Search results for "Dielectric Spectroscopy"
showing 10 items of 243 documents
Dielectric Characterization of Fruit Nectars at Low RF Frequencies
2015
Dielectric properties of apple, apricot, peach, and pear nectars were studied in the frequency range from 15 kHz to 30 MHz and the temperature range from 25 to 60 degrees C. Both the relative dielectric constants and the dielectric loss factors decreased by increasing frequency and increased linearly with increasing temperature with values in the order 10(4)-10(2) and 10(5)-10(2), respectively. The power dissipation densities and the power penetration depths were found to increase linearly with temperature. Power dissipation densities remained essentially constant for all the samples while power penetration depths decreased significantly on increasing frequency. The dependence of each of th…
Radio and Microwave Spectroscopy of 0.2PMN-0.4PSN-0.4PZN Relaxor Ceramics
2005
Dielectric spectroscopy results of 0.2PbMg 1/3 Nb 2/3 O 3 -0.4PbSc 1/2 Nb 1/2 O 3 -0.4PbZn 1/3 Nb 2/3 O 3 ceramics are reported for 200 < T < 450 K and 20 Hz < v < 11 GHz. Dielectric constant is very high (more than 12000) in the vicinity of the peak. Anomalous broad dielectric relaxation has been observed near and below the temperature of the maximum permittivity, T m (at 1 kHz). The distribution of relaxation times have been calculated directly from the dielectric spectra. At higher temperatures than the maximum permittivity, T m the distribution of the relaxation times is symmetrically shaped (Cole-Cole function satisfactory describes the dielectric response). At lower temperatures, the …
Dielectric spectroscopy of an aligned liquid crystalline side chain polymer using high pressures
1995
Abstract The complex permittivity of a liquid crystalline side group polymer has been measured at pressure from ambient up to 300 MPa. The samples were initially not aligned, then planar and finally homeotropically aligned by the field of a 7.2 Tesla magnet. Temperatures ranged up to 130°C, and measurement frequencies from 5 Hz to 5 MHz. The equilibrium permittivity es has been interpreted in terms of an effective dipole moment μ. The frequency of maximum loss has been analysed in terms of enthalpy of activation and volume of activation for α and β relaxation processes.
Dielectric spectroscopy analysis of EVA-silicate nanocomposite insulating materials
2005
Nanocomposite materials show promising results for applications as electrical insulation. Among several materials presently under investigation, previous works indicate that polypropylene and ethylene-vinilacetate filled by nanosilicates present lower content of space charge and higher electric strength. However, efforts are needed to explain nanocomposite behaviour and characterize their electrical, thermal and mechanical properties. In this paper, the results of broad-band dielectric spectroscopy performed on ethylene-vinylacetate copolymer filled by layered micro and nanosized silicates are reported. The nanofillers consist of montmorillonite and fluorohectorite, that is, natural and syn…
Dielectric Permittivity and Conductivity of Li0.07Na0.93Ta0.1Nb0.9O3and Li0.07Na0.93Ta0.111Nb0.889O3Solid Solutions
2011
Results of studies of dielectric properties and conductivity in 290–700 K range of temperature and frequencies from 25 to 106 Hz in ferroelectric perovskite solid solutions Li0.07Na0.93Ta0.1Nb0.9 O3 and Li0.07Na0.93Ta0.111Nb0.889 O3 are reported. A first-order ferroelectric phase transition proceeds in both studied compositions within the observed range of temperature. The co-precipitated Ta2yNb2(1-y)O5 pentoxides being used for synthesis of Li0.07Na0.93Ta0.111Nb0.889O3 the Curie point shifts by ∼75 K to a lower temperature while compared with Li0.07Na0.93Ta0.1Nb0.9O3 synthesised from mechanical mixture of the Ta2O5 and Nb2O5 oxides the high-frequency dielectric permittivity and ion conduct…
Relation of Dielectric Permittivity and Electric Field Dependence of Polarization in Some Relaxors with Perovskite Structure
2011
The dielectric nonlinearity is studied in ferroelectric relaxors 0.92PbMg1/3 Nb2/3O3-0.08PbTiO3, 0.4Na1/2Bi1/2TiO3-0.5SrTiO3-0.1PbTiO3 and Pb0.9075La0.0925 (Zr0.65Ti0.35)0.9775O3. It is shown that above the temperature of dielectric permittivity maximum nonlinearity of dielectric permittivity corresponds to electric field dependence of polarization. The influence of electric field on distribution of relaxation times is studied below the maximum of dielectric permittivity. The role of internal bias field in Pb0.9075La0.0925(Zr0.65Ti0.35)0.9775O3 ceramics is discussed.
Isostructural phase transition, quasielastic neutron scattering and magnetic resonance studies of a bistable dielectric ion-pair crystal [(CH3)2NH2]2…
2019
We have synthesised and characterised a novel organic–inorganic hybrid crystal, [(CH3)2NH2]2KCr(CN)6. The thermal DSC, TMA, DTG and DTA analyses indicate two solid-to-solid structural phase transitions (PTs). According to the X-ray diffraction experiments, the first PT at 220 K is isostructural, since it does not involve a change of the space group. This transition occurs between the states, where the (CH3)2NH2+ cations are orientationally disordered and ordered (frozen). The other reversible PT at 481 K leads to a melt-like phase similar to the one observed in plastic crystals or polar liquids. Dielectric spectroscopy has been used to characterise the switching properties of the dipole mom…
Dielectric polarization in PLZT X/65/35 and PbMg1/3Nb2/3O3at the diffuse phase transition
1992
Abstract The transformation of the hysteresis loops in PLZT x/65/35 in the region of diffuse phase transition is discussed in relation to the behaviour of dielectric permittivity. The Vogel-Fulcher type dielectric relaxation is used to describe the discussed phenomena.
DIELECTRIC AGEING IN LAYERED FERROELECTRICS
2008
ABSTRACT Studies of the effects of sample history on long-term relaxation of polarization in the Na0.5Bi8.5Ti2Nb4O27 and Na0.5Bi8.5Ti2Ta4O27 ferroelectrics of layered structures are reported. The type of functional relationship of e′(t) at measuring procedures including heating or cooling to the temperature being examined Ta is found to change from exponential (Kohlrausch function) to logarithmic. Results are discussed within the assumption of presence of defect complexes in disordered ferroelectrics.
Broadband Dielectric Spectroscopy of Ferroelectric Phase Transitions in PbSc1/2Nb1/2O3Ordered Ceramics
2008
Broadband dielectric spectroscopy of PbSc 1/2 Nb 1/2 O 3 (PSN) ordered ceramics are reported within the range of 20 Hz ≤ ν ≤ 2 THz in 80 K ≤ T ≤ 300 K temperatures. Spectrally very broad dielectric dispersion consisting of two parts − at lower frequencies, ferroelectric domains cause a dispersion and at higher frequencies, higher temperatures the relaxation soft mode is responsible for the dispersion. The relaxation soft mode exhibit pronounced hardening on cooling, whilst the ferroelectric phase transition is connected with an abrupt freezing and rise of polar nanoregions into ferroelectric domains.