Search results for "Diffusion"

showing 10 items of 1615 documents

Comparative electrochemical treatments of two chlorinated aliphatic hydrocarbons. Time course of the main reaction by-products.

2011

The chlorinated aliphatic hydrocarbons conjugate toxicity with high chemical stability, bioaccumulation and long-range diffusivity. Chloroethanes are particularly ubiquitous in the industry and in household products, and their entry to the environment may entail potential risks for the living beings. At present, the US Environmental Protection Agency is carrying out the Endocrine Disruptor Screening Program (EDSP), where 1,2-dichloroethane (DCA) and 1,1,2,2-tetrachloroethane (TCA) are considered as priorities for their potential effects on the endocrine system. DCA is also found in the list of priority substances drawn up by the European Commission. To avoid the release of chloroethanes int…

Environmental EngineeringTime FactorsFormic acidHealth Toxicology and MutagenesisOxalic acidInorganic chemistryReaction pathway1122-Tetrachloroethanechemistry.chemical_element12-DichloroethaneAcetatesElectrochemistryOrganochlorinated pollutant1122-Tetrachloroethane.Chemistry Techniques AnalyticalDiffusionchemistry.chemical_compound12-DichloroethaneElectrochemical water treatment technologieOxidizing agentChlorineElectrochemistryHydrocarbons ChlorinatedEnvironmental ChemistryEthylene DichloridesWaste Management and DisposalElectrodesEthaneAqueous solutionDichloroacetic Acid1122-TetrachloroethaneEquipment DesignHydrogen PeroxidePollutionOxygenchemistryElectro-FentonChlorineJournal of hazardous materials
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An easy-to-use model for O2 supply to red muscle. Validity of assumptions, sensitivity to errors in data

1995

An easy-to-use capillary cylinder model of O2 supply to muscle is presented that considers all those factors that are known to be most important for realistic results: (1) red blood cell (RBC) O2 unloading along the capillary, (2) effects of the particulate nature of blood, (3) free and hemoglobin-facilitated O2 diffusion and reaction kinetics inside RBCs, (4) free and myoglobin-facilitated O2 diffusion inside the muscle cell, and (5) carrier-free region separating RBC and tissue. In a first approach, a highly simplified yet reasonably accurate treatment of the complex three-dimensional oxygen diffusion field in and next to capillaries is employed. As an alternative, a more realistic descri…

ErythrocytesField (physics)Capillary actionBiophysicsBiological Transport ActiveNanotechnologyModels BiologicalBiophysical PhenomenaInterpretation (model theory)DiffusionHemoglobinsDogsOxygen ConsumptionRange (statistics)CylinderAnimalsComputer SimulationSensitivity (control systems)Diffusion (business)MathematicsPropagation of uncertaintyMyoglobinMusclesMechanicsOxygenKineticsMathematicsResearch ArticleBiophysical Journal
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Colorimetric determination of alcohols in spirit drinks using a reversible solid sensor

2018

Abstract A sensor for the colorimetric estimation of the alcoholic content has been developed based on the entrapment of the reagent (4-N,N-dioctylamino)-4‘-trifluoroacetylazobenzene (ETHT 4001) into polydimethylsiloxane (PDMS) modified with tretraethylorthosilicate (TEOS). When exposed to an alcoholic media, the sensor delivers ETHT 4001 so that it reacts with alcohols, resulting in a change in the solution color. The diffusion of the entrapped ETHT 4001 from the polymeric sensor to the working solution depends on the hydrophobicity of both the sensor matrix and the media, while the time of exposure determines whether the reagent reacts with methanol, or with methanol and ethanol. Thus, th…

EthanolChromatographyPolydimethylsiloxaneChemistryDiffusion010401 analytical chemistry02 engineering and technology021001 nanoscience & nanotechnology01 natural sciences0104 chemical sciencesAbsorbanceMatrix (chemical analysis)chemistry.chemical_compoundReagentMethanol0210 nano-technologyFood ScienceBiotechnologyFood Control
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An ethoxylated surfactant enhances the penetration of the sulfated laminarin through leaf cuticle and stomata, leading to increased induced resistanc…

