Search results for "Dithiol"

showing 10 items of 143 documents

CCDC 1562675: Experimental Crystal Structure Determination

2017

Related Article: György Szalóki, Vincent Croué, Vincent Carré, Frédéric Aubriet, Olivier Alévêque, Eric Levillain, Magali Allain, Juan Aragó, Enrique Ortí, Sébastien Goeb, Marc Sallé|2017|Angew.Chem.,Int.Ed.|56|16272|doi:10.1002/anie.201709483

bis(mu-44'4''4'''-{(2367-tetrakis(369-trioxadecoxy)anthracene-910-diylidene)bis[(2H-13-dithiole-45-diyl-2-ylidene)]}tetrapyridine)-octakis(35-dichloro-246-trifluorophenyl)-tetra-platinum acetonitrile solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 639723: Experimental Crystal Structure Determination

2007

Related Article: A.Alberola, R.Llusar, S.Triguero, C.Vicent, M.N.Sokolov, C.Gomez-Garcia|2007|J.Mater.Chem.|17|3440|doi:10.1039/b703551a

bis(tetrabutylammonium) (mu~3~-sulfido)-tris(mu~2~-disulfido)-tris(125-thiadiazole-34-dithiolato)-tri-molybdenum hemihydrateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1450245: Experimental Crystal Structure Determination

2016

Related Article: Esther Delgado, Carlos J. Gómez-García, Diego Hernández, Elisa Hernández, Avelino Martín, Félix Zamora|2016|Dalton Trans.|45|6696|doi:10.1039/C6DT00464D

catena-(bis(mu-36-dichlorobenzene-12-dithiolato)-bis(mu-aqua)-(mu-tetrahydrofuran)-bis(tetrahydrofuran)-nickel-di-potassium)Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1450247: Experimental Crystal Structure Determination

2016

Related Article: Esther Delgado, Carlos J. Gómez-García, Diego Hernández, Elisa Hernández, Avelino Martín, Félix Zamora|2016|Dalton Trans.|45|6696|doi:10.1039/C6DT00464D

catena-(bis(mu-36-dichlorobenzene-12-dithiolato)-bis(mu-aqua)-hexakis(tetrahydrofuran)-di-potassium-platinum)Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1934947: Experimental Crystal Structure Determination

2019

Related Article: Javier Castells-Gil, Samuel Mañas-Valero, Iñigo J. Vitórica-Yrezábal, Duarte Ananias, João Rocha, Raul Santiago, Stefan T. Bromley, José J. Baldoví, Eugenio Coronado, Manuel Souto, Guillermo Mínguez Espallargas|2019|Chem.-Eur.J.|25|12636|doi:10.1002/chem.201902855

catena-[(mu-hydrogen 44'-{2-[45-bis(4-carboxylatophenyl)-2H-13-dithiol-2-ylidene]-2H-13-dithiole-45-diyl}dibenzoato)-aqua-dysprosium acetic acid unknown solvate]Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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Comparative studies of oxidation processes on Group 10 Metals Dithiolene Derivatives in the formation of coordination polymers

2018

This document is the Accepted Manuscript Version of a Published Work that appeared in final form in "Crystal Growth and Design", copyright © 2018 American Chemical Society after peer review and techical editing by publisher. To access the final and published work see "Comparative Studies of Oxidation Processes on Group 10 Metals Dithiolene Derivatives in the Formation of Coordination Polymers Oscar Castillo, Esther Delgado, Carlos J. Gómez-García, Diego Hernández, Elisa Hernández, Pilar Herrasti, Avelino Martín, and Félix Zamora Crystal Growth & Design 2018 18 (4), 2486-2494

chemistry.chemical_classification010405 organic chemistryDianionic tetranickel dithiolene clusterFísicaGeneral ChemistryPolymerQuímica010402 general chemistryCondensed Matter Physics01 natural sciencesMedicinal chemistryRedoxGroup 10 metal dithiolene Ion-Pairs0104 chemical sciencesCoordination polymerschemistryGroup (periodic table)General Materials ScienceGroup 10 metal dithiolene compounds
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Bis(triorganometal) and diorganometal 1,3-dithiolates (R3M)2(C6H3XS2) and R2M(C6H3XS2) (M = Sn, Pb; X= H, Cl)

