Search results for "Diffusion Monte Carlo"

showing 10 items of 21 documents

Structure of metastable 2D liquid helium

2007

We present diffusion Monte Carlo (DMC) results on a novel, superfluid phase in two-dimensional 4He at densities higher than 0.065 A-2, which is very close to the freezing density. The new phase has anisotropic, hexatic orbital order, but the single-particle density remains constant. By increasing density the hexatic superfluid forms a metastable state, which lies above the crystal ground state in energy. This implies that the liquid-solid phase transition takes place in two stages: a second-order phase transition from the isotropic superfluid to the hexatic superfluid, followed by a first-order transition that localizes atoms into the triangular crystal order.

Condensed Matter::Quantum GasesPhase transitionMaterials scienceCondensed matter physicsStatistical Mechanics (cond-mat.stat-mech)Liquid heliumCondensed Matter::OtherGeneral Physics and AstronomyFOS: Physical scienceslaw.inventionCondensed Matter - Other Condensed MatterSuperfluidityCrystalCondensed Matter::Soft Condensed MatterlawPhase (matter)MetastabilityDiffusion Monte CarloGround stateCondensed Matter - Statistical MechanicsOther Condensed Matter (cond-mat.other)
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Monte Carlo study of surface critical behavior in the XY model.

1989

We have used Monte Carlo simulations to study the behavior of $L\ifmmode\times\else\texttimes\fi{}L\ifmmode\times\else\texttimes\fi{}D$ slabs containing classical spins which interact via nearest-neighbor $\mathrm{XY}$ coupling. The coupling constant ${J}_{S}$ for spins in the surface layer is fixed at $0.5J$. Finite-size scaling is used to analyze data for $D=59$ and to extract estimates for the surface critical exponents. We find that ${\ensuremath{\beta}}_{1}$ is in good agreement with theoretical predictions.

Coupling constantPhysicsHybrid Monte CarloCondensed matter physicsQuantum Monte CarloDynamic Monte Carlo methodDiffusion Monte CarloClassical XY modelCoupling (probability)Critical exponentMathematical physicsPhysical review. B, Condensed matter
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Magic numbers, excitation levels, and other properties of small neutral 4He clusters (Nor = 50).

2006

The ground-state energies and the radial and pair distribution functions of neutral 4He clusters are systematically calculated by the diffusion Monte Carlo method in steps of one 4He atom from 3 to 50 atoms. In addition the chemical potential and the low-lying excitation levels of each cluster are determined with high precision. These calculations reveal that the "magic numbers" observed in experimental 4He cluster size distributions, measured for free jet gas expansions by nondestructive matter-wave diffraction, are not caused by enhanced stabilities. Instead they are explained in terms of an enhanced growth due to sharp peaks in the equilibrium concentrations in the early part of the expa…

Distribution functionChemistryExcited stateAtomMonte Carlo methodCluster (physics)General Physics and AstronomyDiffusion Monte CarloPhysical and Theoretical ChemistryAtomic physicsDiffusion (business)ExcitationThe Journal of chemical physics
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Path integral Monte Carlo study of the internal quantum state dynamics of a generic model fluid

1996

We study the quantum dynamics of a generic model fluid with internal quantum states and classical translational degrees of freedom in two spatial dimensions. The path integral Monte Carlo data for the imaginary time correlation functions are presented and analyzed by the maximum entropy method. A comparison of the frequency distribution with those of a mean field approximation and virial expansion shows good agreement at high and low densities, respectively. \textcopyright{} 1996 The American Physical Society.

Hybrid Monte CarloQuantum dynamicsQuantum Monte CarloMonte Carlo methodMonte Carlo integrationDiffusion Monte CarloStatistical physicsPath integral Monte CarloMathematicsMonte Carlo molecular modelingPhysical Review E
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Microscopic calculations of the hipernucleus λ5He

1993

Ground state results for the hypernucleus λ5He are reported. They have been calculated with a variatonal Jastrow-like trial wave function and also within the Diffusion Monte Carlo method. Simple central potential have been used to describe NN and λN interactions. The validity of the rigid core approximation is discussed. Guardiola Barcena, Rafael, Rafael.Guardiola@ific.uv.es Navarro Salas, Jose, Jose.Navarro@ific.uv.es

Jastrow-like:FÍSICA::Nucleónica::Fuentes de partículas [UNESCO]UNESCO::FÍSICA::Nucleónica::Fuentes de partículasHypernucleus:FÍSICA [UNESCO]Diffusion Monte Carlo methodHypernucleus ; Jastrow-like ; Diffusion Monte Carlo methodUNESCO::FÍSICA
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Mg impurity in helium droplets.

2011

Within the diffusion Monte Carlo approach, we have determined the structure of isotopically pure and mixed helium droplets doped with one magnesium atom. For pure 4He clusters, our results confirm those of M. Mella et al. [J. Chem. Phys. 123, 054328 (2005)] that the impurity experiences a transition from a surface to a bulk location as the number of helium atoms in the droplet increases. Contrarily, for pure 3He clusters Mg resides in the bulk of the droplet due to the smaller surface tension of this isotope. Results for mixed droplets are presented. We have also obtained the absorption spectrum of Mg around the 3s3p 1P_1 <-- 3s2 1S_0 transition.