2016

International audience; Some β-1,3-glucans and particularly sulfated laminarin (PS3) are known as resistance inducers (RIs) in grapevine against the downy mildew. However, their efficacy in vineyard is still often too low, which might be caused by a limited penetration through the leaf cuticle following spray application. We used (14) C-sucrose uptake experiments with grapevine leaves in order to select a surfactant as saccharide penetration enhancer. Our results showed that though sucrose foliar uptake was low, it was strongly enhanced by Dehscofix CO125 (DE), a highly ethoxylated surfactant. Fluorescent saccharides were then produced and laser scanning microscopy was used to analyze their…

Ethylene Oxide0106 biological sciences0301 basic medicineSucrosePhysiologyPlant ScienceBiologyDisaccharides[ CHIM ] Chemical Sciences01 natural sciencesFluorescenceDiffusionCell wallSurface-Active Agents03 medical and health sciencesLaminarinchemistry.chemical_compoundPulmonary surfactantPolysaccharidesBotanyGenetics[CHIM]Chemical SciencesVitisCarbon RadioisotopesDisease ResistancePlant DiseasesPlant Stomatafood and beveragesCell BiologyGeneral MedicinePenetration (firestop)TrichomeKineticsHorticultureCholesterol030104 developmental biologyOomycetesPlant cuticlechemistryWaxesPlant StomataDowny mildew010606 plant biology & botanyPhysiologia Plantarum
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La comunicación: disciplina y campo de estudio. La experiencia latina

2011

La investigación en comunicación presenta una serie de particularidades que le otorgan un interés específico y una cierta capacidad de adaptación a la hora de analizar los fenómenos sociales. Se trata de una disciplina y un campo de estudio a la vez, lo que implica una necesaria transdisciplinariedad en el proceso de estudio de los paradigmas sociales y de formación de los profesionales de la comunicación. Esta adaptación de los estudios de comunicación supone una redefinición de las características propias de cada contexto, especialmente si se ha de llevar a cabo este estudio en América latina y en la Europa latina (Francia, Portugal, España e Italia). Su consideración como un espacio prop…

Europa LatinaConcentrationCommunicationResearchInterdisciplinarityAmérique LatineDéveloppement et innovationRechercheDifusiónConcentraciónEurope LatineArte. GeneralidadesI+D+IDiffusionLatin AmericaAmérica LatinaTransdisciplinariedadInvestigaciónInterdisciplinaritéLatin EuropeArteComunicación
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On new ways of group methods for reduction of evolution-type equations

2005

AbstractNew exact solutions of the evolution-type equations are constructed by means of a non-point (contact) symmetries. Also we analyzed the discrete symmetries of Maxwell equations in vacuum and decoupled ones to the four independent equations that can be solved independently.

Exact solutionGroup (mathematics)Independent equationApplied MathematicsMathematical analysisInhomogeneous electromagnetic wave equationEuler equationsSymmetrysymbols.namesakereaction-diffusion equationsExact solutions in general relativityMaxwell's equationsSimultaneous equationsHomogeneous spacesymbolsAnalysisMathematicsJournal of Mathematical Analysis and Applications
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Forward and backward diffusion approximations for haploid exchangeable population models

2001

Abstract The class of haploid population models with non-overlapping generations and fixed population size N is considered such that the family sizes ν1,…,νN within a generation are exchangeable random variables. A criterion for weak convergence in the Skorohod sense is established for a properly time- and space-scaled process counting the number of descendants forward in time. The generator A of the limit process X is constructed using the joint moments of the offspring variables ν1,…,νN. In particular, the Wright–Fisher diffusion with generator Af(x)= 1 2 x(1−x)f″(x) appears in the limit as the population size N tends to infinity if and only if the condition lim N→∞ E((ν 1 −1) 3 )/(N Var …

Exchangeable random variablesStatistics and ProbabilityDualityPopulation geneticsCoalescent theoryDiffusion approximationModelling and SimulationQuantitative Biology::Populations and EvolutionNeutralityWright–Fisher diffusionHille–Yosida theoremWeak convergenceMathematicsWeak convergenceApplied MathematicsMathematical analysisHeavy traffic approximationCommutative diagramHille–Yosida theoremPopulation modelDiffusion processModeling and SimulationAncestorsDescendantsExchangeabilityCoalescentStochastic Processes and their Applications
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Study of the reactive dynamics of nanometric metallic multilayers using Molecular Dynamics: the Al−Ni system

