Search results for "Dextrin"

showing 7 items of 297 documents

Formation of pseudorotaxanes and micelles supramolecular assemblies tuned by selective cyclodextrins

2011

pseudorotaxanes micelles cyclodextrins SANS
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SMART NANOSPONGE-BASED SYSTEMS FOR ADVANCED APPLICATIONS

2023

rosmarinic acidpolymerrelaxometrysmart materialSettore CHIM/06 - Chimica Organicaquercetinphotocatalysifolic acidcontrolled release dyecyclodextrinheuristic analysiadsorptionpH-tunabilitycalixarenenanomaterialnanospongeFFC-NMR
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Supramolecular Organocatalysis in Water Mediated by Macrocyclic Compounds

2018

In the last decades many efforts have been devoted to design supramolecular organocatalysts able to work in water as the reaction medium. The use of water as solvent provides promising benefits with respect to environmental impact. In this context, macrocyclic compounds played a role of primary importance thanks to their ease of synthesis and their molecular recognition abilities toward the reactants. The aim of this review is to give an overview of the recent advances in the field of supramolecular organocatalysis in water, focusing the attention on calixarene and cyclodextrins derivatives. Calixarenes and cyclodextrins, thanks to their hydrophobic cavities, are able to host selectively th…

supramolecular organocatalysisSupramolecular chemistryContext (language use)Review010402 general chemistry01 natural scienceslcsh:ChemistryHydrophobic effectMolecular recognitionCalixareneHydrophobic effectsupramolecular organocatalysis Water Hydrophobic effect molecular recognition Calixarenes CyclodextrinsCyclodextrins010405 organic chemistryChemistryRegioselectivityWaterGeneral ChemistryCombinatorial chemistry0104 chemical sciencesChemistrylcsh:QD1-999Organic reactionOrganocatalysismolecular recognitionCalixarenes
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Liquid Structure Scenario of the Archetypal Supramolecular Deep Eutectic Solvent: Heptakis(2,6-di-O-methyl)-β-cyclodextrin/levulinic Acid

2023

The concept of supramolecular solvents has been recently introduced, and the extended liquid-state window accessible for mixtures of functionalized cyclodextrins (CDs) with hydrogen bond (HB) donor species, e.g., levulinic acid, led to the debut of supramolecular deep eutectic solvents (SUPRA-DES). These solvents retain CD’s inclusion ability and complement it with enhanced solvation effectiveness due to an extended HB network. However, so far, these promising features were not rationalized in terms of a microscopic description, thus hindering a more complete capitalization. This is the first joint experimental and computational study on the archetypal SUPRA-DES: heptakis- (2,6-di-O-methyl)…

supramolecular hydrogen bonding low melting mixtures cyclodextrin solvationSettore CHIM/02 - Chimica Fisica
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Neuronal effects of Sugammadex in combination with Rocuronium or Vecuronium.

2017

Rocuronium (ROC) and Vecuronium (VEC) are the most currently used steroidal non-depolarizing neuromuscular blocking (MNB) agents. Sugammadex (SUG) rapidly reverses steroidal NMB agents after anaesthesia. The present study was conducted in order to evaluate neuronal effects of SUG alone and in combination with both ROC and VEC. Using MTT, CASP-3 activity and Western-blot we determined the toxicity of SUG, ROC or VEC in neurons in primary culture. SUG induces apoptosis/necrosis in neurons in primary culture and increases cytochrome C (CytC), apoptosis-inducing factor (AIF), Smac/Diablo and Caspase 3 (CASP-3) protein expression. Our results also demonstrated that both ROC and VEC prevent these…

vecuroniumNecrosisEstrès oxidatiuPrimary Cell CulturerocuroniumCaspase 3NeuronesPharmacologySugammadexSugammadex03 medical and health sciences0302 clinical medicine030202 anesthesiologymedicineAnimalsHumansAndrostanolsRocuroniumCell damageNeuronsVecuronium BromideDose-Response Relationship DrugCaspase 3business.industryapoptosis.Apoptosis Inducing FactorCytochromes c030208 emergency & critical care medicineGeneral Medicinemedicine.diseaseneuronRatsDrug Combinationsmedicine.anatomical_structureGene Expression RegulationApoptosisToxicityNeuronNeuromuscular Blocking Agentsmedicine.symptombusinessResearch Papergamma-Cyclodextrinsmedicine.drug
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Rücktitelbild: Water Structure Recovery in Chaotropic Anion Recognition: High-Affinity Binding of Dodecaborate Clusters to γ-Cyclodextrin (Angew. Che…

2015

γ cyclodextrinChaotropic agentHigh affinity bindingChemistryDodecaboratePolymer chemistryGeneral MedicineIonAngewandte Chemie
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Back Cover: Water Structure Recovery in Chaotropic Anion Recognition: High-Affinity Binding of Dodecaborate Clusters to γ-Cyclodextrin (Angew. Chem. …

2015

γ cyclodextrinChaotropic agentHofmeister seriesHigh affinity bindingChemistryINTInorganic chemistryDodecaborateSupramolecular chemistryGeneral ChemistryMedicinal chemistryCatalysisIonAngewandte Chemie International Edition
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