamics to driven systems
2007
Application of thermodynamics to driven systems is discussed. As particular examples, simple traffic flow models are considered. On a microscopic level, traffic flow is described by Bando's optimal velocity model in terms of accelerating and decelerating forces. It allows to introduce kinetic, potential, as well as total energy, which is the internal energy of the car system in view of thermodynamics. The latter is not conserved, although it has certain value in any of two possible stationary states corresponding either to fixed point or to limit cycle in the space of headways and velocities. On a mesoscopic level of description, the size n of car cluster is considered as a stochastic varia…
Transport coefficients of self-propelled particles: Reverse perturbations and transverse current correlations
2019
The reverse perturbation method [Phys. Rev. E 59, 4894 (1999)] for shearing simple liquids and measuring their viscosity is extended to the Vicsek model (VM) of active particles [Phys. Rev. Lett. 75, 1226 (1995)] and its metric-free version. The sheared systems exhibit a phenomenon that is similar to the skin effect of an alternating electric current: Momentum that is fed into the boundaries of a layer decays mostly exponentially toward the center of the layer. It is shown how two transport coefficients, i.e., the shear viscosity $\ensuremath{\nu}$ and the momentum amplification coefficient $\ensuremath{\lambda}$, can be obtained by fitting this decay with an analytical solution of the hydr…
Dissociation energies of silver clusters Agn+, n=14, 15, 16, 18
2003
A recently developed method to determine dissociation energies has been applied to positively charged silver clusters of size n=14, 15, 16 and 18. The method uses a combination of sequential and single step decays. It requires an uncalibrated thermometer which here is provided by the evaporation rate constants of the product clusters. For this purpose, earlier measurements [J. Chem. Phys. 57 (1998) 2786] are reanalyzed with the new method. The resulting dissociation energies are compared with the liquid drop values and the measured decay rate constants with expected rate constants from detailed balance theory.