1984

Abstract Bis(triorganometal) and diorganometal 1,3-dithiolates (R3M)2(C6H3XS2) (C6H5XS2 1,3-dithiobenzene (for X = H) or 1,3-dithio-4-chlorobenzene (for X = Cl); M = Sn, X = Cl, R = CH3, C6H5; M = Pb, X = H, Cl, R = CH3, C2H5) and R2M(C6H3XS2) (R = CH3, C2H5, C6H5; M = Sn, X = Cl; M = Pb, X = H, Cl) have been prepared as the first organometal IVB derivatives of 1,3-dithiols, and investigated by vibrational, 1H NMR, and (in the case of organotin compounds) Mossbauer spectroscopy. The triorganometal derivatives are monomeric and the diorganometal derivatives dimeric in solution (37° C). For the latter a twelve-membered ring structure is proposed for both solution and the solid state.

chemistry.chemical_classificationChemistryStereochemistryOrganic ChemistryDithiolNuclear magnetic resonance spectroscopyRing (chemistry)BiochemistryInorganic Chemistrychemistry.chemical_compoundCrystallographyMonomerMössbauer spectroscopyMaterials ChemistryProton NMRMoleculePhysical and Theoretical ChemistryInorganic compoundJournal of Organometallic Chemistry
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A new type of pi-electron donors with one dithiole unit: Substituted 7-(1,3-dithiol-2-ylidene)-7-hydrobenz[d,e]anthracenes

1999

New electron donors 11a–c bearing only one 1,3-dithiole ring conjugated with an acene backbone have been synthesized by Wittig–Horner reactions from 7H-benz[d,e]anthracen-7-one (10) and differently substituted phosphonate esters 9a–c. The donor properties of 11 have been characterized by means of both experimental techniques and quantum chemical calculations. Cyclic voltammetry measurements on the novel compounds predict donor abilities comparable to those of TTF and BEDT-TTF. The voltammograms show a multi-stage redox behaviour with oxidation up to the trication, where the first two oxidation processes take place at very close potentials. These processes have been assigned to a simultaneou…

chemistry.chemical_compoundChemistryIntramolecular forceOrganic ChemistryDithiolAromaticityPhysical and Theoretical ChemistryConjugated systemRing (chemistry)PhotochemistryAceneRedoxDication
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Synthesis and structural characterization of cis- and trans-fused 4a,5,6,7,8,8a-hexahydro-2H,4H-1,3-benzodithiines and their 2-methyl and 2,2-dimethy…

2002

Both cis- and trans-fused 4a,5,6,7,8,8a-hexahydro-2H,4H-1,3-benzodithiine together with their 2-methyl and 2,2-dimethyl derivatives were prepared as racemates from the appropriate dithiols obtained via multistep syntheses. The products were characterized by 1 H and 13 C NMR, mass spectrometry, and for two of the cis-fused compounds by X-ray diffraction. 1 H, 1 H vicinal coupling constants indicated that all compounds attain chair-chair conformations as their predominant conformations. All three trans-fused isomers exist in totally biased chair-chair conformations and are essentially conformationally locked, whereas the cis-fused compounds are conformationally mobile and can potentially atta…

chemistry.chemical_compoundchemistryBicyclic moleculeStereochemistryOrganic ChemistryX-ray crystallographyDithiolMoleculeCarbon-13 NMRChemical synthesisConformational isomerismCis–trans isomerismThe Journal of organic chemistry
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CCDC 2153375: Experimental Crystal Structure Determination

2022

Related Article: María Vicent-Morales, María Esteve-Rochina, Joaquín Calbo, Enrique Ortí, Iñigo J. Vitórica-Yrezábal, Guillermo Mínguez Espallargas|2022|J.Am.Chem.Soc.|144|9074|doi:10.1021/jacs.2c01957

dimethylammonium 4-{2-[45-bis(4-carboxyphenyl)-2H-13-dithiol-2-ylidene]-5-(4-carboxyphenyl)-2H-13-dithiol-4-yl}benzoate NN-dimethylformamide solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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