Search results for "Dielectric Spectroscopy"
showing 10 items of 243 documents
Defined-size DNA triple crossover construct for molecular electronics: modification, positioning and conductance properties.
2011
We present a novel, defined-size, small and rigid DNA template, a so-called B-A-B complex, based on DNA triple crossover motifs (TX tiles), which can be utilized in molecular scale patterning for nanoelectronics, plasmonics and sensing applications. The feasibility of the designed construct is demonstrated by functionalizing the TX tiles with one biotin-triethylene glycol (TEG) and efficiently decorating them with streptavidin, and furthermore by positioning and anchoring single thiol-modified B-A-B complexes to certain locations on a chip via dielectrophoretic trapping. Finally, we characterize the conductance properties of the non-functionalized construct, first by measuring DC conductivi…
Electrochemical impedance spectroscopy of polyelectrolyte multilayer modified gold electrodes: influence of supporting electrolyte and temperature.
2005
Electrochemical impedance spectroscopy and cyclic voltammetry are employed to characterize poly(styrenesulfonate)/poly(allylamine hydrochloride) multilayers assembled onto cysteamine-modified gold surfaces. The influence of the supporting electrolyte and temperature on the impedance response is studied because of both its practical interest and the need to test further the capillary membrane model recently developed by Barreira et al. [J. Phys. Chem. B 2004, 108, 17973]. The results obtained are interpreted quite satisfactorily in terms of this model, thus providing additional support to its usefulness for the description of ionic transport through polyelectrolyte multilayers. It is observe…
Large Area Deposition by Radio Frequency Sputtering of Gd0.1Ce0.9O1.95 Buffer Layers in Solid Oxide Fuel Cells: Structural, Morphological and Electro…
2021
We investigate the influence of position, under large circular sputtering targets, on the final electrochemical performance of 35 mm diameter button solid oxide fuel cells with sputter-deposited Gadolinium doped Ceria barrier layers, positioned in order to almost cover the entirety of the area associated with a 120 × 80 mm2 industrial cell. We compare the results obtained via structural and morphological analysis to the Electrochemical Impedance Spectroscopy (EIS) measurements performed on the button cells, disentangling the role of different parameters. The Atomic Force Microscopy analysis makes it possible to observe a decrease in the roughness values from the peripheral to the central zo…
Evaluation of Rhodamine B Photocatalytic Degradation over BaTiO
2021
This research was funded by UIDB/50006/2020 with funding from FCT/MCTES through national funds and from the Institute of General and Ecological Chemistry of Lodz University of Technology. Susana L.H. Rebelo and Iwona Kuźniarska-Biernacka thank FCT (Fundação para a Ciência e Tecnologia) for funding through program DL 57/2016–Norma transitória (RE-QUIMTE/EEC2018/30 (SLHR) and REQUIMTE/EEC2018/14 (IKB)).
MCM-41 silica effect on gel polymer electrolytes based on thermoplastic polyurethane
2012
Abstract Polymer electrolytes were prepared from thermoplastic polyurethane with addition of mixture of N-ethyl(methylether)-N-methylpyrrolidinium trifluoromethanesulfonimide (PYRA12O1TFSI) ionic liquid, lithium bis(trifluoromethanesulfoneimide) salt and propylene carbonate. MCM-41 mesoporous silica was added in proportions ranging from 5 to 20 wt.% with respect to TPU. The electrolytes were characterized by thermogravimetric analysis, differential scanning calorimetry, linear voltammetry and impedance spectroscopy. The MCM-41 addition to the system was found to improve the electrochemical stability of the membranes and to reduce the gel electrolyte/metallic Li interfacial resistance. The f…
Nafion® and polyaniline composite modification with Li and Mg ions
2019
Funding from European Union`s Horizon 2020 Research and Innovation Program project under grant agreement No 768789 is greatly acknowledged.
Ceria-based electrolytes prepared by solution combustion synthesis: The role of fuel on the materials properties
2016
Ce0.8Sm0.2O2 â xpowders were synthesized by solution combustion synthesis using citric acid, cellulose and sucrose as single, or intimately mixed, fuels. The powders were characterized by X-ray diffraction, transmission electron microscopy, X-ray photoelectron spectroscopy, N2sorption at â196 °C, H2-temperature programmed reduction and thermogravimetric analyses. Textural properties of the powders were shaped by the peculiar employed fuel. The study of reducibility revealed that oxygen vacancies formation is mainly influenced by both parameters, specific surface area and total pore volume. The different tendency toward reduction played a key role in sintering under reducing atmosphe…
A tungsten oxide–lutetium bisphthalocyanine n–p–n heterojunction: from nanomaterials to a new transducer for chemo-sensing
2019
We report on a new hybrid heterojunction gas-sensitive device by combining a molecular material with a metal oxide. WO3 was synthesised via an aerosol-assisted chemical vapour deposition technique from a tungsten hexacarbonyl precursor. Onto an inorganic film, LuPc2 was vacuum evaporated. The morphology of the WO3–LuPc2 hybrid films is dominated by the morphological features of the tungsten oxide film, as shown by scanning electron microscopy and atomic force microscopy. Raman spectroscopy of the device confirms the presence of both materials. The non-linear I–V characteristics demonstrate the existence of an energy barrier at the interface between the inorganic and molecular materials. The…
Low-Frequency Relaxation Phenomena in α-LiIO3: The Nature and Role of Defects
2002
The lithium iodate ionic conduction in the polar c-axis direction is studied between 35 and 470 K for crystals grown in various conditions. So far, to separate processes induced by the nature of electrodes, the impedance spectroscopy technique had been used at room temperature with both metallic and ideally polarizable insulating electrodes, so that a relaxation of space charges was clearly identified. Here, the temperature dependence of the hopping ionic conductivity exhibits quite different activation energies well related to the growth conditions. Following low-temperature Raman and thermodynamic experiments, a new approach based on a vacancy diffusion mechanism is proposed. Experimental…
Soret coefficient of trace ions determined with electrochemical impedance spectroscopy in a thin cell. Theory and measurement
2018
The tendency of a substance to migrate due to a temperature gradient is known as thermodiffusion or the Soret effect. We believe that this is the first work that describes the study of the Soret effect using electrochemical impedance spectroscopy in a non-isothermal thin cell, and shows how the Soret coefficient can be determined from these measurements. The effect of a temperature gradient in a thin cell is analyzed, both theoretically and experimentally. Our theoretical modeling of the system predicts the effect of key parameters to the impedance spectra. Experimentally we determine the Soret coefficient of the redox couple Fe(CN)64−/Fe(CN)63− in an aqueous KCl solution. It is found that …