Search results for "Diffusiophoresis"

Thermodynamic Approach to the Self-Diffusiophoresis of Colloidal Janus Particles

2019

Most available theoretical predictions for the self-diffusiophoretic motion of colloidal particles are based on the hydrodynamic thin boundary layer approximation in combination with a solvent body force due to a self-generated local solute gradient. This gradient is enforced through specifying boundary conditions, typically without accounting for the thermodynamic cost to maintain the gradient. Here, we present an alternative thermodynamic approach that exploits a direct link between dynamics and entropy production: the local detailed balance condition. We study two cases: First, we revisit self-propulsion in a demixing binary solvent. At variance with a slip velocity, we find that propuls…