Search results for "Diagenesi"
showing 10 items of 130 documents
Integrative analysis of the mineralogical and chemical composition of modern microbialites from ten Mexican lakes: What do we learn about their forma…
2021
International audience; Interpreting the environmental conditions under which ancient microbialites formed relies upon comparisons with modern analogues. This is why we need a detailed reference framework relating the chemical and mineralogical compositions of modern microbialites to the physical and chemical parameters prevailing in the environments where they form. Here, we measured the chemical, including major and trace elements, and mineralogical composition of microbialites from ten Mexican lakes as well as the chemical composition of the surrounding waters. Saturation states of lakes with different mineral phases were systematically determined and correlations between solution and so…
Diagenetic stability of non-traditional stable isotope systems (Ca, Sr, Mg, Zn) in teeth – An in-vitro alteration experiment of biogenic apatite in i…
2021
Stable isotope ratios and trace element concentrations of fossil bones and teeth are important geochemical proxies for the reconstruction of diet and past environment in archaeology and palaeontology. However, since diagenesis can significantly alter primary diet-related isotope signatures and elemental compositions, it is important to understand and quantify alteration processes. Here, we present the results of in-vitro alteration experiments of dental tissues from a modern African elephant molar reacted in aqueous solutions at 30 °C and 90 °C for 4 to 63 days. Dental cubes with ≈ 3 mm edge length, comprising both enamel and dentin, were placed into 2 mL of acidic aqueous sol…
Interpretation of the nitrogen isotopic composition of Precambrian sedimentary rocks: Assumptions and perspectives
2016
International audience; Nitrogen isotope compositions in sedimentary rocks (d(15)N(sed)) are routinely used for reconstructing Cenozoic N-biogeochemical cycling and are also being increasingly applied to understanding the evolution of ancient environments. Here we review the existing knowledge and rationale behind the use of d(15)N(sed) as a proxy for the Precambrian N-biogeochemical cycle with the aims of (i) identifying the major uncertainties that affect analyses and interpretation of nitrogen isotopes in ancient sedimentary rocks, (ii) developing a framework for interpreting the Precambrian d(15)N(sed) record, (iii) testing this framework against a database of Precambrian d(15)N(sed) va…
Soil development on sediments and evaporites of the Messinian crisis
2020
Abstract Vast areas in the Mediterranean are characterised by evaporite deposits of the Messinian crises (c. 6–5.3 Ma BP). During this period, large deposits were built up in shallow lagoon-like systems and are now found in southern Italy, Albania, Cyprus and Turkey. So far, soil formation on evaporites has been studied predominantly in subarid to arid environments. Although the formation of soils has received new significance, little is known about the evolutional trajectories on evaporites of the Mediterranean. We therefore studied soil formation in the Caltanissetta basin (Sicily) where evaporites are most widespread. The lithologies included the sequence: marine clay deposits, laminated…
Impact of basin burial and exhumation on Jurassic carbonates diagenesis on both sides of a thick clay barrier (Paris Basin, NE France).
2014
27 pages; International audience; Several diagenetic models have been proposed for Middle and Upper Jurassic carbonates of the eastern Paris Basin. The paragenetic sequences are compared in both aquifers to propose a diagenetic model for the Middle and Late Jurassic deposits as a whole. Petrographic (optical and cathodoluminescence microscopy), structural (fracture orientations) and geochemical (δ18O, δ13C, REE) studies were conducted to characterize diagenetic cements, with a focus on blocky calcite cements, and their connection with fracturation events. Four generations of blocky calcite (Cal1-Cal4) are identified. Cal1 and Cal2 are widespread in the dominantly grain-supported facies of t…
The behaviour of zirconium, hafnium and rare earth elements during the crystallisation of halite and other salt minerals
2017
Abstract Halite crystals from Messinian and Tortonian evaporites from Sicily and Spain and current precipitated halite crystals and the relative parent brines (active evaporation systems) were investigated in order to evaluate the Zr, Hf and Rare Earth Element (REE) behaviour. Halite crystallisation from evaporating brines fractionates Zr, Hf and REE through a two-step process. During the first step, dissolved complexes of studied elements are scavenged onto the surfaces of crystallising halite. During the second step, elements are co-precipitated into the crystal lattice as it grows. The first step mechanism is determined by the dissolved REE speciation. In saltworks where carbonate-REE co…
Reactive transport modelling of carbonate cementation in a deep saline aquifer, the Middle Jurassic Oolithe Blanche Formation, Paris Basin, France.
2016
10 pages; International audience; The Oolithe Blanche Formation (Bathonian, Middle Jurassic) is one of the deep saline aquifers of the Paris Basin in France. The spatial distribution of its reservoir properties (porosity, permeability, tortuosity, etc.) is now better known with relatively homogeneous properties, except for some levels in the central part of the basin, where permeability exhibits higher values. This spatial distribution has been correlated with diagenetic events (variability of cementation) and palaeo-fluid flow circulation phases leading to variable cementation. In this paper, numerical simulations of reactive transport are performed. They provide a preliminary quantitative…
Petrographic and geochemical characterization of the Middle‒Upper Jurassic Fe–Mn crusts and mineralizations from Monte Inici (north-western Sicily): …
2021
AbstractFe–Mn concretions and mineralizations, associated with condensed horizons and hardground, are significant archives in ancient carbonate rocks. Their petro-chemical study allows an assessment of the palaeoenvironmental context in which they were formed also connected to their biotic or abiotic origin. At the western side of the Monte Inici (Fornazzo section, north-western Sicily) a well exposed outcrop of condensed pelagic limestones (Rosso Ammonitico facies: Middle‒Upper Jurassic) is well-known and thoroughly studied. In this section, the base of the Rosso Ammonitico facies consists of a very condensed level rich in fossils with a variable thickness deposited from the early Bathonia…
Acoustic properties of ancient shallow-marine carbonates: effects of depositional environments and diagenetic processes (Middle Jurassic, Paris Basin…
2010
17 pages; International audience; Examination of petrophysical properties (acoustic velocity, porosity, permeability, and density) and petrographical characteristics (texture, facies composition, and diagenesis) of more than 250 core plugs from the Middle Jurassic carbonates of the eastern Paris Basin provides insights into the parameters controlling acoustic velocities in relatively low-porosity carbonate rocks ({Phi} < 20%). The pore-type observations reveal distinct acoustic velocities in samples with intergranular macropores and samples with micropores in subhedral micrite, such that velocities in microporous mudstone–wackestone (lagoonal) deposits are greater than in macroporous grains…
Geodynamic control on carbonate diagenesis: Petrographic and isotopic investigation of the Upper Jurassic formations of the Paris Basin (France).
2007
23 pages; International audience; The Oxfordian and Kimmeridgian carbonates of the eastern edge of the Paris Basin display poor reservoir properties (Φb15% and Kb0.1 md). The petrographic investigation and the resultant paragenetic sequence show that this is due to extensive precipitation of 2 types of almost synchronous blocky LMC (Low Magnesian Calcite) cements during mesogenesis (burial). Stable isotope investigation of these non-recrystallized cements, through both microdrilling sampling and in-situ SIMS (Secondary IonMass Spectrometry) analysis, shows that they originated from slightly buffered meteoric fluids (−3‰SMOW to −8‰SMOW) flowing through the Malm carbonate aquifers of the east…