Search results for "Distillation"
showing 10 items of 184 documents
Polish Yellow Sweet Clover (Melilotus officinalis L.) Honey, Chromatographic Fingerprints, and Chemical Markers
2017
A case study of Polish Melilotus officinalis honey was presented for the first time. Gas chromatography–mass spectrometry (GC-MS) (after steam distillation, Soxhlet extraction, ultrasonic solvent extraction, and solid phase extraction (SPE)) and targeted high performance liquid chromatography with a photodiode array detector (HPLC-PAD) were applied to determine the characteristic components of honey. While ubiquitous in most honeys, carbohydrates, terpene derivatives, and phenylacetic acid dominated in the Soxhlet extracts (25.54%) and in the application of SPE (13.04%). In addition, lumichrome (1.85%) was found, and may be considered as a marker of this honey. Due to the presence of these …
On-line solvent recycling: a tool for the development of clean analytical chemistry in flow injection Fourier transform infrared spectrometry. Determ…
1998
Abstract A flow injection strategy has been developed for the direct determination of ketoprofen in pharmaceuticals by Fourier transform infrared spectrometry also incorporating a distillation unit which allows the carbon tetrachloride employed to dissolve samples and standards and used as a carrier to be recovered on-line. The system developed permits a drastic reduction of reagent consumption and easy and fast sampling and cleaning of the measurement cell. For the quantification of ketoprofen in pharmaceuticals the carbonyl bands at 1712 and 1666 cm −1 were employed and the developed method provided a 3 σ limit of detection of 0.04 mg ml −1 , a dynamic range up to 10 mg ml −1 and typical …
Atomic fluorescence determination of inorganic arsenic in soils after microwave-assisted distillation
2000
Abstract An inexpensive microwave-assisted distillation procedure has been developed for quantitative determination of inorganic arsenic in soils by atomic fluorescence spectrometry (AFS). After reduction of As(V) to its trivalent state with potassium iodide, inorganic arsenic was distilled as AsCl 3 that was finally determined by atomic fluorescence after hydride generation with NaBH 4 in HCl medium. The different parameters that control the distillation: concentration and volume of HCl, time of distillation, sample weight, and oven load, were studied. The methodology developed has a detection limit of 0.015 μg l −1 , which corresponds to a concentration of 0.006 μg of As per gram of soil,…
ASSESMENT OF TEMPERATURE POLARIZATION IN MEMBRANE DISTILLATION CHANNELS BY LIQUID CRYSTAL THERMOGRAPHY
2014
AbstractThe measurement of local temperature distributions within a membrane distillation (MD) channel is a crucial step for the optimization of the channel and spacer geometry. This information allows the estimation of temperature polarization phenomena, which can dramatically influence the thermal efficiency of the process and the optimal choice of the geometric configuration (net spacer features, channel size, etc.). In the present work, a recently presented experimental technique, based on the use of thermochromic liquid crystals and digital image analysis, has been employed in order to assess the temperature polarization phenomena. The local heat transfer coefficient distribution on th…
Evaluation of the Economic and Environmental Performance of Low-Temperature Heat to Power Conversion using a Reverse Electrodialysis – Multi-Effect D…
2019
In the examined heat engine, reverse electrodialysis (RED) is used to generate electricity from the salinity difference between two artificial solutions. The salinity gradient is restored through a multi-effect distillation system (MED) powered by low-temperature waste heat at 100 °C. The current work presents the first comprehensive economic and environmental analysis of this advanced concept, when varying the number of MED effects, the system sizing, the salt of the solutions, and other key parameters. The levelized cost of electricity (LCOE) has been calculated, showing that competitive solutions can be reached only when the system is at least medium to large scale. The lowest LCOE, at a…
CHP (combined heat and power) retrofit for a large MED-TVC (multiple effect distillation along with thermal vapour compression) desalination plant: H…
2016
Abstract Integrated power plants in “dual purpose” configuration may represent a viable option for energy cost abatement of desalted water produced by MED-TVC (Multiple Effect Distillation along with Thermal Vapour Compression). In this paper an existing large MED-TVC plant with a 36,000 m 3 /day capacity is studied: a plant retrofit is designed, based on a steam power plant with condensation and steam extraction used to drive the steam ejector. As the plant operates in CHP (Combined Heat and Power) mode, the possibility to assess the integrated “CHP + MED-TVC” as high efficiency cogeneration according to Directive 2004/8/EC is discussed. Based on a model developed in Engineering Equation S…
A dynamic model for MED-TVC transient operation
2017
Abstract The Multi Effect Distillation (MED) process is often proposed as a key technology for the construction of new thermal desalination plants, especially within solar-powered cogeneration schemes. With this respect, the need for transient behaviour analysis requires the development of dynamic models for the MED process. Only a few have been presented so far in the literature, in which, however, several simplifying assumptions and constrains are still limiting their potential use. The model here proposed addresses most of the aspects still limiting previous models formulations. The powerful equation-based process simulator gPROMS® was chosen for the implementation of the model, develope…
A neural network-based optimizing control system for a seawater-desalination solar-powered membrane distillation unit
2013
Abstract Several schemes have been proposed so far for coupling desalination processes with the use of renewable energy. One of their main drawbacks, however, is the nature of the energy source that requires a discontinuous and non-stationary operation, with some control and optimization problems. In the present work, a solar powered membrane distillation system has been used for developing an optimizing control strategy. A neural network (NN) model of the system has been trained and tested using experimental data purposely collected. Afterwards, the NN model has been used for the analysis of the process performance under various operating conditions, namely distillate production versus fee…
Membrane distillation: Solar and waste heat driven demonstration plants for desalination
2013
Abstract The development of small to medium size, autonomous and robust desalination units is needed to establish an independent water supply in remote areas. This is the motivation for research on alternative desalination processes. Membrane distillation (MD) seems to meet the specific requirements very well. This work is focused on experimental studies on full scale demonstration systems, utilizing a parallel multi MD-module setup. Three different plant concepts are introduced, one of them is waste heat driven and two of them are powered by solar thermal collectors. Design parameters and system design are presented. After the analysis of plant operation a comparison among the plants as we…
Development of a Membrane Distillation module for solar energy seawater desalination
2012
Abstract Membrane Distillation (MD) processes are gaining growing interest among novel desalination technologies, in particular for small scale applications also coupled with non-conventional energy sources. In the present work an original laboratory scale planar geometry Membrane Distillation unit was designed, built and tested for future coupling with solar energy. Though conceptually simple, the original geometry was developed in order to allow for multi-stage arrangement, compactness, internal heat recovery and possible integration with a polymeric heat exchanger for final brine heating by means of solar energy or waste heat. The laboratory scale unit was tested in order to investigate …