Search results for "Distillation"

Inhibitory Activity and Chemical Characterization ofDaucus carotasubsp.maximusEssential Oils

2017

The essential oils (EOs) of green seeds from Daucus carota subsp. maximus growing wild in Pantelleria Island (Sicily, Italy) were characterized. EOs were extracted by steam distillation, examined for their inhibitory properties against food-borne Gram-positive and Gram-negative bacteria and analyzed for the chemical composition by gas chromatography (GC) and mass spectrometry (MS). Undiluted EOs showed a large inhibition spectrum against Gram-positive strains and also vs. Acinetobacter spp. and Stenotrophomonas maltophilia. The minimum inhibition concentration (MIC) was in the range 1.25 – 2.50 μl/ml for the most sensitive strains. The chemical analysis indicated that D. carota subsp…

CHEMICAL COMPOSITION OF THE ESSENTIAL OILS OF SOME TAXA OF THE GENUS CLINOPODIUM (LAMIACEAE) FROM SICILY

2017

The genus Clinopodium L. (Lamiaceae) is known for its medical uses in folk medicine and as a spice in Italian food. Recently, several taxa previously assigned to Satureja L. and Calamintha Mill. have been transferred to this genus (1). Pharmacological studies reveal, for instance, that Calamintha nepeta (L.) Savi [Clinopodium nepeta Kuntze subsp. nepeta], commonly known as “nepetella”, exhibits cholagogue, expectorant, sedative and antibiotic properties (2); furthermore, the essential oil of its aerial parts showed an antifungal activity (3). The apical flowering parts and leaves of Clinopodium vulgare L. are used in popular medicine for their carminative and emmenagogue properties (1); rec…

Essential oils composition of two Sicilian cultivars of Opuntia ficus-indica (L.) Mill. (Cactaceae) fruits (prickly pear).

2013

The essential oils composition of the skin, pulp and seeds from fruits of two Sicilian cultivars of Opuntia ficus-indica (cv. Sanguigna and cv. Surfarina) has been obtained by hydrodistillation and the possible antioxidant, antimicrobial and semiochemical roles have been investigated comparing the data with those reported in the literature. The presence of antioxidants and antimicrobials found in this study increases the spectrum of compounds that have beneficial properties in O. ficus-indica. In addition, several compounds identified in this study have been reported to influence the behaviour of Ceratitis capitata, a phytophagous pest which causes severe damages to several crops including …

Essential oil components of orange peels and antimicrobial activity

2016

In this study, the orange peel of 12 cultivars of Citrus sinensis from central-eastern Sicily was employed to obtain essential oils and extracts. The ones were extracted through steam distillation, the others through extraction in hexane. Chemical constituents were evaluated in terms of qualitative and quantitative analyses by gas chromatography/mass spectrometry. Fifty-four components were identified in the steam essential oils and 44 in the extracts. In all the cultivars, the main component is d-limonene (73.9–97%); discrete percentages of linalool, geraniol and nerol were also found. Cluster analysis based on essential oils composition showed a certain degree of affinity between cultivar…

PMRs Utilizing Non–Pressure-Driven Membrane Techniques

2018

In the present chapter it is shown how photocatalytic membrane reactors utilizing membrane processes, which are not pressure driven, can exploit various mechanisms to obtain a substantial improvement of the process. The fundamentals of this particular type of membrane reactors are reviewed including the effects of the most important parameters and the methods and rules of coupling photocatalysis and membrane separation. The survey of the studies on photocatalytic membrane reactors (PMRs) utilizing pervaporation, dialysis, membrane contactors and membrane distillation offers the opportunity of discussing the advantages with respect to PMRs adopting pressure driven membrane processes. Indeed,…

Photocatalytic Membrane Reactors: Case Studies and Perspectives

2009

Photocatalysis by polycrystalline semiconductor oxides is being successfully applied to the abatement of organic and inorganic pollutants both in gas and in liquid phase. In order to increase the efficiency of this method, the coupling of this technology with the membrane separation process has been the object of sound investigation. In this combination, the membrane may act in different ways: to confine the photocatalytic powder in the reacting suspension, to selectively separate the photoreaction products, or to be the support of photocatalyst. This article reports recent studies in which different types of membranes (such as distillation, dialysis, nanofiltration, pervaporation and osmos…

CHARACTERIZATION OF HYDROPHOBIC POLYMERIC MEMBRANES FOR MEMBRANE DISTILLATION PROCESS

2010

Hydrophobic microporous membranes are utilized in membrane distillation (MD) processes, e.g. seawater desalination at moderate temperatures. The vapour permeability of commercial hydrophobic membranes with different pore sizes (0.2-1 micron) was characterized through a simple apparatus designed-on-purpose. A cylindrical vessel had a face closed by the membrane and the other connected to a thin graduate tube. The water level variation in the tube is recorded and related to the vapour flux across the membrane. Measurements were taken in the temperature range 20-80°C. A fan tangential to membrane surface was employed to maintain a constant driving force for vapour transport. Vapour flux did no…

Turbulent heat transfer in spacer-filled channels: Experimental and computational study and selection of turbulence models

2019

Abstract Heat transfer in spacer-filled channels of the kind used in Membrane Distillation was studied in the Reynolds number range 100–2000, encompassing both steady laminar and early-turbulent flow conditions. Experimental data, including distributions of the local heat transfer coefficient h, were obtained by Liquid Crystal Thermography and Digital Image Processing. Alternative turbulence models, both of first order (k-e, RNG k-e, k-ω, BSL k-ω, SST k-ω) and of second order (LRR RS, SSG RS, ω RS, BSL RS), were tested for their ability to predict measured distributions and mean values of h. The best agreement with the experimental results was provided by first-order ω-based models able to …

Techno-economic analysis of integrated processes for the treatment and valorisation of neutral coal mine effluents

2020

Abstract The disposal of highly-concentrated neutral coal mine effluents into the environment constitutes a severe threat to the natural ecosystem. This work proposes and compares five novel treatment chains to purify the effluent and recover raw materials. The chains present different combinations of pre-treatment and concentration technologies. In all cases, the solution sent to the concentration step is concentrated up to saturation to recover water and sodium chloride. Concerning the technical performances, the treatment chains are compared in terms of total energy demand and salt recovery. Furthermore, the economic feasibility assessment is performed via a novel global parameter, i.e. …

CFD parametrical study of the spacer geometry for Membrane Distillation

Membrane Distillation (MD) is a thermal process that separates water from aqueous solutions containing non-volatile components such as salt. Water vapor from the hot feed channel permeates through a hydrophobic membrane thanks to a partial pressure gradient, and condenses in the cool channel. One of the main advantages of MD is the easy coupling with renewable resources, as the solar thermal energy. In the various MD configurations developed, net spacers are used in order to support the membrane, thus creating the channels; moreover, they can counteract the side effects of temperature polarization by promoting mixing. However, the presence of the spacer involves an increase of pressure drop…