Search results for "Direct method"
showing 10 items of 51 documents
Application of delta recycling to electron automated diffraction tomography data from inorganic crystalline nanovolumes
2013
δ Recycling is a simple procedure for directly extracting phase information from Patterson-type functions [Rius (2012). Acta Cryst. A68, 399-400]. This new phasing method has a clear theoretical basis and was developed with ideal single-crystal X-ray diffraction data. On the other hand, introduction of the automated diffraction tomography (ADT) technique has represented a significant advance in electron diffraction data collection [Kolb et al. (2007). Ultramicroscopy, 107, 507-513]. When combined with precession electron diffraction, it delivers quasi-kinematical intensity data even for complex inorganic compounds, so that single-crystal diffraction data of nanometric volumes are now availa…
Using FOCUS to solve zeolite structures from three-dimensional electron diffraction data
2013
The programFOCUS[Grosse-Kunstleve, McCusker & Baerlocher (1997).J. Appl. Cryst.30, 985–995] was originally developed to solve zeolite structures from X-ray powder diffraction data. It uses zeolite-specific chemical information (three-dimensional 4-connected framework structure with known bond distances and angles) to supplement the diffraction data. In this way, it is possible to compensate, at least in part, for the ambiguity of the reflection intensities resulting from reflection overlap, and the program has proven to be quite successful. Recently, advances in electron microscopy have led to the development of automated diffraction tomography (ADT) and rotation electron diffraction (R…
Forecasting industry sector default rates through dynamic factor models
2008
In this paper we use a reduced-form model for the analysis of portfolio credit risk. For this purpose, we fit a dynamic factor model to a large data set of default rate proxies and macro-variables for Italy. Multiple step ahead density and probability forecasts are obtained by employing both the direct and indirect methods of prediction together with stochastic simulation of the dynamic factor model. We first find that the direct method is the best performer regarding the out-of-sample projection of financial distressful events. In a second stage of the analysis, we find that reducedform portfolio credit risk measures obtained through the dynamic factor model are lower than those correspond…
Measuring rill erosion at plot scale by a drone-based technology
2015
The traditional direct method (i.e. metric ruler and rillmeter) of monitoring rill erosion at plot scale is time consuming and invasive because it modifies the surface of the rilled area. Measuring rill features using a drone-based technology is considered a non-invasive method allowing a fast field relief. In the experimental Sparacia area a survey by a quadricopter Microdrones md4-200 was carried out, and this relief allowed the generation of a Digital Elevation Model (DEM), with a mesh size of 1 cm and a resolution elevation equal to 2 mm, for three plots (L, G and C) affected by rill erosion. At first for the experimental L plot, which is 44 m long, the rill features were surveyed by a …
La traducció en l'ensenyament de llengües : un recurs exclòs de les aules del mètode directe?
2022
Tradicionalment s'ha pensat que la traducció com a eina a l'aula de llengües estrangeres va quedar desaconsellada en el mètode directe. Així, des de llavors, molts docents han defensat la idea que la traducció és un recurs nociu per ensenyar idiomes, encara que, segons Cook (2010), no hi ha evidències que ho hagin provat científicament. Abans de continuar acceptant aquesta creença heretada del mètode directe, pensem que és necessari revaluar si la traducció va ser rebutjada per tots els seus exponents i si va ser realment possible excloure-la de les aules del moment. Per tant, l'objectiu d'aquest article és dur a terme una revisió teòrica sobre què va ser, quan i per què va sorgir el mètode…
Multicommutation cold vapour atomic fluorescence determination of Hg in water.
2002
Abstract A multicommutation-based method has been developed for the on-line direct atomic fluorescence spectrometric (AFS) determination of Hg in waters without any previous sample treatment. The performance of the proposed procedure has been compared with that of a conventional AFS system based on continuous mode measurements. In short, the use of multicommutation, together with a reduction of the size of the liquid–gas phase separator, provides an increase of the laboratory productivity by improving the sample throughput by a factor of 3.6 and strongly reduces the sample consumed by a factor of 6 and reagent consumed by a factor of 8.4. The waste generation is reduced by a factor of 2.4 a…
Combining EXAFS and XRay Powder Diffraction to Solve Structures Containing Heavy Atoms
2005
Determination of structures using x-ray powder diffraction is complicated if the reflection intensities are mainly influenced by the scattering from heavy atoms and the atomic coordinates of light atoms remain uncertain. A method like EXAFS, which is sensitive to short range order, gives reliable atomic distances in the surroundings of heavy atoms with a precision of ±0.02 A. The probability for obtaining the complete structure from x-ray powder diffraction increases if one includes parameters derived from EXAFS measurements as restraints during the procedure of structure solving. We demonstrate the potential of combining EXAFS and x-ray powder diffraction by solving the structure UO2[H2AsO…
Approximate Solution on Large Deflection of Glass Panels Subjected to Uniform Pressure
2015
The estimation of the deflection of glass panels under wind pressure is important in designing external facades of buildings. A direct method to compute the large deflections of glass panels under uniform loads such as wind pressure is presented. The model allows for derivation of the load-deflection response of square or rectangular multilayered glass panels subject to uniform loads. The boundary conditions examined are those of four-point discontinuous supports or continuous supports along the four sides. With some assumptions on bending and membrane action of flat glasses, simple analytical expressions were derived from the elastic theory. Viscoelastic effects for multilayered glass pane…
Non-linear systems under delta correlated processes handled by perturbation theory
1998
Statistical responses in terms of moment and correlation functions of non-linear systems driven by non-normal delta correlated external pulses are derived. The procedure takes full advantage of the perturbation theory approach. Then, by means of a proper coordinate transformation, the system is replaced by a quasi-linear system for which the statistical quantities can be exactly found.
Efficient numerical methods for pricing American options under stochastic volatility
2007
Five numerical methods for pricing American put options under Heston's stochastic volatility model are described and compared. The option prices are obtained as the solution of a two-dimensional parabolic partial differential inequality. A finite difference discretization on nonuniform grids leading to linear complementarity problems with M-matrices is proposed. The projected SOR, a projected multigrid method, an operator splitting method, a penalty method, and a componentwise splitting method are considered. The last one is a direct method while all other methods are iterative. The resulting systems of linear equations in the operator splitting method and in the penalty method are solved u…