Materials scienceAbsorption spectroscopyMagnesiumDopingAnalytical chemistryGeneral Physics and Astronomychemistry.chemical_elementFísicaFOS: Physical sciencesSurface tensionCondensed Matter - Other Condensed MatterchemistryImpurityAtomPhysics::Atomic and Molecular ClustersDiffusion Monte CarloPhysics::Atomic PhysicsPhysics - Atomic and Molecular ClustersPhysical and Theoretical ChemistryAtomic and Molecular Clusters (physics.atm-clus)HeliumOther Condensed Matter (cond-mat.other)The Journal of chemical physics
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On the adoption of the Monte Carlo method to solve one-dimensional steady state thermal diffusion problems for non-uniform solids

2013

Abstract The present paper is focussed on the investigation of the potential adoption of the Monte Carlo method to solve one-dimensional, steady state, thermal diffusion problems for continuous solids characterised by an isotropic, space-dependent conductivity tensor and subjected to non-uniform heat power deposition. To this purpose the steady state form of Fourier’s heat diffusion equation relevant to a continuous, heterogeneous and isotropic solid, undergoing a space-dependent heat power density has been solved in a closed analytical form for the general case of Cauchy’s boundary conditions. The thermal field obtained has been, then, put in a peculiar functional form, indicating that it …

Materials scienceApplied MathematicsQuantum Monte CarloMonte Carlo methodThermal diffusivityModeling and SimulationIsotropic solidDynamic Monte Carlo methodMonte Carlo method Heat diffusion Space-dependent thermal conductivityDiffusion Monte CarloHeat equationStatistical physicsSettore ING-IND/19 - Impianti NucleariMonte Carlo molecular modeling
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Excitation spectra of aHe3impurity onHe4clusters

2004

The diffusion Monte Carlo technique is used to calculate and analyze the excitation spectrum of a single $^{3}\mathrm{He}$ atom bound to a cluster with $N$ $^{4}\mathrm{He}$ atoms, with the aim of establishing the most adequate filling ordering of single-fermion orbits to the mixed clusters with a large number of $^{3}\mathrm{He}$ atoms. The resulting ordering looks like the rotational spectrum of a diatomic molecule, being classified only by the angular momentum of the level, although vibrational-like excitations appear at higher energies for sufficiently large $N$.

PhysicsAngular momentumHelium-4AtomPhysics::Atomic and Molecular ClustersCluster (physics)Diffusion Monte CarloFermionAtomic physicsDiatomic moleculeAtomic and Molecular Physics and OpticsExcitationPhysical Review A
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Excitation levels and magic numbers of small parahydrogen clusters (N⩽40)

2008

The excitation energies of parahydrogen clusters have been systematically calculated by the diffusion Monte Carlo technique in steps of one molecule from 3 to 40 molecules. These clusters possess a very rich spectra, with angular momentum excitations arriving up to L=13 for the heavier ones. No regular pattern can be guessed in terms of the angular momenta and the size of the cluster. Clusters with N=13 and 36 are characterized by a peak in the chemical potential and a large energy gap of the first excited level, which indicate the magical character of these clusters. From the calculated excitation energies the partition function has been obtained, thus allowing for an estimate of thermal e…

PhysicsAngular momentumPartition function (statistical mechanics)Excited statesFOS: Physical sciencesGeneral Physics and AstronomyMonte Carlo methodsSpin isomers of hydrogenMolecular physicsSpectral lineUNESCO::FÍSICA::Química físicaEnergy gapMolecular clustersExcited stateChemical potential ; Energy gap ; Excited states ; Molecular clusters ; Monte Carlo methodsCluster (physics)Diffusion Monte CarloPhysics - Atomic and Molecular ClustersPhysical and Theoretical Chemistry:FÍSICA::Química física [UNESCO]Atomic and Molecular Clusters (physics.atm-clus)Chemical potentialExcitationThe Journal of Chemical Physics
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Rotational Motion of Linear Molecules in Three Dimensions. A Path-Integral Monte Carlo Approach

1994

Abstract A path-integral Monte Carlo (PIMC) simulation method for the rotational motion of linear molecules in three dimensions is presented. The technique is applied to an H2 impurity in a static crystal-field. The resulting orientational distributions from quantum and classical simulations are obtained and discussed. The algorithm suffers from the “sign problem” of quantum simulations. However, as can be seen by comparing the low temperature simulation result to the variational solution of the Schrodinger equation, the PIMC method captures the quantum fluctuations.

PhysicsGeneral Chemical EngineeringQuantum Monte CarloMonte Carlo methodGeneral ChemistryCondensed Matter PhysicsHybrid Monte CarloModeling and SimulationDynamic Monte Carlo methodGeneral Materials ScienceMonte Carlo integrationDiffusion Monte CarloStatistical physicsPath integral Monte CarloInformation SystemsMonte Carlo molecular modelingMolecular Simulation
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