Search results for "Dispersion"
showing 10 items of 1101 documents
Simple method for measuring bilayer system optical parameters
2012
A simple method for measuring bilayer system refractive indexes and thicknesses in the low absorbing part of spectra is demonstrated. The method is based on application of Savitzky - Golay smoothing filters and interference fringe separation in the reflected or transmitted spectra of the bilayer system. The refractive indexes and thicknesses are extracted from the wavelengths corresponding to extreme points in the spectrum. Due to the fact that wavelength difference of extreme points in the analyzed spectrum is defined by the product of both, the layer thickness and refractive index, one must generate an appropriate initial guess of these parameters. For refractive index approximation two d…
Microstructured Optical Fiber on the Silica Platform for pulse-maintaining 2-octave supercontinuum in short-wavelength infra-red
2016
Numerical design of all normal dispersion fiber for SWIR supercontinuum generation based on standard air-silica microstructure is presented. We increase the spectral width of generated supercontinuum up to 2 octaves while maintaining perfect spectral flatness by tailoring the dispersion profile.
Effect of different dispersing additives on the morphology and the properties of polyethylene-based nanocomposite films
2011
In this work, the use of a polar wax, e.g. amphiphilic Tegomer ® E 525 (TEG) is investigated with the aim of mod- ifying, and possibly improving, the dispersion of an organically modified nanoclay (OMMT), loaded at 5 wt%, in a poly- ethylene matrix (PE) at relatively low loading levels. We have indeed found that the incorporation of low loadings, e.g. 0.5 wt%, of TEG, an amphiphilic block co-polymer, into a PE/OMMT sample results in a substantial improvement of the clay dispersion in the nanocomposite and, consequently, of the mechanical and thermomechanical properties of the films. The achieved results are comparable to those obtained for systems containing traditional dispersing agents su…
Flavor release from salad dressings: sensory and physicochemical approaches in relation with the structure
2000
The effect of process and formulation on sensory perception and flavor release was investigated on salad dressing models. Oil/vinegar emulsions (φ = 0.5, droplet size > 10 μm) with thickeners and a whey protein concentrate were prepared with different fat droplet sizes and different distributions of fat droplet size. The effect of the amount of emulsifier was also tested. Sensory profile analysis was performed by a trained panel and flavor release quantified by dynamic headspace analysis. When the droplet size is increased, the lemon smell and citrus aroma significantly increase, whereas the egg note, mustard, and butter aroma significantly decrease. The concentrations of alcohols and acids…
Overdispersion tests in count-data analysis.
2008
Count data are commonly assumed to have a Poisson distribution, especially when there is no diagnostic procedure for checking this assumption. However, count data rarely fit the restrictive assumptions of the Poisson distribution. The violation of much of such assumptions commonly results in overdispersion, which invalidates the Poisson distribution. Undetected overdispersion may entail important misleading inferences, so its detection is essential. In this study, different overdispersion diagnostic tests are evaluated through two simulation studies. In Exp. 1, the nominal error rate is compared under different sample sizes and Λ conditions. Analysis shows a remarkable performance of the χ…
Peak dispersion in gradient elution: An insight based on the plate model.
2020
Gradient elution in liquid chromatography reduces the analysis time, improves the efficiency and increases the peak capacity. The study of this chromatographic mode has been based mainly on kinetic dispersion models. The plate model has been applied to a lesser extent, despite being the basis for the concepts of plate height and chromatographic efficiency. In this work, a general equation describing peak dispersion in HPLC gradient elution is derived from the plate model. This equation is studied and validated for three types of gradients: (i) a reference gradient without ramp in which the retention factor varies with time identically throughout the column, (ii) a gradient of stationary pha…
Theoretical study on hydrogen storage capacity of expanded h-BN systems
2017
In this work, the hydrogen storage capacity of the expanded hexagonal Boron Nitride (eh-BN) systems has been presented. We have employed a new equation of state (EOS) for hydrogen gas to figure out the hydrogen density distribution profiles in the eh-BN systems. In this regard, the environmental conditions (i.e., temperature and pressure) are considered in the prediction procedure using DFT single point calculations. The eh-BN systems with different layer spacings are studied by PBE method with consideration of the long range dispersion corrections. On account of the in-plane polar bonds, a series of adsorption positions are considered. Additionally, the adsorption energy and hydrogen densi…
On the measurement of local gas hold-up, interfacial area and bubble size distribution in gas–liquid contactors via light sheet and image analysis: I…
2013
Abstract In this work a novel experimental technique for measuring local gas hold-up, interfacial area and bubble size distribution, in gas–liquid systems is proposed. The technique is based on advanced Image Processing coupled with experimental set-ups typically available for Particle Image Velocimetry. A fluorescent dye dissolved in the liquid phase allows to identify in-plane bubbles among all visible bubbles in the images. To this end, a suitable algorithm is proposed. The raw data so obtained are processed by previously developed statistical methods that result in a reliable reconstruction of actual dispersion properties. The technique is applied to the case of a gas-dispersed mechanic…
Wall collision and drug-carrier detachment in dry powder inhalers: Using DEM to devise a sub-scale model for CFD calculations
2018
Abstract In this work, the Discrete Element Method (DEM) is used to simulate the dispersion process of Active Pharmaceutical Ingredients (API) after a wall collision in dry powders inhaler used for lung delivery. Any fluid dynamic effects are neglected in this analysis at the moment. A three-dimensional model is implemented with one carrier particle (diameter 100 μm) and 882 drug particles (diameter 5 μm). The effect of the impact velocity (varied between 1 and 20 m s−1), angle of impact (between 5° and 90°) and the carrier rotation (±100,000 rad s−1) are investigated for both elastic and sticky walls. The dispersion process shows a preferential area of drug detachment located in the southe…
Optical properties of TiO2 suspensions: Influence of pH and powder concentration on mean particle size
2007
WOS: 000250584100025