2012

A molecular dynamics study of a layered Ni-Al-Ni system is developed using an embedded atom method potential. The specific geometry is designed to model a Ni-Al nanometric metallic multilayer. The system is initially thermalized at the fixed temperature of 600 K. We first observe the interdiffusion of Ni and Al at the interfaces, which is followed by the spontaneous phase formation of B2-NiAl in the Al layer. The solid-state reaction is associated with a rapid system's heating which further enhances the diffusion processes. NiAl phase is organized in small regions separated by grain boundaries. This study confirms the hypothesis of a layer-by-layer development of the new phase. For longer t…

Exothermic reactionNialMaterials scienceDiffusionmultilayersIntermetallicnanometric metallic multilayersNanotechnology02 engineering and technology01 natural sciencesinterfacesMolecular dynamicsPhase (matter)0103 physical sciencesGeneral Materials Scienceintermetallics010306 general physicscomputer.programming_languageRadiationnanoscale effects[CHIM.MATE]Chemical Sciences/Material chemistry021001 nanoscience & nanotechnologyCondensed Matter PhysicsMicrostructuremolecular dynamics[ PHYS.PHYS.PHYS-CHEM-PH ] Physics [physics]/Physics [physics]/Chemical Physics [physics.chem-ph]Chemical physics[ CHIM.MATE ] Chemical Sciences/Material chemistryGrain boundary[PHYS.PHYS.PHYS-CHEM-PH]Physics [physics]/Physics [physics]/Chemical Physics [physics.chem-ph]0210 nano-technologycomputer
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An exploratory study of COVID-19 misinformation on Twitter.

2020

During the COVID-19 pandemic, social media has become a home ground for misinformation. To tackle this infodemic, scientific oversight, as well as a better understanding by practitioners in crisis management, is needed. We have conducted an exploratory study into the propagation, authors and content of misinformation on Twitter around the topic of COVID-19 in order to gain early insights. We have collected all tweets mentioned in the verdicts of fact-checked claims related to COVID-19 by over 92 professional fact-checking organisations between January and mid-July 2020 and share this corpus with the community. This resulted in 1 500 tweets relating to 1 274 false and 276 partially false cla…

FOS: Computer and information sciencesCoronavirus disease 2019 (COVID-19)Computer Networks and CommunicationsDiffusion of informationInternet privacyTwitterExploratory research02 engineering and technologyCrisis managementFalse accusationArticleSocial mediaComputer Science - Computers and SocietyOrder (exchange)Computers and Society (cs.CY)0202 electrical engineering electronic engineering information engineeringSocial mediaMisinformationSocial and Information Networks (cs.SI)business.industryCommunicationCOVID-19Computer Science - Social and Information Networks020206 networking & telecommunicationsExploratory analysisVDP::Samfunnsvitenskap: 200::Sosiologi: 220CoronavirusInformatikFake newsMisinformation020201 artificial intelligence & image processingPsychologybusinessInformation SystemsOnline social networks and media
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Diffusion map for clustering fMRI spatial maps extracted by Indipendent Component Analysis

2013

Functional magnetic resonance imaging (fMRI) produces data about activity inside the brain, from which spatial maps can be extracted by independent component analysis (ICA). In datasets, there are n spatial maps that contain p voxels. The number of voxels is very high compared to the number of analyzed spatial maps. Clustering of the spatial maps is usually based on correlation matrices. This usually works well, although such a similarity matrix inherently can explain only a certain amount of the total variance contained in the high-dimensional data where n is relatively small but p is large. For high-dimensional space, it is reasonable to perform dimensionality reduction before clustering.…

FOS: Computer and information sciencesDiffusion (acoustics)Computer sciencediffusion mapMachine Learning (stat.ML)02 engineering and technologycomputer.software_genreMachine Learning (cs.LG)Computational Engineering Finance and Science (cs.CE)Correlation03 medical and health sciencesTotal variation0302 clinical medicineStatistics - Machine LearningVoxel0202 electrical engineering electronic engineering information engineeringComputer Science - Computational Engineering Finance and ScienceCluster analysisdimensionality reductionta113spatial mapsbusiness.industryDimensionality reductionfunctional magnetic resonance imaging (fMRI)Pattern recognitionIndependent component analysisSpectral clusteringComputer Science - Learningindependent component analysista6131020201 artificial intelligence & image processingArtificial intelligenceDYNAMICAL-SYSTEMSbusinesscomputer030217 neurology & neurosurgeryclustering
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