Search results for "Dithioerythritol"

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Artificial Oral Processing of Extruded Pea Flour Snacks

2021

International audience; The structure of extruded pea flour can affect chewing performances. Our objective was to relate the bolus properties (fragmentation, moisture content and viscosity) of chewed extruded pea snacks to their structure. In order to have control over oral physiological parameters, we opted for an in vitro approach using a chewing simulator, the variables of which were the flow rate of artificial salivary fluid and chewing time. The structure of the extruded pea snacks was characterized by its density and protein solubility in dithioerythritol (DTE), which reflected the amount of protein aggregates cross-linked by disulphide bonds. The particle size distribution and median…

0106 biological sciencesProtein aggregatesSalivaDithioerythritol[SPI.GPROC] Engineering Sciences [physics]/Chemical and Process EngineeringViscosity.[SPI.MECA.MSMECA]Engineering Sciences [physics]/Mechanics [physics.med-ph]/Materials and structures in mechanics [physics.class-ph]01 natural sciencesIndustrial and Manufacturing Engineeringchemistry.chemical_compound0404 agricultural biotechnology010608 biotechnology[SDV.IDA]Life Sciences [q-bio]/Food engineeringRelative density[SPI.GPROC]Engineering Sciences [physics]/Chemical and Process EngineeringFood scienceComputingMilieux_MISCELLANEOUS2. Zero hungerShear thinningRheometryViscositydigestive oral and skin physiologyPlasticizationPlasticizerfood and beveragesStarch04 agricultural and veterinary sciences040401 food scienceChewingstomatognathic diseaseschemistryParticle-size distributionGravimetric analysisDisulphide bonds
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Synthesis and characterization of complexes of trialkyl- and triarylphosphine gold(I) with thiolated purines and pyrimidines. A class of bifunctional…

1991

Abstract New complexes of the type R 3 PAuL or (R 3 PAu) 2 (μ-L) where R=ethyl or phenyl and L=6-thioguanine, 2, 6- dithioxanthine, 2, 4-dithiouracil and/or dithioerythritol have been prepared. These complexes have been identified by using elemental analysis, 1 H, 13 C and 31 P NMR spectroscopy. The structures have been proposed based on these spectroscopic studies. Sulfur appears to be the binding site in disubstituted complexes of 2, 4-dithiouracil and 1, 4-dithioerythritol, while the phosphine gold( I ) moieties appear to be S and N bonded in 2, 6-dithioxanthine and 6-thioguanine. The potential use of these complexes as antitumor drugs is discussed.

Antitumor activityBicyclic moleculeDithioerythritolStereochemistryChemistrychemistry.chemical_elementBiological activityNuclear magnetic resonance spectroscopySulfurBiochemistryCombinatorial chemistryInorganic Chemistrychemistry.chemical_compoundMaterials ChemistryPhysical and Theoretical ChemistryBinding sitePurine metabolismBifunctionalPhosphineJournal of Inorganic Biochemistry
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